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Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane plus n-alkane systems
The Peng-Robinson-Stryjek-Vera (PRSV) equation of state (EOS) coupled with a modified two parameter van der Waals one-fluid mixing rule (MvdW1) and the Huron-Vidal-Orbey-Sandler mixing rule incorporating the NRTL equation as a G(E) model was used for the correlation of excess enthalpy (H-E, excess heat capacity (C-p(E)) and the simultaneous correlation of both properties. All calculations with temperature dependent parameters of EOS models were applied to 1,3-dioxolane+n-alkane systems. The correlation of the H-E and C-p(E) data alone with four coefficients and the H-E+C-p(E) data with six coefficients of the temperature dependent parameters of the HVOS-NRTL models could be considered as very satisfactory.
Keywords:
equation of state / mixing rule / excess properties / 1,3-dioxolane / n-alkane
Source:
Journal of the Serbian Chemical Society, 1999, 64, 12, 801-811
TY - JOUR
AU - Đorđević, Bojan D.
AU - Kijevčanin, Mirjana
AU - Tasić, Aleksandar
AU - Šerbanović, Slobodan P.
PY - 1999
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/228
AB - The Peng-Robinson-Stryjek-Vera (PRSV) equation of state (EOS) coupled with a modified two parameter van der Waals one-fluid mixing rule (MvdW1) and the Huron-Vidal-Orbey-Sandler mixing rule incorporating the NRTL equation as a G(E) model was used for the correlation of excess enthalpy (H-E, excess heat capacity (C-p(E)) and the simultaneous correlation of both properties. All calculations with temperature dependent parameters of EOS models were applied to 1,3-dioxolane+n-alkane systems. The correlation of the H-E and C-p(E) data alone with four coefficients and the H-E+C-p(E) data with six coefficients of the temperature dependent parameters of the HVOS-NRTL models could be considered as very satisfactory.
PB - Serbian Chemical Society, Belgrade
T2 - Journal of the Serbian Chemical Society
T1 - Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane plus n-alkane systems
EP - 811
IS - 12
SP - 801
VL - 64
DO - 10.2298/jsc9912801d
ER -
@article{
author = "Đorđević, Bojan D. and Kijevčanin, Mirjana and Tasić, Aleksandar and Šerbanović, Slobodan P.",
year = "1999",
abstract = "The Peng-Robinson-Stryjek-Vera (PRSV) equation of state (EOS) coupled with a modified two parameter van der Waals one-fluid mixing rule (MvdW1) and the Huron-Vidal-Orbey-Sandler mixing rule incorporating the NRTL equation as a G(E) model was used for the correlation of excess enthalpy (H-E, excess heat capacity (C-p(E)) and the simultaneous correlation of both properties. All calculations with temperature dependent parameters of EOS models were applied to 1,3-dioxolane+n-alkane systems. The correlation of the H-E and C-p(E) data alone with four coefficients and the H-E+C-p(E) data with six coefficients of the temperature dependent parameters of the HVOS-NRTL models could be considered as very satisfactory.",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane plus n-alkane systems",
pages = "811-801",
number = "12",
volume = "64",
doi = "10.2298/jsc9912801d"
}
Đorđević, B. D., Kijevčanin, M., Tasić, A.,& Šerbanović, S. P.. (1999). Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane plus n-alkane systems. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 64(12), 801-811.
https://doi.org/10.2298/jsc9912801d
Đorđević BD, Kijevčanin M, Tasić A, Šerbanović SP. Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane plus n-alkane systems. in Journal of the Serbian Chemical Society. 1999;64(12):801-811.
doi:10.2298/jsc9912801d .
Đorđević, Bojan D., Kijevčanin, Mirjana, Tasić, Aleksandar, Šerbanović, Slobodan P., "Application of the MvdW1 and HVOS-NRTL mixing rules to the simultaneous correlation of excess enthalpies and W-shaped excess heat capacities data of 1,3-dioxolane plus n-alkane systems" in Journal of the Serbian Chemical Society, 64, no. 12 (1999):801-811,
https://doi.org/10.2298/jsc9912801d . .
