Physical, chemical and structural effects as important factors for the determination of thermodynamic and transport properties and the modelling of non-electrolyte solutions

Abstract

In our previous review, an attempt was made to relate the volumetric effects involved in binary mixtures of normal and branched alcohols. The present paper summarizes some selected research activities related to complex molecular structure of various authors that appeared in leading international journals. The main aim was a better understanding of the complex structure of different non-electrolyte mixtures with no alcohols, which are most frequently present in the chemical, petrochemical and related industries. The influences of the basic physical, chemical and structural effects of the most often chosen types of various binary and ternary mixtures were analyzed. These contributions are of primary importance for the determination and modelling of thermodynamic, transport and other properties. .

U našem preglednom radu učinjen je pokušaj da se povežu volumetrijski efekti uključeni u binarne smeše normalnih i razgranatih alkohola. U ovom radu su ukratko izložene neke izabrane istraživačke aktivnosti autora povezanih sa složenim molekulskim strukturama koje su objavljene u vodećim međunarodnim časopisima. Glavni cilj je bio bolje razumevanje kompleksne strukture različitih smeša neelektrolita, bez alkohola, koje su najčešće prisutne u hemijskoj, petrohemijskoj i srodnim industrijama. Analiziran je uticaj osnovnih fizičkih, hemijskih i strukturnih efekata više izabranih tipova različitih binarnih i ternernih smeša. Ovakva istraživanja su od primarnog značaja za određivanje i modelovanje termodinamičkih, transportnih i drugih osobina. .