Correlation of liquid-liquid equilibria of non-ideal binary systems using the non-random, two-liquid model
Korelisanje ravnoteže tečno-tečno neidealnih binarnih sistema pomoću NRTL modela
Authors
Grozdanić, Nikola
Kijevčanin, Mirjana

Višak, Zoran P.

Grozdanić, Dušan K.
Šerbanović, Slobodan P.
Article (Published version)
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Show full item recordAbstract
The non-random, two-liquid (NRTL) model with three different forms of temperature dependant parameters was used to correlate the liquidliquid equilibrium data for systems of alcohols with alkanes, and alcohols with two ionic liquids: 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([bmmim][BF4]) and 1-butyl-3-ethylimidazolium tetrafluoroborate ([beim][BF4]). Different temperature dependences of the NRTL parameters were tested on thirteen literature experimental liquid-liquid equilibrium data for binary systems.
NRTL model sa tri različita temperaturno zavisna parametra korišćen je za korelisanje ravnoteže tečno-tečno za binarne sisteme alkohola sa alkanima, kao i alkohola sa dve jonske tečnosti: 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([bmmim] [BF4]) i 1-butyl-3-ethylimidazolium tetrafluoroborate ([beim][BF4]). U radu su testirane tri različite forme temperaturne zavisnosti parametara NRTL modela. Ravnoteža tečnost-tečnost je modelovana na trinaest binarnih sistema. Kod svih sistema su dobijeni veoma zadovoljavajući rezultati sa srednjim greškama oko 3 %, korišćenjem sve tri forme temperaturne zavisnosti.
Keywords:
liquid-liquid equilibria / NRTL model / optimization / ionic liquids / modelingSource:
Journal of the Serbian Chemical Society, 2013, 78, 6, 865-872Publisher:
- Serbian Chemical Society, Belgrade
Funding / projects:
- New industrial and environmental application of chemical thermodynamics to the development of the chemical processes with multiphase and multicomponent systems (RS-172063)
- Faculty of Technology and Metallurgy, University of Belgrade
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Grozdanić, Nikola AU - Kijevčanin, Mirjana AU - Višak, Zoran P. AU - Grozdanić, Dušan K. AU - Šerbanović, Slobodan P. PY - 2013 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2361 AB - The non-random, two-liquid (NRTL) model with three different forms of temperature dependant parameters was used to correlate the liquidliquid equilibrium data for systems of alcohols with alkanes, and alcohols with two ionic liquids: 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([bmmim][BF4]) and 1-butyl-3-ethylimidazolium tetrafluoroborate ([beim][BF4]). Different temperature dependences of the NRTL parameters were tested on thirteen literature experimental liquid-liquid equilibrium data for binary systems. AB - NRTL model sa tri različita temperaturno zavisna parametra korišćen je za korelisanje ravnoteže tečno-tečno za binarne sisteme alkohola sa alkanima, kao i alkohola sa dve jonske tečnosti: 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([bmmim] [BF4]) i 1-butyl-3-ethylimidazolium tetrafluoroborate ([beim][BF4]). U radu su testirane tri različite forme temperaturne zavisnosti parametara NRTL modela. Ravnoteža tečnost-tečnost je modelovana na trinaest binarnih sistema. Kod svih sistema su dobijeni veoma zadovoljavajući rezultati sa srednjim greškama oko 3 %, korišćenjem sve tri forme temperaturne zavisnosti. PB - Serbian Chemical Society, Belgrade T2 - Journal of the Serbian Chemical Society T1 - Correlation of liquid-liquid equilibria of non-ideal binary systems using the non-random, two-liquid model T1 - Korelisanje ravnoteže tečno-tečno neidealnih binarnih sistema pomoću NRTL modela EP - 872 IS - 6 SP - 865 VL - 78 UR - https://hdl.handle.net/21.15107/rcub_technorep_2361 ER -
@article{ author = "Grozdanić, Nikola and Kijevčanin, Mirjana and Višak, Zoran P. and Grozdanić, Dušan K. and Šerbanović, Slobodan P.", year = "2013", abstract = "The non-random, two-liquid (NRTL) model with three different forms of temperature dependant parameters was used to correlate the liquidliquid equilibrium data for systems of alcohols with alkanes, and alcohols with two ionic liquids: 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([bmmim][BF4]) and 1-butyl-3-ethylimidazolium tetrafluoroborate ([beim][BF4]). Different temperature dependences of the NRTL parameters were tested on thirteen literature experimental liquid-liquid equilibrium data for binary systems., NRTL model sa tri različita temperaturno zavisna parametra korišćen je za korelisanje ravnoteže tečno-tečno za binarne sisteme alkohola sa alkanima, kao i alkohola sa dve jonske tečnosti: 1-butyl-2,3-dimethylimidazolium tetrafluoroborate ([bmmim] [BF4]) i 1-butyl-3-ethylimidazolium tetrafluoroborate ([beim][BF4]). U radu su testirane tri različite forme temperaturne zavisnosti parametara NRTL modela. Ravnoteža tečnost-tečnost je modelovana na trinaest binarnih sistema. Kod svih sistema su dobijeni veoma zadovoljavajući rezultati sa srednjim greškama oko 3 %, korišćenjem sve tri forme temperaturne zavisnosti.", publisher = "Serbian Chemical Society, Belgrade", journal = "Journal of the Serbian Chemical Society", title = "Correlation of liquid-liquid equilibria of non-ideal binary systems using the non-random, two-liquid model, Korelisanje ravnoteže tečno-tečno neidealnih binarnih sistema pomoću NRTL modela", pages = "872-865", number = "6", volume = "78", url = "https://hdl.handle.net/21.15107/rcub_technorep_2361" }
Grozdanić, N., Kijevčanin, M., Višak, Z. P., Grozdanić, D. K.,& Šerbanović, S. P.. (2013). Correlation of liquid-liquid equilibria of non-ideal binary systems using the non-random, two-liquid model. in Journal of the Serbian Chemical Society Serbian Chemical Society, Belgrade., 78(6), 865-872. https://hdl.handle.net/21.15107/rcub_technorep_2361
Grozdanić N, Kijevčanin M, Višak ZP, Grozdanić DK, Šerbanović SP. Correlation of liquid-liquid equilibria of non-ideal binary systems using the non-random, two-liquid model. in Journal of the Serbian Chemical Society. 2013;78(6):865-872. https://hdl.handle.net/21.15107/rcub_technorep_2361 .
Grozdanić, Nikola, Kijevčanin, Mirjana, Višak, Zoran P., Grozdanić, Dušan K., Šerbanović, Slobodan P., "Correlation of liquid-liquid equilibria of non-ideal binary systems using the non-random, two-liquid model" in Journal of the Serbian Chemical Society, 78, no. 6 (2013):865-872, https://hdl.handle.net/21.15107/rcub_technorep_2361 .
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