This paper reports the results of FTIR study of N-tert-butylacetamide in carbon tetrachloride solution and in presence of seven different molecules as H acceptors. The spectroscopic characteristics for N-H center dot center dot center dot O hydrogen bonded complexes are given. Also, the equilibrium constants for 1:1 complex formation, at 25 degrees C were determined by using IR measurements. Frequency shifts of carbonyl stretching vibration nu(C=O) of N-tert-butylacetamide in the same organic H acceptors was also investigated. The wavenumbers of carbonyl stretching vibration nu(C=O) were correlated with the solvent acceptor number (AN) and the linear solvation energy relationships (LSERs).
TY - JOUR
AU - Jović, Branislav
AU - Nikolić, Aleksandar
AU - Petrović, Slobodan
PY - 2013
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2438
AB - This paper reports the results of FTIR study of N-tert-butylacetamide in carbon tetrachloride solution and in presence of seven different molecules as H acceptors. The spectroscopic characteristics for N-H center dot center dot center dot O hydrogen bonded complexes are given. Also, the equilibrium constants for 1:1 complex formation, at 25 degrees C were determined by using IR measurements. Frequency shifts of carbonyl stretching vibration nu(C=O) of N-tert-butylacetamide in the same organic H acceptors was also investigated. The wavenumbers of carbonyl stretching vibration nu(C=O) were correlated with the solvent acceptor number (AN) and the linear solvation energy relationships (LSERs).
PB - Elsevier Science Bv, Amsterdam
T2 - Journal of Molecular Structure
T1 - FTIR spectroscopic study of hydrogen bonding and solvent induced frequency shifts of N-tert-butylacetamide
EP - 143
SP - 140
VL - 1044
DO - 10.1016/j.molstruc.2012.10.009
ER -
@article{
author = "Jović, Branislav and Nikolić, Aleksandar and Petrović, Slobodan",
year = "2013",
abstract = "This paper reports the results of FTIR study of N-tert-butylacetamide in carbon tetrachloride solution and in presence of seven different molecules as H acceptors. The spectroscopic characteristics for N-H center dot center dot center dot O hydrogen bonded complexes are given. Also, the equilibrium constants for 1:1 complex formation, at 25 degrees C were determined by using IR measurements. Frequency shifts of carbonyl stretching vibration nu(C=O) of N-tert-butylacetamide in the same organic H acceptors was also investigated. The wavenumbers of carbonyl stretching vibration nu(C=O) were correlated with the solvent acceptor number (AN) and the linear solvation energy relationships (LSERs).",
publisher = "Elsevier Science Bv, Amsterdam",
journal = "Journal of Molecular Structure",
title = "FTIR spectroscopic study of hydrogen bonding and solvent induced frequency shifts of N-tert-butylacetamide",
pages = "143-140",
volume = "1044",
doi = "10.1016/j.molstruc.2012.10.009"
}
Jović, B., Nikolić, A.,& Petrović, S.. (2013). FTIR spectroscopic study of hydrogen bonding and solvent induced frequency shifts of N-tert-butylacetamide. in Journal of Molecular Structure
Elsevier Science Bv, Amsterdam., 1044, 140-143.
https://doi.org/10.1016/j.molstruc.2012.10.009
Jović B, Nikolić A, Petrović S. FTIR spectroscopic study of hydrogen bonding and solvent induced frequency shifts of N-tert-butylacetamide. in Journal of Molecular Structure. 2013;1044:140-143.
doi:10.1016/j.molstruc.2012.10.009 .
Jović, Branislav, Nikolić, Aleksandar, Petrović, Slobodan, "FTIR spectroscopic study of hydrogen bonding and solvent induced frequency shifts of N-tert-butylacetamide" in Journal of Molecular Structure, 1044 (2013):140-143,
https://doi.org/10.1016/j.molstruc.2012.10.009 . .
