FTIR spectroscopic study of hydrogen bonding and solvent induced frequency shifts of N-tert-butylacetamide
Abstract
This paper reports the results of FTIR study of N-tert-butylacetamide in carbon tetrachloride solution and in presence of seven different molecules as H acceptors. The spectroscopic characteristics for N-H center dot center dot center dot O hydrogen bonded complexes are given. Also, the equilibrium constants for 1:1 complex formation, at 25 degrees C were determined by using IR measurements. Frequency shifts of carbonyl stretching vibration nu(C=O) of N-tert-butylacetamide in the same organic H acceptors was also investigated. The wavenumbers of carbonyl stretching vibration nu(C=O) were correlated with the solvent acceptor number (AN) and the linear solvation energy relationships (LSERs).
Keywords:
Hydrogen bonding / N-tert-butylacetamide / Solvent effectSource:
Journal of Molecular Structure, 2013, 1044, 140-143Publisher:
- Elsevier Science Bv, Amsterdam
Funding / projects:
- Study of the Synthesis, Structure and Activity of Natural and Synthetic Organic Compounds (RS-172013)
DOI: 10.1016/j.molstruc.2012.10.009
ISSN: 0022-2860
WoS: 000320635200023
Scopus: 2-s2.0-84878289211
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Jović, Branislav AU - Nikolić, Aleksandar AU - Petrović, Slobodan PY - 2013 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2438 AB - This paper reports the results of FTIR study of N-tert-butylacetamide in carbon tetrachloride solution and in presence of seven different molecules as H acceptors. The spectroscopic characteristics for N-H center dot center dot center dot O hydrogen bonded complexes are given. Also, the equilibrium constants for 1:1 complex formation, at 25 degrees C were determined by using IR measurements. Frequency shifts of carbonyl stretching vibration nu(C=O) of N-tert-butylacetamide in the same organic H acceptors was also investigated. The wavenumbers of carbonyl stretching vibration nu(C=O) were correlated with the solvent acceptor number (AN) and the linear solvation energy relationships (LSERs). PB - Elsevier Science Bv, Amsterdam T2 - Journal of Molecular Structure T1 - FTIR spectroscopic study of hydrogen bonding and solvent induced frequency shifts of N-tert-butylacetamide EP - 143 SP - 140 VL - 1044 DO - 10.1016/j.molstruc.2012.10.009 ER -
@article{ author = "Jović, Branislav and Nikolić, Aleksandar and Petrović, Slobodan", year = "2013", abstract = "This paper reports the results of FTIR study of N-tert-butylacetamide in carbon tetrachloride solution and in presence of seven different molecules as H acceptors. The spectroscopic characteristics for N-H center dot center dot center dot O hydrogen bonded complexes are given. Also, the equilibrium constants for 1:1 complex formation, at 25 degrees C were determined by using IR measurements. Frequency shifts of carbonyl stretching vibration nu(C=O) of N-tert-butylacetamide in the same organic H acceptors was also investigated. The wavenumbers of carbonyl stretching vibration nu(C=O) were correlated with the solvent acceptor number (AN) and the linear solvation energy relationships (LSERs).", publisher = "Elsevier Science Bv, Amsterdam", journal = "Journal of Molecular Structure", title = "FTIR spectroscopic study of hydrogen bonding and solvent induced frequency shifts of N-tert-butylacetamide", pages = "143-140", volume = "1044", doi = "10.1016/j.molstruc.2012.10.009" }
Jović, B., Nikolić, A.,& Petrović, S.. (2013). FTIR spectroscopic study of hydrogen bonding and solvent induced frequency shifts of N-tert-butylacetamide. in Journal of Molecular Structure Elsevier Science Bv, Amsterdam., 1044, 140-143. https://doi.org/10.1016/j.molstruc.2012.10.009
Jović B, Nikolić A, Petrović S. FTIR spectroscopic study of hydrogen bonding and solvent induced frequency shifts of N-tert-butylacetamide. in Journal of Molecular Structure. 2013;1044:140-143. doi:10.1016/j.molstruc.2012.10.009 .
Jović, Branislav, Nikolić, Aleksandar, Petrović, Slobodan, "FTIR spectroscopic study of hydrogen bonding and solvent induced frequency shifts of N-tert-butylacetamide" in Journal of Molecular Structure, 1044 (2013):140-143, https://doi.org/10.1016/j.molstruc.2012.10.009 . .