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New facile one-pot synthesis of S-alkyl thiolcarbamates from xanthogenate in water
dc.creator | Milosavljević, Milutin M. | |
dc.creator | Mijin, Dušan | |
dc.creator | Milisavljević, Smiljka S. | |
dc.creator | Elezović, Nataša M. | |
dc.creator | Milanović, Jelena K. | |
dc.date.accessioned | 2021-03-10T12:10:21Z | |
dc.date.available | 2021-03-10T12:10:21Z | |
dc.date.issued | 2013 | |
dc.identifier.issn | 0026-9247 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2442 | |
dc.description.abstract | A simple and efficient one-pot synthesis was developed for the preparation of S-alkyl thiolcarbamates from xanthogenate without catalyst using water as a solvent. The water can be recycled after removal of the product. The significant features of this protocol are: operational simplicity, mild reaction conditions, recycling of solvent and high product yields. Starting basic alkyl xanthogenate reacts with alkyl ammonium sulfate (aryl ammonium sulfate) and hydrogen peroxide (molar ratio 1:0.55:1) in water at 40 A degrees C for 1 h, followed by additional heating at 70-110 A degrees C for 1-2.3 h. Good to excellent yields were achieved using ammonium sulfate in 10 % molar excess. | en |
dc.publisher | Springer Wien, Wien | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172013/RS// | |
dc.rights | restrictedAccess | |
dc.source | Monatshefte Fur Chemie | |
dc.subject | Amines | en |
dc.subject | Catalyst-free reaction | en |
dc.subject | Fungicides | en |
dc.subject | Alkyl ammonium sulfate | en |
dc.subject | Aryl ammonium sulfate | en |
dc.title | New facile one-pot synthesis of S-alkyl thiolcarbamates from xanthogenate in water | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 1837 | |
dc.citation.issue | 12 | |
dc.citation.other | 144(12): 1833-1837 | |
dc.citation.rank | M22 | |
dc.citation.spage | 1833 | |
dc.citation.volume | 144 | |
dc.identifier.doi | 10.1007/s00706-013-1083-7 | |
dc.identifier.scopus | 2-s2.0-84890099477 | |
dc.identifier.wos | 000327083100011 | |
dc.type.version | publishedVersion |