The thermal degradation of some isomers of poly(di-butyl itaconates)
Само за регистроване кориснике
1999
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The non-oxidative and oxidative thermal degradation of poly(di-iso-butyl itaconate) (PDiBI), poly(di-n-butyl itaconate) (PDnBI), and poly(di-sec-butyl itaconate) (PDsBI) were studied by following changes in the polymer residue such as mass loss, limiting viscosity number (LVN) and the formation of carboxylic groups. Depolymerization is the dominant degradation mechanism of PDiBI, while PDnBI and PDsBI predominantly degrade by deesterification. The thermolysis mechanism is determined by the number of beta-hydrogen atoms in the ester substituent: five in PDsBI, two in PDnBI and one in PDiBi.
Кључне речи:
thermal degradation / isomer / poly(di-butyl itaconates) / pyrolysisИзвор:
Journal of Analytical and Applied Pyrolysis, 1999, 49, 1-2, 75-86Издавач:
- Elsevier, Amsterdam
DOI: 10.1016/S0165-2370(98)00128-4
ISSN: 0165-2370
WoS: 000079423300006
Scopus: 2-s2.0-0344183051
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Veličković, Sava AU - Katsikas, Lynne AU - Popović, Ivanka PY - 1999 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/244 AB - The non-oxidative and oxidative thermal degradation of poly(di-iso-butyl itaconate) (PDiBI), poly(di-n-butyl itaconate) (PDnBI), and poly(di-sec-butyl itaconate) (PDsBI) were studied by following changes in the polymer residue such as mass loss, limiting viscosity number (LVN) and the formation of carboxylic groups. Depolymerization is the dominant degradation mechanism of PDiBI, while PDnBI and PDsBI predominantly degrade by deesterification. The thermolysis mechanism is determined by the number of beta-hydrogen atoms in the ester substituent: five in PDsBI, two in PDnBI and one in PDiBi. PB - Elsevier, Amsterdam T2 - Journal of Analytical and Applied Pyrolysis T1 - The thermal degradation of some isomers of poly(di-butyl itaconates) EP - 86 IS - 1-2 SP - 75 VL - 49 DO - 10.1016/S0165-2370(98)00128-4 ER -
@article{ author = "Veličković, Sava and Katsikas, Lynne and Popović, Ivanka", year = "1999", abstract = "The non-oxidative and oxidative thermal degradation of poly(di-iso-butyl itaconate) (PDiBI), poly(di-n-butyl itaconate) (PDnBI), and poly(di-sec-butyl itaconate) (PDsBI) were studied by following changes in the polymer residue such as mass loss, limiting viscosity number (LVN) and the formation of carboxylic groups. Depolymerization is the dominant degradation mechanism of PDiBI, while PDnBI and PDsBI predominantly degrade by deesterification. The thermolysis mechanism is determined by the number of beta-hydrogen atoms in the ester substituent: five in PDsBI, two in PDnBI and one in PDiBi.", publisher = "Elsevier, Amsterdam", journal = "Journal of Analytical and Applied Pyrolysis", title = "The thermal degradation of some isomers of poly(di-butyl itaconates)", pages = "86-75", number = "1-2", volume = "49", doi = "10.1016/S0165-2370(98)00128-4" }
Veličković, S., Katsikas, L.,& Popović, I.. (1999). The thermal degradation of some isomers of poly(di-butyl itaconates). in Journal of Analytical and Applied Pyrolysis Elsevier, Amsterdam., 49(1-2), 75-86. https://doi.org/10.1016/S0165-2370(98)00128-4
Veličković S, Katsikas L, Popović I. The thermal degradation of some isomers of poly(di-butyl itaconates). in Journal of Analytical and Applied Pyrolysis. 1999;49(1-2):75-86. doi:10.1016/S0165-2370(98)00128-4 .
Veličković, Sava, Katsikas, Lynne, Popović, Ivanka, "The thermal degradation of some isomers of poly(di-butyl itaconates)" in Journal of Analytical and Applied Pyrolysis, 49, no. 1-2 (1999):75-86, https://doi.org/10.1016/S0165-2370(98)00128-4 . .