The non-oxidative and oxidative thermal degradation of poly(di-iso-butyl itaconate) (PDiBI), poly(di-n-butyl itaconate) (PDnBI), and poly(di-sec-butyl itaconate) (PDsBI) were studied by following changes in the polymer residue such as mass loss, limiting viscosity number (LVN) and the formation of carboxylic groups. Depolymerization is the dominant degradation mechanism of PDiBI, while PDnBI and PDsBI predominantly degrade by deesterification. The thermolysis mechanism is determined by the number of beta-hydrogen atoms in the ester substituent: five in PDsBI, two in PDnBI and one in PDiBi.
TY - JOUR
AU - Veličković, Sava
AU - Katsikas, Lynne
AU - Popović, Ivanka
PY - 1999
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/244
AB - The non-oxidative and oxidative thermal degradation of poly(di-iso-butyl itaconate) (PDiBI), poly(di-n-butyl itaconate) (PDnBI), and poly(di-sec-butyl itaconate) (PDsBI) were studied by following changes in the polymer residue such as mass loss, limiting viscosity number (LVN) and the formation of carboxylic groups. Depolymerization is the dominant degradation mechanism of PDiBI, while PDnBI and PDsBI predominantly degrade by deesterification. The thermolysis mechanism is determined by the number of beta-hydrogen atoms in the ester substituent: five in PDsBI, two in PDnBI and one in PDiBi.
PB - Elsevier, Amsterdam
T2 - Journal of Analytical and Applied Pyrolysis
T1 - The thermal degradation of some isomers of poly(di-butyl itaconates)
EP - 86
IS - 1-2
SP - 75
VL - 49
DO - 10.1016/S0165-2370(98)00128-4
ER -
@article{
author = "Veličković, Sava and Katsikas, Lynne and Popović, Ivanka",
year = "1999",
abstract = "The non-oxidative and oxidative thermal degradation of poly(di-iso-butyl itaconate) (PDiBI), poly(di-n-butyl itaconate) (PDnBI), and poly(di-sec-butyl itaconate) (PDsBI) were studied by following changes in the polymer residue such as mass loss, limiting viscosity number (LVN) and the formation of carboxylic groups. Depolymerization is the dominant degradation mechanism of PDiBI, while PDnBI and PDsBI predominantly degrade by deesterification. The thermolysis mechanism is determined by the number of beta-hydrogen atoms in the ester substituent: five in PDsBI, two in PDnBI and one in PDiBi.",
publisher = "Elsevier, Amsterdam",
journal = "Journal of Analytical and Applied Pyrolysis",
title = "The thermal degradation of some isomers of poly(di-butyl itaconates)",
pages = "86-75",
number = "1-2",
volume = "49",
doi = "10.1016/S0165-2370(98)00128-4"
}
Veličković, S., Katsikas, L.,& Popović, I.. (1999). The thermal degradation of some isomers of poly(di-butyl itaconates). in Journal of Analytical and Applied Pyrolysis
Elsevier, Amsterdam., 49(1-2), 75-86.
https://doi.org/10.1016/S0165-2370(98)00128-4
Veličković S, Katsikas L, Popović I. The thermal degradation of some isomers of poly(di-butyl itaconates). in Journal of Analytical and Applied Pyrolysis. 1999;49(1-2):75-86.
doi:10.1016/S0165-2370(98)00128-4 .
Veličković, Sava, Katsikas, Lynne, Popović, Ivanka, "The thermal degradation of some isomers of poly(di-butyl itaconates)" in Journal of Analytical and Applied Pyrolysis, 49, no. 1-2 (1999):75-86,
https://doi.org/10.1016/S0165-2370(98)00128-4 . .
