The incorporation of Mn(II) cations into a chabazite-like MnAlPO material is studied with Mn K-edge XANES and EXAFS. Both methods show that Mn(II) is inserted exclusively into the tetrahedrally coordinated aluminum sites. Calcination and rehydration of the as-synthesized MnAlPO cause a partial oxidation of Mn(II) as well as a change of its coordination geometry to a distorted octahedron.
TY - JOUR
AU - Arcon, Iztok
AU - Rajić, Nevenka
AU - Kodre, A
PY - 1999
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/245
AB - The incorporation of Mn(II) cations into a chabazite-like MnAlPO material is studied with Mn K-edge XANES and EXAFS. Both methods show that Mn(II) is inserted exclusively into the tetrahedrally coordinated aluminum sites. Calcination and rehydration of the as-synthesized MnAlPO cause a partial oxidation of Mn(II) as well as a change of its coordination geometry to a distorted octahedron.
PB - Int Union Crystallography, Chester
T2 - Journal of Synchrotron Radiation
T1 - EXAFS and XANES study of the incorporation of Mn cations into a chabazite-like AlPO molecular sieve
EP - 461
SP - 460
VL - 6
DO - 10.1107/S0909049598015684
ER -
@article{
author = "Arcon, Iztok and Rajić, Nevenka and Kodre, A",
year = "1999",
abstract = "The incorporation of Mn(II) cations into a chabazite-like MnAlPO material is studied with Mn K-edge XANES and EXAFS. Both methods show that Mn(II) is inserted exclusively into the tetrahedrally coordinated aluminum sites. Calcination and rehydration of the as-synthesized MnAlPO cause a partial oxidation of Mn(II) as well as a change of its coordination geometry to a distorted octahedron.",
publisher = "Int Union Crystallography, Chester",
journal = "Journal of Synchrotron Radiation",
title = "EXAFS and XANES study of the incorporation of Mn cations into a chabazite-like AlPO molecular sieve",
pages = "461-460",
volume = "6",
doi = "10.1107/S0909049598015684"
}
Arcon, I., Rajić, N.,& Kodre, A.. (1999). EXAFS and XANES study of the incorporation of Mn cations into a chabazite-like AlPO molecular sieve. in Journal of Synchrotron Radiation
Int Union Crystallography, Chester., 6, 460-461.
https://doi.org/10.1107/S0909049598015684
Arcon I, Rajić N, Kodre A. EXAFS and XANES study of the incorporation of Mn cations into a chabazite-like AlPO molecular sieve. in Journal of Synchrotron Radiation. 1999;6:460-461.
doi:10.1107/S0909049598015684 .
Arcon, Iztok, Rajić, Nevenka, Kodre, A, "EXAFS and XANES study of the incorporation of Mn cations into a chabazite-like AlPO molecular sieve" in Journal of Synchrotron Radiation, 6 (1999):460-461,
https://doi.org/10.1107/S0909049598015684 . .
