The Effects of Functionalization on the Thermal and Tribo-Mechanical Behaviors of Neat and Grafted Polyethylene Nanocomposites
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2013
Authors
Stojanović, Dušica
Orlović, Aleksandar

Zrilić, Milorad

Balać, Igor
Tang, C. Y.

Uskoković, Petar

Aleksić, Radoslav
Article (Published version)

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This article presents research on the influence of a coupling agent -methacryloxypropyltrimethoxysilane (MEMO) and cross-linking agent dicumyl peroxide (DCP) on thermal and nanomechanical properties of neat and waste polyethylene (WPE) as well as their blend. Modification of nanosilica by silanization was performed under supercritical conditions of carbon dioxide-ethanol mixture. Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), indentation as well as scratch testing at nanoscale were employed for characterization of the polymer matrix with unmodified and modified nano-SiO2 particles. Low amounts of the peroxide and silanized nano-SiO2 particles in the composite formulation significantly improved thermal and tribo-mechanical behavior at nanoscale. POLYM. COMPOS., 34:1710-1719, 2013.
Source:
Polymer Composites, 2013, 34, 10, 1710-1719Publisher:
- Wiley, Hoboken
Funding / projects:
- Predefined functional properties polymer composite materials processes and equipment development (RS-34011)
- Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-45019)
- EI4040
DOI: 10.1002/pc.22574
ISSN: 0272-8397
WoS: 000325089400017
Scopus: 2-s2.0-84885021846
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Stojanović, Dušica AU - Orlović, Aleksandar AU - Zrilić, Milorad AU - Balać, Igor AU - Tang, C. Y. AU - Uskoković, Petar AU - Aleksić, Radoslav PY - 2013 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2466 AB - This article presents research on the influence of a coupling agent -methacryloxypropyltrimethoxysilane (MEMO) and cross-linking agent dicumyl peroxide (DCP) on thermal and nanomechanical properties of neat and waste polyethylene (WPE) as well as their blend. Modification of nanosilica by silanization was performed under supercritical conditions of carbon dioxide-ethanol mixture. Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), indentation as well as scratch testing at nanoscale were employed for characterization of the polymer matrix with unmodified and modified nano-SiO2 particles. Low amounts of the peroxide and silanized nano-SiO2 particles in the composite formulation significantly improved thermal and tribo-mechanical behavior at nanoscale. POLYM. COMPOS., 34:1710-1719, 2013. PB - Wiley, Hoboken T2 - Polymer Composites T1 - The Effects of Functionalization on the Thermal and Tribo-Mechanical Behaviors of Neat and Grafted Polyethylene Nanocomposites EP - 1719 IS - 10 SP - 1710 VL - 34 DO - 10.1002/pc.22574 ER -
@article{ author = "Stojanović, Dušica and Orlović, Aleksandar and Zrilić, Milorad and Balać, Igor and Tang, C. Y. and Uskoković, Petar and Aleksić, Radoslav", year = "2013", abstract = "This article presents research on the influence of a coupling agent -methacryloxypropyltrimethoxysilane (MEMO) and cross-linking agent dicumyl peroxide (DCP) on thermal and nanomechanical properties of neat and waste polyethylene (WPE) as well as their blend. Modification of nanosilica by silanization was performed under supercritical conditions of carbon dioxide-ethanol mixture. Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), indentation as well as scratch testing at nanoscale were employed for characterization of the polymer matrix with unmodified and modified nano-SiO2 particles. Low amounts of the peroxide and silanized nano-SiO2 particles in the composite formulation significantly improved thermal and tribo-mechanical behavior at nanoscale. POLYM. COMPOS., 34:1710-1719, 2013.", publisher = "Wiley, Hoboken", journal = "Polymer Composites", title = "The Effects of Functionalization on the Thermal and Tribo-Mechanical Behaviors of Neat and Grafted Polyethylene Nanocomposites", pages = "1719-1710", number = "10", volume = "34", doi = "10.1002/pc.22574" }
Stojanović, D., Orlović, A., Zrilić, M., Balać, I., Tang, C. Y., Uskoković, P.,& Aleksić, R.. (2013). The Effects of Functionalization on the Thermal and Tribo-Mechanical Behaviors of Neat and Grafted Polyethylene Nanocomposites. in Polymer Composites Wiley, Hoboken., 34(10), 1710-1719. https://doi.org/10.1002/pc.22574
Stojanović D, Orlović A, Zrilić M, Balać I, Tang CY, Uskoković P, Aleksić R. The Effects of Functionalization on the Thermal and Tribo-Mechanical Behaviors of Neat and Grafted Polyethylene Nanocomposites. in Polymer Composites. 2013;34(10):1710-1719. doi:10.1002/pc.22574 .
Stojanović, Dušica, Orlović, Aleksandar, Zrilić, Milorad, Balać, Igor, Tang, C. Y., Uskoković, Petar, Aleksić, Radoslav, "The Effects of Functionalization on the Thermal and Tribo-Mechanical Behaviors of Neat and Grafted Polyethylene Nanocomposites" in Polymer Composites, 34, no. 10 (2013):1710-1719, https://doi.org/10.1002/pc.22574 . .