Experimental measurement and modelling of viscosity of the binary systems pyridine or nicotine with polyethylene glycols at T = (288.15-333.15) K. New UNIFAC-VISCO and ASOG-VISCO interaction parameters
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2013
Authors
Majstorović, DivnaJovanović, Jovan
Živković, Emila
Višak, Zoran P.
Šerbanović, Slobodan P.
Kijevčanin, Mirjana
Article (Published version)
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Viscosities of four binary mixtures: pyridine + PEG200, pyridine + PEG400, nicotine + PEG200 and nicotine + PEG400 have been measured in temperature range 288.15-333.15 K with temperature step of 5 K and at the atmospheric pressure. Viscosity deviations and excess molar Gibbs energies of activation of viscous flow for the selected binary systems were calculated from the experimental data and fitted to the Redlich-Kister polynomial equation. In addition, UNIFAC-VISCO and ASOG-VISCO models were used to predict the dynamic viscosities of the investigated binary mixtures. The experimental values of viscosity for the investigated four binary systems were used to determine the new interaction parameters for their application in UNIFAC-VISCO and ASOG-VISCO models. The viscosity data have also been correlated by two parameters Teja-Rice and three and four parameters McAllister models.
Keywords:
Viscosities / Pyridine / Nicotine / Prediction and correlation / New UNIFAC-VISCO and ASOG-VISCO interaction parametersSource:
Fluid Phase Equilibria, 2013, 338, 282-293Publisher:
- Elsevier Science Bv, Amsterdam
Funding / projects:
- Research Fund of Ministry of Education and Science, Serbia
- New industrial and environmental application of chemical thermodynamics to the development of the chemical processes with multiphase and multicomponent systems (RS-172063)
- Fundacao para a Ciencia e a Tecnologia (FCT), PortugalPortuguese Foundation for Science and Technology [PTDC/EQU-EPR/103505/2008]
DOI: 10.1016/j.fluid.2012.11.021
ISSN: 0378-3812
WoS: 000314737000036
Scopus: 2-s2.0-84871682950
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Majstorović, Divna AU - Jovanović, Jovan AU - Živković, Emila AU - Višak, Zoran P. AU - Šerbanović, Slobodan P. AU - Kijevčanin, Mirjana PY - 2013 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2492 AB - Viscosities of four binary mixtures: pyridine + PEG200, pyridine + PEG400, nicotine + PEG200 and nicotine + PEG400 have been measured in temperature range 288.15-333.15 K with temperature step of 5 K and at the atmospheric pressure. Viscosity deviations and excess molar Gibbs energies of activation of viscous flow for the selected binary systems were calculated from the experimental data and fitted to the Redlich-Kister polynomial equation. In addition, UNIFAC-VISCO and ASOG-VISCO models were used to predict the dynamic viscosities of the investigated binary mixtures. The experimental values of viscosity for the investigated four binary systems were used to determine the new interaction parameters for their application in UNIFAC-VISCO and ASOG-VISCO models. The viscosity data have also been correlated by two parameters Teja-Rice and three and four parameters McAllister models. PB - Elsevier Science Bv, Amsterdam T2 - Fluid Phase Equilibria T1 - Experimental measurement and modelling of viscosity of the binary systems pyridine or nicotine with polyethylene glycols at T = (288.15-333.15) K. New UNIFAC-VISCO and ASOG-VISCO interaction parameters EP - 293 SP - 282 VL - 338 DO - 10.1016/j.fluid.2012.11.021 ER -
@article{ author = "Majstorović, Divna and Jovanović, Jovan and Živković, Emila and Višak, Zoran P. and Šerbanović, Slobodan P. and Kijevčanin, Mirjana", year = "2013", abstract = "Viscosities of four binary mixtures: pyridine + PEG200, pyridine + PEG400, nicotine + PEG200 and nicotine + PEG400 have been measured in temperature range 288.15-333.15 K with temperature step of 5 K and at the atmospheric pressure. Viscosity deviations and excess molar Gibbs energies of activation of viscous flow for the selected binary systems were calculated from the experimental data and fitted to the Redlich-Kister polynomial equation. In addition, UNIFAC-VISCO and ASOG-VISCO models were used to predict the dynamic viscosities of the investigated binary mixtures. The experimental values of viscosity for the investigated four binary systems were used to determine the new interaction parameters for their application in UNIFAC-VISCO and ASOG-VISCO models. The viscosity data have also been correlated by two parameters Teja-Rice and three and four parameters McAllister models.", publisher = "Elsevier Science Bv, Amsterdam", journal = "Fluid Phase Equilibria", title = "Experimental measurement and modelling of viscosity of the binary systems pyridine or nicotine with polyethylene glycols at T = (288.15-333.15) K. New UNIFAC-VISCO and ASOG-VISCO interaction parameters", pages = "293-282", volume = "338", doi = "10.1016/j.fluid.2012.11.021" }
Majstorović, D., Jovanović, J., Živković, E., Višak, Z. P., Šerbanović, S. P.,& Kijevčanin, M.. (2013). Experimental measurement and modelling of viscosity of the binary systems pyridine or nicotine with polyethylene glycols at T = (288.15-333.15) K. New UNIFAC-VISCO and ASOG-VISCO interaction parameters. in Fluid Phase Equilibria Elsevier Science Bv, Amsterdam., 338, 282-293. https://doi.org/10.1016/j.fluid.2012.11.021
Majstorović D, Jovanović J, Živković E, Višak ZP, Šerbanović SP, Kijevčanin M. Experimental measurement and modelling of viscosity of the binary systems pyridine or nicotine with polyethylene glycols at T = (288.15-333.15) K. New UNIFAC-VISCO and ASOG-VISCO interaction parameters. in Fluid Phase Equilibria. 2013;338:282-293. doi:10.1016/j.fluid.2012.11.021 .
Majstorović, Divna, Jovanović, Jovan, Živković, Emila, Višak, Zoran P., Šerbanović, Slobodan P., Kijevčanin, Mirjana, "Experimental measurement and modelling of viscosity of the binary systems pyridine or nicotine with polyethylene glycols at T = (288.15-333.15) K. New UNIFAC-VISCO and ASOG-VISCO interaction parameters" in Fluid Phase Equilibria, 338 (2013):282-293, https://doi.org/10.1016/j.fluid.2012.11.021 . .