Investigation of enhanced CO tolerance in proton exchange membrane fuel cells by carbon supported PtMo alloy catalyst
Само за регистроване кориснике
1999
Аутори
Mukerjee, SLee, SJ
Ticianelli, EA
McBreen, J
Grgur, Branimir
Marković, NM
Ross, PN
Giallombardo, JR
De Castro, ES
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
We report a two- to threefold enhancement of CO tolerance in a proton exchange membrane (PEM) fuel cell, exhibited by carbon supported nanocrystalline PtMo/C as compared to the current state of the art PtRu/C electrocatalysts. The bulk of these nanocrystals were comprised of Pt alloyed with Mo in the ratio 8.7: 1.3 as shown by both X-ray diffraction and in situ extended X-ray absorption fine structure measurements. Rotating disk electrode measurements and cyclic voltammetry in a PEM fuel cell indicate the onset of CO oxidation at potentials as low as 0.1 V. Further, the oxidation of CO exhibits two distinct peaks, indicating redox behavior involving oxyhydroxides of Mo. This is supported by in situ X-ray absorption near edge structure measurements at the Mo K edge.
Извор:
Electrochemical and Solid State Letters, 1999, 2, 1, 12-15Издавач:
- Electrochemical Soc Inc, Pennington
DOI: 10.1149/1.1390718
ISSN: 1099-0062
WoS: 000079697000005
Scopus: 2-s2.0-0032714850
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Mukerjee, S AU - Lee, SJ AU - Ticianelli, EA AU - McBreen, J AU - Grgur, Branimir AU - Marković, NM AU - Ross, PN AU - Giallombardo, JR AU - De Castro, ES PY - 1999 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/250 AB - We report a two- to threefold enhancement of CO tolerance in a proton exchange membrane (PEM) fuel cell, exhibited by carbon supported nanocrystalline PtMo/C as compared to the current state of the art PtRu/C electrocatalysts. The bulk of these nanocrystals were comprised of Pt alloyed with Mo in the ratio 8.7: 1.3 as shown by both X-ray diffraction and in situ extended X-ray absorption fine structure measurements. Rotating disk electrode measurements and cyclic voltammetry in a PEM fuel cell indicate the onset of CO oxidation at potentials as low as 0.1 V. Further, the oxidation of CO exhibits two distinct peaks, indicating redox behavior involving oxyhydroxides of Mo. This is supported by in situ X-ray absorption near edge structure measurements at the Mo K edge. PB - Electrochemical Soc Inc, Pennington T2 - Electrochemical and Solid State Letters T1 - Investigation of enhanced CO tolerance in proton exchange membrane fuel cells by carbon supported PtMo alloy catalyst EP - 15 IS - 1 SP - 12 VL - 2 DO - 10.1149/1.1390718 ER -
@article{ author = "Mukerjee, S and Lee, SJ and Ticianelli, EA and McBreen, J and Grgur, Branimir and Marković, NM and Ross, PN and Giallombardo, JR and De Castro, ES", year = "1999", abstract = "We report a two- to threefold enhancement of CO tolerance in a proton exchange membrane (PEM) fuel cell, exhibited by carbon supported nanocrystalline PtMo/C as compared to the current state of the art PtRu/C electrocatalysts. The bulk of these nanocrystals were comprised of Pt alloyed with Mo in the ratio 8.7: 1.3 as shown by both X-ray diffraction and in situ extended X-ray absorption fine structure measurements. Rotating disk electrode measurements and cyclic voltammetry in a PEM fuel cell indicate the onset of CO oxidation at potentials as low as 0.1 V. Further, the oxidation of CO exhibits two distinct peaks, indicating redox behavior involving oxyhydroxides of Mo. This is supported by in situ X-ray absorption near edge structure measurements at the Mo K edge.", publisher = "Electrochemical Soc Inc, Pennington", journal = "Electrochemical and Solid State Letters", title = "Investigation of enhanced CO tolerance in proton exchange membrane fuel cells by carbon supported PtMo alloy catalyst", pages = "15-12", number = "1", volume = "2", doi = "10.1149/1.1390718" }
Mukerjee, S., Lee, S., Ticianelli, E., McBreen, J., Grgur, B., Marković, N., Ross, P., Giallombardo, J.,& De Castro, E.. (1999). Investigation of enhanced CO tolerance in proton exchange membrane fuel cells by carbon supported PtMo alloy catalyst. in Electrochemical and Solid State Letters Electrochemical Soc Inc, Pennington., 2(1), 12-15. https://doi.org/10.1149/1.1390718
Mukerjee S, Lee S, Ticianelli E, McBreen J, Grgur B, Marković N, Ross P, Giallombardo J, De Castro E. Investigation of enhanced CO tolerance in proton exchange membrane fuel cells by carbon supported PtMo alloy catalyst. in Electrochemical and Solid State Letters. 1999;2(1):12-15. doi:10.1149/1.1390718 .
Mukerjee, S, Lee, SJ, Ticianelli, EA, McBreen, J, Grgur, Branimir, Marković, NM, Ross, PN, Giallombardo, JR, De Castro, ES, "Investigation of enhanced CO tolerance in proton exchange membrane fuel cells by carbon supported PtMo alloy catalyst" in Electrochemical and Solid State Letters, 2, no. 1 (1999):12-15, https://doi.org/10.1149/1.1390718 . .