Aluminum was incorporated into a polycrystalline cadmium electrode surface by underpotential deposition from equimolar AlCl3+ NaCl melt at 473 K, 523 K, and 573 K (200 A degrees C, 250 A degrees C, and 300 A degrees C). The process was studied by linear sweep voltammetry and potentiostatic deposition/galvanostatic striping. The deposits were characterized X-ray diffraction (XRD), Auger electron spectroscopy (AES), and electron probe microanalyzer (EPMA). The electrochemical measurements showed evidence of Cd-Al alloys being formed but they could not be identified. The growth kinetics of the Cd-Al layers of various proportion and depths that depended on temperature and deposition time were described.
Source:
Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science, 2013, 44, 1, 106-114
TY - JOUR
AU - Jovicević, Niko
AU - Cvetković, Vesna S.
AU - Kamberović, Željko
AU - Jovicević, Jovan N.
PY - 2013
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2520
AB - Aluminum was incorporated into a polycrystalline cadmium electrode surface by underpotential deposition from equimolar AlCl3+ NaCl melt at 473 K, 523 K, and 573 K (200 A degrees C, 250 A degrees C, and 300 A degrees C). The process was studied by linear sweep voltammetry and potentiostatic deposition/galvanostatic striping. The deposits were characterized X-ray diffraction (XRD), Auger electron spectroscopy (AES), and electron probe microanalyzer (EPMA). The electrochemical measurements showed evidence of Cd-Al alloys being formed but they could not be identified. The growth kinetics of the Cd-Al layers of various proportion and depths that depended on temperature and deposition time were described.
PB - Springer, New York
T2 - Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science
T1 - Al-Cd Alloy Formation by Aluminum Underpotential Deposition from AlCl3+NaCl Melts on Cadmium Substrate
EP - 114
IS - 1
SP - 106
VL - 44
DO - 10.1007/s11663-012-9750-3
ER -
@article{
author = "Jovicević, Niko and Cvetković, Vesna S. and Kamberović, Željko and Jovicević, Jovan N.",
year = "2013",
abstract = "Aluminum was incorporated into a polycrystalline cadmium electrode surface by underpotential deposition from equimolar AlCl3+ NaCl melt at 473 K, 523 K, and 573 K (200 A degrees C, 250 A degrees C, and 300 A degrees C). The process was studied by linear sweep voltammetry and potentiostatic deposition/galvanostatic striping. The deposits were characterized X-ray diffraction (XRD), Auger electron spectroscopy (AES), and electron probe microanalyzer (EPMA). The electrochemical measurements showed evidence of Cd-Al alloys being formed but they could not be identified. The growth kinetics of the Cd-Al layers of various proportion and depths that depended on temperature and deposition time were described.",
publisher = "Springer, New York",
journal = "Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science",
title = "Al-Cd Alloy Formation by Aluminum Underpotential Deposition from AlCl3+NaCl Melts on Cadmium Substrate",
pages = "114-106",
number = "1",
volume = "44",
doi = "10.1007/s11663-012-9750-3"
}
Jovicević, N., Cvetković, V. S., Kamberović, Ž.,& Jovicević, J. N.. (2013). Al-Cd Alloy Formation by Aluminum Underpotential Deposition from AlCl3+NaCl Melts on Cadmium Substrate. in Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science
Springer, New York., 44(1), 106-114.
https://doi.org/10.1007/s11663-012-9750-3
Jovicević N, Cvetković VS, Kamberović Ž, Jovicević JN. Al-Cd Alloy Formation by Aluminum Underpotential Deposition from AlCl3+NaCl Melts on Cadmium Substrate. in Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science. 2013;44(1):106-114.
doi:10.1007/s11663-012-9750-3 .
Jovicević, Niko, Cvetković, Vesna S., Kamberović, Željko, Jovicević, Jovan N., "Al-Cd Alloy Formation by Aluminum Underpotential Deposition from AlCl3+NaCl Melts on Cadmium Substrate" in Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science, 44, no. 1 (2013):106-114,
https://doi.org/10.1007/s11663-012-9750-3 . .
