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Effects of the concentrated NH4NO3 solution on mechanical properties and structure of the fly ash based geopolymers

Authorized Users Only
2013
Authors
Baščarević, Zvezdana
Komljenović, Miroslav
Miladinović, Zoran P.
Nikolić, Violeta
Marjanović, Nataša
Zujović, Zoran
Petrović, Rada
Article (Published version)
Metadata
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Abstract
The geopolymers based on fly ash were exposed to the concentrated (6 M) NH4NO3 solution for 540 days. The highest compressive strength decrease occurred in the initial 28 days testing period. Study of the effects of the NH4NO3 solution on the geopolymer structure indicated leaching of alkali and alkaline earth cations and breaking of -Si-O-Al- bonds in aluminosilicate gel. The reduction of compressive strength of the geopolymers was associated with the structural defects in the aluminosilicate gel created by breaking of -Si-O-Al- bonds. Subsequent fluctuation in compressive strength was a result of the structural defects reparation by silicon.
Keywords:
Geopolymer / Durability / NH4NO3 / Leaching / Dealumination
Source:
Construction and Building Materials, 2013, 41, 570-579
Publisher:
  • Elsevier Sci Ltd, Oxford
Funding / projects:
  • Geopolymers - technology for converting the industrial waste into functional materials (RS-34026)

DOI: 10.1016/j.conbuildmat.2012.12.067

ISSN: 0950-0618

WoS: 000317528900064

Scopus: 2-s2.0-84873881682
[ Google Scholar ]
51
42
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2521
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Baščarević, Zvezdana
AU  - Komljenović, Miroslav
AU  - Miladinović, Zoran P.
AU  - Nikolić, Violeta
AU  - Marjanović, Nataša
AU  - Zujović, Zoran
AU  - Petrović, Rada
PY  - 2013
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2521
AB  - The geopolymers based on fly ash were exposed to the concentrated (6 M) NH4NO3 solution for 540 days. The highest compressive strength decrease occurred in the initial 28 days testing period. Study of the effects of the NH4NO3 solution on the geopolymer structure indicated leaching of alkali and alkaline earth cations and breaking of -Si-O-Al- bonds in aluminosilicate gel. The reduction of compressive strength of the geopolymers was associated with the structural defects in the aluminosilicate gel created by breaking of -Si-O-Al- bonds. Subsequent fluctuation in compressive strength was a result of the structural defects reparation by silicon.
PB  - Elsevier Sci Ltd, Oxford
T2  - Construction and Building Materials
T1  - Effects of the concentrated NH4NO3 solution on mechanical properties and structure of the fly ash based geopolymers
EP  - 579
SP  - 570
VL  - 41
DO  - 10.1016/j.conbuildmat.2012.12.067
ER  - 
@article{
author = "Baščarević, Zvezdana and Komljenović, Miroslav and Miladinović, Zoran P. and Nikolić, Violeta and Marjanović, Nataša and Zujović, Zoran and Petrović, Rada",
year = "2013",
abstract = "The geopolymers based on fly ash were exposed to the concentrated (6 M) NH4NO3 solution for 540 days. The highest compressive strength decrease occurred in the initial 28 days testing period. Study of the effects of the NH4NO3 solution on the geopolymer structure indicated leaching of alkali and alkaline earth cations and breaking of -Si-O-Al- bonds in aluminosilicate gel. The reduction of compressive strength of the geopolymers was associated with the structural defects in the aluminosilicate gel created by breaking of -Si-O-Al- bonds. Subsequent fluctuation in compressive strength was a result of the structural defects reparation by silicon.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Construction and Building Materials",
title = "Effects of the concentrated NH4NO3 solution on mechanical properties and structure of the fly ash based geopolymers",
pages = "579-570",
volume = "41",
doi = "10.1016/j.conbuildmat.2012.12.067"
}
Baščarević, Z., Komljenović, M., Miladinović, Z. P., Nikolić, V., Marjanović, N., Zujović, Z.,& Petrović, R.. (2013). Effects of the concentrated NH4NO3 solution on mechanical properties and structure of the fly ash based geopolymers. in Construction and Building Materials
Elsevier Sci Ltd, Oxford., 41, 570-579.
https://doi.org/10.1016/j.conbuildmat.2012.12.067
Baščarević Z, Komljenović M, Miladinović ZP, Nikolić V, Marjanović N, Zujović Z, Petrović R. Effects of the concentrated NH4NO3 solution on mechanical properties and structure of the fly ash based geopolymers. in Construction and Building Materials. 2013;41:570-579.
doi:10.1016/j.conbuildmat.2012.12.067 .
Baščarević, Zvezdana, Komljenović, Miroslav, Miladinović, Zoran P., Nikolić, Violeta, Marjanović, Nataša, Zujović, Zoran, Petrović, Rada, "Effects of the concentrated NH4NO3 solution on mechanical properties and structure of the fly ash based geopolymers" in Construction and Building Materials, 41 (2013):570-579,
https://doi.org/10.1016/j.conbuildmat.2012.12.067 . .

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