Corrosion Evaluation of Zirconium Doped Oxide Coatings on Aluminum Formed by Plasma Electrolytic Oxidation
Abstract
The plasma electrolytic oxidation (PEO) of aluminum in sodium tungstate (Na2WO4 center dot 2H(2)O) and Na2WO4 center dot 2H(2)O doped with Zr was analyzed in order to obtain oxide coatings with improved corrosion resistance. The influence of current density in PEO process and anodization time was investigated, as well as the influence of Zr, with the aim to find out how they affect the chemical content, morphology, surface roughness, and corrosion stability of oxide coatings. It was shown that the presence of Zr increases the corrosion stability of oxide coatings for all investigated PEO times. Evolution of EIS spectra during the exposure to 3% NaCl, as a strong corrosive agent, indicated the highest corrosion stability for PEO coating formed on aluminum at 70 mA/cm(2) for 2 min in a zirconium containing electrolyte.
Keywords:
Aluminum / Plasma electrolytic oxidation / Oxide coatings / Zr / EIS / CorrosionSource:
Acta Chimica Slovenica, 2014, 61, 2, 308-315Publisher:
- Slovenian Chemical Society
Funding / projects:
- Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45019)
- Graphitic and Inorganic Low-dimensional Nanostructures (RS-MESTD-Basic Research (BR or ON)-171035)
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Bajat, Jelena AU - Mišković-Stanković, Vesna AU - Vasilić, Rastko AU - Stojadinović, Stevan PY - 2014 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2558 AB - The plasma electrolytic oxidation (PEO) of aluminum in sodium tungstate (Na2WO4 center dot 2H(2)O) and Na2WO4 center dot 2H(2)O doped with Zr was analyzed in order to obtain oxide coatings with improved corrosion resistance. The influence of current density in PEO process and anodization time was investigated, as well as the influence of Zr, with the aim to find out how they affect the chemical content, morphology, surface roughness, and corrosion stability of oxide coatings. It was shown that the presence of Zr increases the corrosion stability of oxide coatings for all investigated PEO times. Evolution of EIS spectra during the exposure to 3% NaCl, as a strong corrosive agent, indicated the highest corrosion stability for PEO coating formed on aluminum at 70 mA/cm(2) for 2 min in a zirconium containing electrolyte. PB - Slovenian Chemical Society T2 - Acta Chimica Slovenica T1 - Corrosion Evaluation of Zirconium Doped Oxide Coatings on Aluminum Formed by Plasma Electrolytic Oxidation EP - 315 IS - 2 SP - 308 VL - 61 UR - https://hdl.handle.net/21.15107/rcub_technorep_2558 ER -
@article{ author = "Bajat, Jelena and Mišković-Stanković, Vesna and Vasilić, Rastko and Stojadinović, Stevan", year = "2014", abstract = "The plasma electrolytic oxidation (PEO) of aluminum in sodium tungstate (Na2WO4 center dot 2H(2)O) and Na2WO4 center dot 2H(2)O doped with Zr was analyzed in order to obtain oxide coatings with improved corrosion resistance. The influence of current density in PEO process and anodization time was investigated, as well as the influence of Zr, with the aim to find out how they affect the chemical content, morphology, surface roughness, and corrosion stability of oxide coatings. It was shown that the presence of Zr increases the corrosion stability of oxide coatings for all investigated PEO times. Evolution of EIS spectra during the exposure to 3% NaCl, as a strong corrosive agent, indicated the highest corrosion stability for PEO coating formed on aluminum at 70 mA/cm(2) for 2 min in a zirconium containing electrolyte.", publisher = "Slovenian Chemical Society", journal = "Acta Chimica Slovenica", title = "Corrosion Evaluation of Zirconium Doped Oxide Coatings on Aluminum Formed by Plasma Electrolytic Oxidation", pages = "315-308", number = "2", volume = "61", url = "https://hdl.handle.net/21.15107/rcub_technorep_2558" }
Bajat, J., Mišković-Stanković, V., Vasilić, R.,& Stojadinović, S.. (2014). Corrosion Evaluation of Zirconium Doped Oxide Coatings on Aluminum Formed by Plasma Electrolytic Oxidation. in Acta Chimica Slovenica Slovenian Chemical Society., 61(2), 308-315. https://hdl.handle.net/21.15107/rcub_technorep_2558
Bajat J, Mišković-Stanković V, Vasilić R, Stojadinović S. Corrosion Evaluation of Zirconium Doped Oxide Coatings on Aluminum Formed by Plasma Electrolytic Oxidation. in Acta Chimica Slovenica. 2014;61(2):308-315. https://hdl.handle.net/21.15107/rcub_technorep_2558 .
Bajat, Jelena, Mišković-Stanković, Vesna, Vasilić, Rastko, Stojadinović, Stevan, "Corrosion Evaluation of Zirconium Doped Oxide Coatings on Aluminum Formed by Plasma Electrolytic Oxidation" in Acta Chimica Slovenica, 61, no. 2 (2014):308-315, https://hdl.handle.net/21.15107/rcub_technorep_2558 .