Приказ основних података о документу

dc.creatorZdravković, Jelena D.
dc.creatorPoleti, Dejan
dc.creatorRogan, Jelena
dc.creatorMinić, Dragica M.
dc.date.accessioned2021-03-10T12:24:09Z
dc.date.available2021-03-10T12:24:09Z
dc.date.issued2014
dc.identifier.issn0277-5387
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/2660
dc.description.abstractCrystal structure of the title compound: [Cu-2(bipy)(2)(pht)(2)]center dot 4H(2)O (bipy = 2,2'-bipyridine, pht = dianion of phthalic acid), CuBP center dot 4H(2)O, consists of dinuclear entities, which are further connected by pi-pi stacking interactions between bipy ligands. In this way small channels (micropores) oriented parallel to the [001] direction and containing loosely hydrogen bonded water molecules are formed. The structural changes during dehydration-rehydration have been thoroughly investigated using TG/DSC analysis, FT-IR spectroscopy, X-ray powder diffraction, optical and scanning electron microscopy, and sorption experiments. In addition, dehydration process was analyzed from the aspect of kinetics. A complete reversibility of the dehydration-rehydration CuBP center dot 4H(2)O(s) reversible arrow CuBP(s) + 4H(2)O(g) process was confirmed by all means. Therefore, CuBP center dot 4H(2)O can be classified as molecular sieve with quite unexpected zero-dimensional structure.en
dc.publisherPergamon-Elsevier Science Ltd, Oxford
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45007/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172015/RS//
dc.rightsrestrictedAccess
dc.sourcePolyhedron
dc.subjectCu(II) complexen
dc.subjectPhthalate ionen
dc.subjectCrystal structureen
dc.subjectReversible dehydrationen
dc.subjectMolecular sieveen
dc.titleBis(2,2 '-bipyridine)-bis(mu(3)-phthalato)-dicopper(II) tetrahydrate as molecular sieve with zero-dimensional structureen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage264
dc.citation.other80: 256-264
dc.citation.rankM22
dc.citation.spage256
dc.citation.volume80
dc.identifier.doi10.1016/j.poly.2014.05.026
dc.identifier.scopus2-s2.0-84905512902
dc.identifier.wos000341348300034
dc.type.versionpublishedVersion


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Приказ основних података о документу