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ZnO/Ag hybrid nanocubes in alginate biopolymer: Synthesis and properties

Authorized Users Only
2014
Authors
Trandafilović, Lidija V.
Krsmanović, Radenka
Dimitrijević-Branković, Suzana
Stoiljković, Milovan
Luyt, Adriaan S.
Đoković, Vladimir
Article (Published version)
Metadata
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Abstract
A procedure for the preparation of ZnO nanocubes in an alginate biopolymer was introduced. The obtained nanocubes were used for the preparation of ZnO/Ag heterostructures. High resolution scanning electron microscopy showed that reduction of silver salts in the presence of nanocubes results in the formation of spherical silver nanoparticles at their edges and vertices. UV-vis and photoluminescence spectroscopy revealed that alginate-ZnO/Ag nanostructures exhibit different optical properties compared to the starting alginate-ZnO system. The surface plasmon resonance peak of the silver nanoparticles dominates the absorption spectra of the ZnO/Ag hybrid particles, while at the same time the Ag nanoparticles quench the ZnO emission. The photocatalytic activity of the ZnO/Ag heterostructure was faster than that of the pure ZnO and further improved with increasing the concentration of silver. Both the alginate-ZnO and alginate-ZnO/Ag nanocomposites showed strong antimicrobial activities agai...nst gram-positive (Staphylococcus aureus) and gram-negative (Escherichia coli) bacteria.

Keywords:
Biopolymer / Nanocubes / ZnO / Heterostructures / Photocatalysis / Antimicrobial
Source:
Chemical Engineering Journal, 2014, 253, 341-349
Publisher:
  • Elsevier Science Sa, Lausanne
Funding / projects:
  • Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites (RS-172056)
  • Materials of Reduced Dimensions for Efficient Light Harvesting and Energy conversion (RS-45020)

DOI: 10.1016/j.cej.2014.05.056

ISSN: 1385-8947

WoS: 000340213600041

Scopus: 2-s2.0-84901999872
[ Google Scholar ]
33
29
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2663
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Trandafilović, Lidija V.
AU  - Krsmanović, Radenka
AU  - Dimitrijević-Branković, Suzana
AU  - Stoiljković, Milovan
AU  - Luyt, Adriaan S.
AU  - Đoković, Vladimir
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2663
AB  - A procedure for the preparation of ZnO nanocubes in an alginate biopolymer was introduced. The obtained nanocubes were used for the preparation of ZnO/Ag heterostructures. High resolution scanning electron microscopy showed that reduction of silver salts in the presence of nanocubes results in the formation of spherical silver nanoparticles at their edges and vertices. UV-vis and photoluminescence spectroscopy revealed that alginate-ZnO/Ag nanostructures exhibit different optical properties compared to the starting alginate-ZnO system. The surface plasmon resonance peak of the silver nanoparticles dominates the absorption spectra of the ZnO/Ag hybrid particles, while at the same time the Ag nanoparticles quench the ZnO emission. The photocatalytic activity of the ZnO/Ag heterostructure was faster than that of the pure ZnO and further improved with increasing the concentration of silver. Both the alginate-ZnO and alginate-ZnO/Ag nanocomposites showed strong antimicrobial activities against gram-positive (Staphylococcus aureus) and gram-negative (Escherichia coli) bacteria.
PB  - Elsevier Science Sa, Lausanne
T2  - Chemical Engineering Journal
T1  - ZnO/Ag hybrid nanocubes in alginate biopolymer: Synthesis and properties
EP  - 349
SP  - 341
VL  - 253
DO  - 10.1016/j.cej.2014.05.056
ER  - 
@article{
author = "Trandafilović, Lidija V. and Krsmanović, Radenka and Dimitrijević-Branković, Suzana and Stoiljković, Milovan and Luyt, Adriaan S. and Đoković, Vladimir",
year = "2014",
abstract = "A procedure for the preparation of ZnO nanocubes in an alginate biopolymer was introduced. The obtained nanocubes were used for the preparation of ZnO/Ag heterostructures. High resolution scanning electron microscopy showed that reduction of silver salts in the presence of nanocubes results in the formation of spherical silver nanoparticles at their edges and vertices. UV-vis and photoluminescence spectroscopy revealed that alginate-ZnO/Ag nanostructures exhibit different optical properties compared to the starting alginate-ZnO system. The surface plasmon resonance peak of the silver nanoparticles dominates the absorption spectra of the ZnO/Ag hybrid particles, while at the same time the Ag nanoparticles quench the ZnO emission. The photocatalytic activity of the ZnO/Ag heterostructure was faster than that of the pure ZnO and further improved with increasing the concentration of silver. Both the alginate-ZnO and alginate-ZnO/Ag nanocomposites showed strong antimicrobial activities against gram-positive (Staphylococcus aureus) and gram-negative (Escherichia coli) bacteria.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Chemical Engineering Journal",
title = "ZnO/Ag hybrid nanocubes in alginate biopolymer: Synthesis and properties",
pages = "349-341",
volume = "253",
doi = "10.1016/j.cej.2014.05.056"
}
Trandafilović, L. V., Krsmanović, R., Dimitrijević-Branković, S., Stoiljković, M., Luyt, A. S.,& Đoković, V.. (2014). ZnO/Ag hybrid nanocubes in alginate biopolymer: Synthesis and properties. in Chemical Engineering Journal
Elsevier Science Sa, Lausanne., 253, 341-349.
https://doi.org/10.1016/j.cej.2014.05.056
Trandafilović LV, Krsmanović R, Dimitrijević-Branković S, Stoiljković M, Luyt AS, Đoković V. ZnO/Ag hybrid nanocubes in alginate biopolymer: Synthesis and properties. in Chemical Engineering Journal. 2014;253:341-349.
doi:10.1016/j.cej.2014.05.056 .
Trandafilović, Lidija V., Krsmanović, Radenka, Dimitrijević-Branković, Suzana, Stoiljković, Milovan, Luyt, Adriaan S., Đoković, Vladimir, "ZnO/Ag hybrid nanocubes in alginate biopolymer: Synthesis and properties" in Chemical Engineering Journal, 253 (2014):341-349,
https://doi.org/10.1016/j.cej.2014.05.056 . .

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