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Effect of Electrodeposition Current Density on the Microstructure and Magnetic Properties of Nickel-cobalt-molybdenum Alloy Powders

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2014
0350-820X1401117P.pdf (569.1Kb)
Authors
Pesić, O.
Spasojević, M.
Jordović, Branka
Spasojević, Pavle
Maricić, A.
Article (Published version)
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Abstract
Nanostructured nickel-cobalt-molybdenum alloy powders were electrodeposited from an ammonium sulfate bath. The powders mostly consist of an amorphous phase and a very small amount of nanocrystals with an mean size of less than 3 nm. An increase in deposition current density increases the amorphous phase percentage, the density of chaotically distributed dislocations and internal microstrains in the powders, while decreasing the mean nanocrystal size. The temperature range over which the structural relaxation of the powders deposited at higher current densities occurs is shifted towards lower temperatures. A change in relative magnetic permeability during structural relaxation is higher in powders deposited at higher current densities. Powder crystallization takes place at temperatures above 700 degrees C. The formation of the stable crystal structure causes a decrease in relative magnetic permeability.
Keywords:
X-ray diffraction / Nanostructured materials / Dislocations / Magnetic permeability / Powder
Source:
Science of Sintering, 2014, 46, 1, 117-127
Publisher:
  • Međunarodni Institut za nauku o sinterovanju, Beograd
Funding / projects:
  • Directed synthesis, structure and properties of multifunctional materials (RS-172057)

DOI: 10.2298/SOS1401117P

ISSN: 0350-820X

WoS: 000339449400011

Scopus: 2-s2.0-84899682147
[ Google Scholar ]
4
4
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2684
Collections
  • Radovi istraživača (Inovacioni centar) / Researchers’ publications (Innovation Centre)
Institution/Community
Inovacioni centar
TY  - JOUR
AU  - Pesić, O.
AU  - Spasojević, M.
AU  - Jordović, Branka
AU  - Spasojević, Pavle
AU  - Maricić, A.
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2684
AB  - Nanostructured nickel-cobalt-molybdenum alloy powders were electrodeposited from an ammonium sulfate bath. The powders mostly consist of an amorphous phase and a very small amount of nanocrystals with an mean size of less than 3 nm. An increase in deposition current density increases the amorphous phase percentage, the density of chaotically distributed dislocations and internal microstrains in the powders, while decreasing the mean nanocrystal size. The temperature range over which the structural relaxation of the powders deposited at higher current densities occurs is shifted towards lower temperatures. A change in relative magnetic permeability during structural relaxation is higher in powders deposited at higher current densities. Powder crystallization takes place at temperatures above 700 degrees C. The formation of the stable crystal structure causes a decrease in relative magnetic permeability.
PB  - Međunarodni Institut za nauku o sinterovanju, Beograd
T2  - Science of Sintering
T1  - Effect of Electrodeposition Current Density on the Microstructure and Magnetic Properties of Nickel-cobalt-molybdenum Alloy Powders
EP  - 127
IS  - 1
SP  - 117
VL  - 46
DO  - 10.2298/SOS1401117P
ER  - 
@article{
author = "Pesić, O. and Spasojević, M. and Jordović, Branka and Spasojević, Pavle and Maricić, A.",
year = "2014",
abstract = "Nanostructured nickel-cobalt-molybdenum alloy powders were electrodeposited from an ammonium sulfate bath. The powders mostly consist of an amorphous phase and a very small amount of nanocrystals with an mean size of less than 3 nm. An increase in deposition current density increases the amorphous phase percentage, the density of chaotically distributed dislocations and internal microstrains in the powders, while decreasing the mean nanocrystal size. The temperature range over which the structural relaxation of the powders deposited at higher current densities occurs is shifted towards lower temperatures. A change in relative magnetic permeability during structural relaxation is higher in powders deposited at higher current densities. Powder crystallization takes place at temperatures above 700 degrees C. The formation of the stable crystal structure causes a decrease in relative magnetic permeability.",
publisher = "Međunarodni Institut za nauku o sinterovanju, Beograd",
journal = "Science of Sintering",
title = "Effect of Electrodeposition Current Density on the Microstructure and Magnetic Properties of Nickel-cobalt-molybdenum Alloy Powders",
pages = "127-117",
number = "1",
volume = "46",
doi = "10.2298/SOS1401117P"
}
Pesić, O., Spasojević, M., Jordović, B., Spasojević, P.,& Maricić, A.. (2014). Effect of Electrodeposition Current Density on the Microstructure and Magnetic Properties of Nickel-cobalt-molybdenum Alloy Powders. in Science of Sintering
Međunarodni Institut za nauku o sinterovanju, Beograd., 46(1), 117-127.
https://doi.org/10.2298/SOS1401117P
Pesić O, Spasojević M, Jordović B, Spasojević P, Maricić A. Effect of Electrodeposition Current Density on the Microstructure and Magnetic Properties of Nickel-cobalt-molybdenum Alloy Powders. in Science of Sintering. 2014;46(1):117-127.
doi:10.2298/SOS1401117P .
Pesić, O., Spasojević, M., Jordović, Branka, Spasojević, Pavle, Maricić, A., "Effect of Electrodeposition Current Density on the Microstructure and Magnetic Properties of Nickel-cobalt-molybdenum Alloy Powders" in Science of Sintering, 46, no. 1 (2014):117-127,
https://doi.org/10.2298/SOS1401117P . .

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