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Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams

Authorized Users Only
2014
Authors
Nikolić, Vesna
Kamberović, Željko
Anđić, Zoran
Korać, Marija
Sokić, Miroslav
Maksimović, Vesna
Article (Published version)
Metadata
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Abstract
A method of synthesizing Ni-based catalysts supported on alpha-Al2O3-based foams was developed. The foams were impregnated with aqueous solutions of metal chlorides under an air atmosphere using an aerosol route. Separate procedures involved calcination to form oxides and drying to obtain chlorides on the foam surface. The synthesized samples were subsequently reduced with hydrogen. With respect to the Ni/Al2O3 catalysts, the chloride reduction route enabled the formation of a Ni coating without agglomerates or cracks. Further research included catalyst modification by the addition of Pd, Cu, and Fe. The influences of the additives on the degree of reduction and on the low-temperature reduction effectiveness (533 and 633 K) were examined and compared for the catalysts obtained from oxides and chlorides. Greater degrees of reduction were achieved with chlorides, whereas Pd was the most effective modifier among those investigated. The reduction process was nearly complete at 533 K in the... sample that contained 0.1wt% Pd. A lower reduction temperature was utilized, and the calcination step was avoided, which may enhance the economical and technological aspects of the developed catalyst production method.

Keywords:
catalysts / nickel / ceramic foams / modification / aerosol process / catalytic properties
Source:
International Journal of Minerals Metallurgy and Materials, 2014, 21, 8, 806-812
Publisher:
  • Springer, New York
Funding / projects:
  • Innovative synergy of by-products, waste minimization and clean technologies in metallurgy (RS-34033)
  • Developing technological processes for nonstandard copper concentrates processing with the aim to decrease pollutants emission (RS-34023)

DOI: 10.1007/s12613-014-0974-x

ISSN: 1674-4799

WoS: 000340094800009

Scopus: 2-s2.0-84924243463
[ Google Scholar ]
6
6
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2685
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
  • Radovi istraživača (Inovacioni centar) / Researchers’ publications (Innovation Centre)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Nikolić, Vesna
AU  - Kamberović, Željko
AU  - Anđić, Zoran
AU  - Korać, Marija
AU  - Sokić, Miroslav
AU  - Maksimović, Vesna
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2685
AB  - A method of synthesizing Ni-based catalysts supported on alpha-Al2O3-based foams was developed. The foams were impregnated with aqueous solutions of metal chlorides under an air atmosphere using an aerosol route. Separate procedures involved calcination to form oxides and drying to obtain chlorides on the foam surface. The synthesized samples were subsequently reduced with hydrogen. With respect to the Ni/Al2O3 catalysts, the chloride reduction route enabled the formation of a Ni coating without agglomerates or cracks. Further research included catalyst modification by the addition of Pd, Cu, and Fe. The influences of the additives on the degree of reduction and on the low-temperature reduction effectiveness (533 and 633 K) were examined and compared for the catalysts obtained from oxides and chlorides. Greater degrees of reduction were achieved with chlorides, whereas Pd was the most effective modifier among those investigated. The reduction process was nearly complete at 533 K in the sample that contained 0.1wt% Pd. A lower reduction temperature was utilized, and the calcination step was avoided, which may enhance the economical and technological aspects of the developed catalyst production method.
PB  - Springer, New York
T2  - International Journal of Minerals Metallurgy and Materials
T1  - Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams
EP  - 812
IS  - 8
SP  - 806
VL  - 21
DO  - 10.1007/s12613-014-0974-x
ER  - 
@article{
author = "Nikolić, Vesna and Kamberović, Željko and Anđić, Zoran and Korać, Marija and Sokić, Miroslav and Maksimović, Vesna",
year = "2014",
abstract = "A method of synthesizing Ni-based catalysts supported on alpha-Al2O3-based foams was developed. The foams were impregnated with aqueous solutions of metal chlorides under an air atmosphere using an aerosol route. Separate procedures involved calcination to form oxides and drying to obtain chlorides on the foam surface. The synthesized samples were subsequently reduced with hydrogen. With respect to the Ni/Al2O3 catalysts, the chloride reduction route enabled the formation of a Ni coating without agglomerates or cracks. Further research included catalyst modification by the addition of Pd, Cu, and Fe. The influences of the additives on the degree of reduction and on the low-temperature reduction effectiveness (533 and 633 K) were examined and compared for the catalysts obtained from oxides and chlorides. Greater degrees of reduction were achieved with chlorides, whereas Pd was the most effective modifier among those investigated. The reduction process was nearly complete at 533 K in the sample that contained 0.1wt% Pd. A lower reduction temperature was utilized, and the calcination step was avoided, which may enhance the economical and technological aspects of the developed catalyst production method.",
publisher = "Springer, New York",
journal = "International Journal of Minerals Metallurgy and Materials",
title = "Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams",
pages = "812-806",
number = "8",
volume = "21",
doi = "10.1007/s12613-014-0974-x"
}
Nikolić, V., Kamberović, Ž., Anđić, Z., Korać, M., Sokić, M.,& Maksimović, V.. (2014). Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams. in International Journal of Minerals Metallurgy and Materials
Springer, New York., 21(8), 806-812.
https://doi.org/10.1007/s12613-014-0974-x
Nikolić V, Kamberović Ž, Anđić Z, Korać M, Sokić M, Maksimović V. Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams. in International Journal of Minerals Metallurgy and Materials. 2014;21(8):806-812.
doi:10.1007/s12613-014-0974-x .
Nikolić, Vesna, Kamberović, Željko, Anđić, Zoran, Korać, Marija, Sokić, Miroslav, Maksimović, Vesna, "Influences of synthesis methods and modifier addition on the properties of Ni-based catalysts supported on reticulated ceramic foams" in International Journal of Minerals Metallurgy and Materials, 21, no. 8 (2014):806-812,
https://doi.org/10.1007/s12613-014-0974-x . .

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