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FTIR investigation of solvent effects of N-methyl and N-tert-butyl benzamide

Authorized Users Only
2014
Authors
Jović, B.
Nikolić, A.
Petrović, Slobodan
Kordić, Branko
Đaković-Sekulić, Tatjana
Stojanović, N.
Article (Published version)
Metadata
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Abstract
Infrared spectroscopy studies of N-methyl benzamide and N-tert-butyl benzamide in 12 organic solvents were undretaken to investigate solvent-solute interactions. The wavenumbers of carbonyl stretching vibration nu(C=O) in different solvents were correlated with the solvent acceptor number (AN), the linear solvation energy relationships (LSER), Catalan solvent parameters (SA, SB and SPP) and Buckingham equation. For both studied amides significant correlation of the position of the carbonyl band with empirical parameters was obtained. Based on obtained results it was assumed that the amide self-association and the steric effects are most important factors that determine position of carbonyl groups band in the IR spectra.
Keywords:
N-methyl benzamide / N-tert-butylbenzamide / Solvent effect / solvent parameters
Source:
Journal of Structural Chemistry, 2014, 55, 8, 1616-1622
Publisher:
  • Maik Nauka/Interperiodica/Springer, New York
Funding / projects:
  • Study of the Synthesis, Structure and Activity of Natural and Synthetic Organic Compounds (RS-172013)

DOI: 10.1134/S0022476614080319

ISSN: 0022-4766

WoS: 000348920200024

Scopus: 2-s2.0-84921803838
[ Google Scholar ]
7
9
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2713
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Jović, B.
AU  - Nikolić, A.
AU  - Petrović, Slobodan
AU  - Kordić, Branko
AU  - Đaković-Sekulić, Tatjana
AU  - Stojanović, N.
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2713
AB  - Infrared spectroscopy studies of N-methyl benzamide and N-tert-butyl benzamide in 12 organic solvents were undretaken to investigate solvent-solute interactions. The wavenumbers of carbonyl stretching vibration nu(C=O) in different solvents were correlated with the solvent acceptor number (AN), the linear solvation energy relationships (LSER), Catalan solvent parameters (SA, SB and SPP) and Buckingham equation. For both studied amides significant correlation of the position of the carbonyl band with empirical parameters was obtained. Based on obtained results it was assumed that the amide self-association and the steric effects are most important factors that determine position of carbonyl groups band in the IR spectra.
PB  - Maik Nauka/Interperiodica/Springer, New York
T2  - Journal of Structural Chemistry
T1  - FTIR investigation of solvent effects of N-methyl and N-tert-butyl benzamide
EP  - 1622
IS  - 8
SP  - 1616
VL  - 55
DO  - 10.1134/S0022476614080319
ER  - 
@article{
author = "Jović, B. and Nikolić, A. and Petrović, Slobodan and Kordić, Branko and Đaković-Sekulić, Tatjana and Stojanović, N.",
year = "2014",
abstract = "Infrared spectroscopy studies of N-methyl benzamide and N-tert-butyl benzamide in 12 organic solvents were undretaken to investigate solvent-solute interactions. The wavenumbers of carbonyl stretching vibration nu(C=O) in different solvents were correlated with the solvent acceptor number (AN), the linear solvation energy relationships (LSER), Catalan solvent parameters (SA, SB and SPP) and Buckingham equation. For both studied amides significant correlation of the position of the carbonyl band with empirical parameters was obtained. Based on obtained results it was assumed that the amide self-association and the steric effects are most important factors that determine position of carbonyl groups band in the IR spectra.",
publisher = "Maik Nauka/Interperiodica/Springer, New York",
journal = "Journal of Structural Chemistry",
title = "FTIR investigation of solvent effects of N-methyl and N-tert-butyl benzamide",
pages = "1622-1616",
number = "8",
volume = "55",
doi = "10.1134/S0022476614080319"
}
Jović, B., Nikolić, A., Petrović, S., Kordić, B., Đaković-Sekulić, T.,& Stojanović, N.. (2014). FTIR investigation of solvent effects of N-methyl and N-tert-butyl benzamide. in Journal of Structural Chemistry
Maik Nauka/Interperiodica/Springer, New York., 55(8), 1616-1622.
https://doi.org/10.1134/S0022476614080319
Jović B, Nikolić A, Petrović S, Kordić B, Đaković-Sekulić T, Stojanović N. FTIR investigation of solvent effects of N-methyl and N-tert-butyl benzamide. in Journal of Structural Chemistry. 2014;55(8):1616-1622.
doi:10.1134/S0022476614080319 .
Jović, B., Nikolić, A., Petrović, Slobodan, Kordić, Branko, Đaković-Sekulić, Tatjana, Stojanović, N., "FTIR investigation of solvent effects of N-methyl and N-tert-butyl benzamide" in Journal of Structural Chemistry, 55, no. 8 (2014):1616-1622,
https://doi.org/10.1134/S0022476614080319 . .

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