FTIR investigation of solvent effects of N-methyl and N-tert-butyl benzamide
Samo za registrovane korisnike
2014
Autori
Jović, B.Nikolić, A.
Petrović, Slobodan
Kordić, Branko
Đaković-Sekulić, Tatjana
Stojanović, N.
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Infrared spectroscopy studies of N-methyl benzamide and N-tert-butyl benzamide in 12 organic solvents were undretaken to investigate solvent-solute interactions. The wavenumbers of carbonyl stretching vibration nu(C=O) in different solvents were correlated with the solvent acceptor number (AN), the linear solvation energy relationships (LSER), Catalan solvent parameters (SA, SB and SPP) and Buckingham equation. For both studied amides significant correlation of the position of the carbonyl band with empirical parameters was obtained. Based on obtained results it was assumed that the amide self-association and the steric effects are most important factors that determine position of carbonyl groups band in the IR spectra.
Ključne reči:
N-methyl benzamide / N-tert-butylbenzamide / Solvent effect / solvent parametersIzvor:
Journal of Structural Chemistry, 2014, 55, 8, 1616-1622Izdavač:
- Maik Nauka/Interperiodica/Springer, New York
Finansiranje / projekti:
- Proučavanje sinteze, strukture i aktivnosti organskih jedinjenja prirodnog i sintetskog porekla (RS-MESTD-Basic Research (BR or ON)-172013)
DOI: 10.1134/S0022476614080319
ISSN: 0022-4766
WoS: 000348920200024
Scopus: 2-s2.0-84921803838
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Jović, B. AU - Nikolić, A. AU - Petrović, Slobodan AU - Kordić, Branko AU - Đaković-Sekulić, Tatjana AU - Stojanović, N. PY - 2014 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2713 AB - Infrared spectroscopy studies of N-methyl benzamide and N-tert-butyl benzamide in 12 organic solvents were undretaken to investigate solvent-solute interactions. The wavenumbers of carbonyl stretching vibration nu(C=O) in different solvents were correlated with the solvent acceptor number (AN), the linear solvation energy relationships (LSER), Catalan solvent parameters (SA, SB and SPP) and Buckingham equation. For both studied amides significant correlation of the position of the carbonyl band with empirical parameters was obtained. Based on obtained results it was assumed that the amide self-association and the steric effects are most important factors that determine position of carbonyl groups band in the IR spectra. PB - Maik Nauka/Interperiodica/Springer, New York T2 - Journal of Structural Chemistry T1 - FTIR investigation of solvent effects of N-methyl and N-tert-butyl benzamide EP - 1622 IS - 8 SP - 1616 VL - 55 DO - 10.1134/S0022476614080319 ER -
@article{ author = "Jović, B. and Nikolić, A. and Petrović, Slobodan and Kordić, Branko and Đaković-Sekulić, Tatjana and Stojanović, N.", year = "2014", abstract = "Infrared spectroscopy studies of N-methyl benzamide and N-tert-butyl benzamide in 12 organic solvents were undretaken to investigate solvent-solute interactions. The wavenumbers of carbonyl stretching vibration nu(C=O) in different solvents were correlated with the solvent acceptor number (AN), the linear solvation energy relationships (LSER), Catalan solvent parameters (SA, SB and SPP) and Buckingham equation. For both studied amides significant correlation of the position of the carbonyl band with empirical parameters was obtained. Based on obtained results it was assumed that the amide self-association and the steric effects are most important factors that determine position of carbonyl groups band in the IR spectra.", publisher = "Maik Nauka/Interperiodica/Springer, New York", journal = "Journal of Structural Chemistry", title = "FTIR investigation of solvent effects of N-methyl and N-tert-butyl benzamide", pages = "1622-1616", number = "8", volume = "55", doi = "10.1134/S0022476614080319" }
Jović, B., Nikolić, A., Petrović, S., Kordić, B., Đaković-Sekulić, T.,& Stojanović, N.. (2014). FTIR investigation of solvent effects of N-methyl and N-tert-butyl benzamide. in Journal of Structural Chemistry Maik Nauka/Interperiodica/Springer, New York., 55(8), 1616-1622. https://doi.org/10.1134/S0022476614080319
Jović B, Nikolić A, Petrović S, Kordić B, Đaković-Sekulić T, Stojanović N. FTIR investigation of solvent effects of N-methyl and N-tert-butyl benzamide. in Journal of Structural Chemistry. 2014;55(8):1616-1622. doi:10.1134/S0022476614080319 .
Jović, B., Nikolić, A., Petrović, Slobodan, Kordić, Branko, Đaković-Sekulić, Tatjana, Stojanović, N., "FTIR investigation of solvent effects of N-methyl and N-tert-butyl benzamide" in Journal of Structural Chemistry, 55, no. 8 (2014):1616-1622, https://doi.org/10.1134/S0022476614080319 . .