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Photocatalytic efficiency of titania photocatalysts in saline waters

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2014
0352-51391400020A.pdf (559.4Kb)
Authors
Albrbar, Asma Juma
Bjelajac, Anđelika
Đokić, Veljko
Miladinović, Jelena
Janaćković, Đorđe
Petrović, Rada
Article (Published version)
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Abstract
The photocatalytic efficiency of a recently synthesized TiO2 powder, denoted P160, for the degradation of the Dye C.I. Reactive Orange 16 in natural and artificial seawater was investigated in comparison to its efficiency in deionized water and the efficiency of a standard TiO2 powder, Degusa P25. It was shown that the photocatalytic efficiency of P160 was slightly higher than that of P25, probably due to slightly higher specific surface area, higher pore volume and larger pores of the powder P160. The efficiency of both photocatalysts in natural and artificial seawater was significantly lower than in deionized water. The overall rate of dye degradation for both types of photocatalysts was slightly higher in artificial seawater than in natural seawater, which shows the influence of organic compounds naturally present in seawater on the photocatalysts activity. A saturation Langmuir-type relationship between the initial degradation rate and the initial dye concentration indicated that a...dsorption plays a role in the photocatalytic reaction. The photodegradation rate constant, k, which represents the maximum reaction rate, had similar values for P25 and P160 in all types of water due to the similar properties of the photocatalysts.

Keywords:
photocatalysis / titanium dioxide / dye degradation / seawater / Langmuir-Hinshelwood model
Source:
Journal of the Serbian Chemical Society, 2014, 79, 9, 1127-1140
Publisher:
  • Srpsko hemijsko društvo, Beograd
Funding / projects:
  • Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-45019)

DOI: 10.2298/JSC131114020A

ISSN: 0352-5139

WoS: 000342524500007

Scopus: 2-s2.0-84918538540
[ Google Scholar ]
7
7
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2730
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
  • Radovi istraživača (Inovacioni centar) / Researchers’ publications (Innovation Centre)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Albrbar, Asma Juma
AU  - Bjelajac, Anđelika
AU  - Đokić, Veljko
AU  - Miladinović, Jelena
AU  - Janaćković, Đorđe
AU  - Petrović, Rada
PY  - 2014
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2730
AB  - The photocatalytic efficiency of a recently synthesized TiO2 powder, denoted P160, for the degradation of the Dye C.I. Reactive Orange 16 in natural and artificial seawater was investigated in comparison to its efficiency in deionized water and the efficiency of a standard TiO2 powder, Degusa P25. It was shown that the photocatalytic efficiency of P160 was slightly higher than that of P25, probably due to slightly higher specific surface area, higher pore volume and larger pores of the powder P160. The efficiency of both photocatalysts in natural and artificial seawater was significantly lower than in deionized water. The overall rate of dye degradation for both types of photocatalysts was slightly higher in artificial seawater than in natural seawater, which shows the influence of organic compounds naturally present in seawater on the photocatalysts activity. A saturation Langmuir-type relationship between the initial degradation rate and the initial dye concentration indicated that adsorption plays a role in the photocatalytic reaction. The photodegradation rate constant, k, which represents the maximum reaction rate, had similar values for P25 and P160 in all types of water due to the similar properties of the photocatalysts.
PB  - Srpsko hemijsko društvo, Beograd
T2  - Journal of the Serbian Chemical Society
T1  - Photocatalytic efficiency of titania photocatalysts in saline waters
EP  - 1140
IS  - 9
SP  - 1127
VL  - 79
DO  - 10.2298/JSC131114020A
ER  - 
@article{
author = "Albrbar, Asma Juma and Bjelajac, Anđelika and Đokić, Veljko and Miladinović, Jelena and Janaćković, Đorđe and Petrović, Rada",
year = "2014",
abstract = "The photocatalytic efficiency of a recently synthesized TiO2 powder, denoted P160, for the degradation of the Dye C.I. Reactive Orange 16 in natural and artificial seawater was investigated in comparison to its efficiency in deionized water and the efficiency of a standard TiO2 powder, Degusa P25. It was shown that the photocatalytic efficiency of P160 was slightly higher than that of P25, probably due to slightly higher specific surface area, higher pore volume and larger pores of the powder P160. The efficiency of both photocatalysts in natural and artificial seawater was significantly lower than in deionized water. The overall rate of dye degradation for both types of photocatalysts was slightly higher in artificial seawater than in natural seawater, which shows the influence of organic compounds naturally present in seawater on the photocatalysts activity. A saturation Langmuir-type relationship between the initial degradation rate and the initial dye concentration indicated that adsorption plays a role in the photocatalytic reaction. The photodegradation rate constant, k, which represents the maximum reaction rate, had similar values for P25 and P160 in all types of water due to the similar properties of the photocatalysts.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Photocatalytic efficiency of titania photocatalysts in saline waters",
pages = "1140-1127",
number = "9",
volume = "79",
doi = "10.2298/JSC131114020A"
}
Albrbar, A. J., Bjelajac, A., Đokić, V., Miladinović, J., Janaćković, Đ.,& Petrović, R.. (2014). Photocatalytic efficiency of titania photocatalysts in saline waters. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 79(9), 1127-1140.
https://doi.org/10.2298/JSC131114020A
Albrbar AJ, Bjelajac A, Đokić V, Miladinović J, Janaćković Đ, Petrović R. Photocatalytic efficiency of titania photocatalysts in saline waters. in Journal of the Serbian Chemical Society. 2014;79(9):1127-1140.
doi:10.2298/JSC131114020A .
Albrbar, Asma Juma, Bjelajac, Anđelika, Đokić, Veljko, Miladinović, Jelena, Janaćković, Đorđe, Petrović, Rada, "Photocatalytic efficiency of titania photocatalysts in saline waters" in Journal of the Serbian Chemical Society, 79, no. 9 (2014):1127-1140,
https://doi.org/10.2298/JSC131114020A . .

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