Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K
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2014
Authors
Spasojević, Vuk D.Đorđević, Bojan D.
Šerbanović, Slobodan P.
Radović, Ivona

Kijevčanin, Mirjana

Article (Published version)

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Densities, refractive indices, and viscosities of 1-amino-2-propanol (monoisopropanolamine (MIPA)) + 1-butanol and 1-amino-2-propanol + 2-butanol solutions are reported over the entire range of mole fractions and the temperature range from (288.15 to 333.15) K. The Redlich-Kister relation was used for correlation of measured results of excess molar volumes, viscosities, and refractive indices as a function of temperature and composition. Partial molar volumes at infinite dilution were determined from apparent molar volumes. Negative values for excess molar volumes, refractive indices, and viscosity deviations are observed over the entire composition range. The viscosities of 1-amino-2-propanol with 1-butanol and 1-amino-2-propanol with 2-butanol are well represented by an Arrhenius equation. Activation energies for viscous flows are determined by linearization of the Arrhenius equation, providing a clear explanation of the influence on hydrogen bonding. In order to confirm molecular in...teractions between compounds obtained by analysis of infinite dilution of solute, a FT-IR spectroscopy study was performed at T = 298.15 K. Interactional and structural effects were investigated through calculations of excess Gibbs free energy of activation of viscous flow.
Source:
Journal of Chemical and Engineering Data, 2014, 59, 6, 1817-1829Publisher:
- Amer Chemical Soc, Washington
Funding / projects:
- Ministry of Science and Environmental Protection, Serbia
- New industrial and environmental application of chemical thermodynamics to the development of the chemical processes with multiphase and multicomponent systems (RS-172063)
DOI: 10.1021/je401036f
ISSN: 0021-9568
WoS: 000337336700012
Scopus: 2-s2.0-84902357305
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Spasojević, Vuk D. AU - Đorđević, Bojan D. AU - Šerbanović, Slobodan P. AU - Radović, Ivona AU - Kijevčanin, Mirjana PY - 2014 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2787 AB - Densities, refractive indices, and viscosities of 1-amino-2-propanol (monoisopropanolamine (MIPA)) + 1-butanol and 1-amino-2-propanol + 2-butanol solutions are reported over the entire range of mole fractions and the temperature range from (288.15 to 333.15) K. The Redlich-Kister relation was used for correlation of measured results of excess molar volumes, viscosities, and refractive indices as a function of temperature and composition. Partial molar volumes at infinite dilution were determined from apparent molar volumes. Negative values for excess molar volumes, refractive indices, and viscosity deviations are observed over the entire composition range. The viscosities of 1-amino-2-propanol with 1-butanol and 1-amino-2-propanol with 2-butanol are well represented by an Arrhenius equation. Activation energies for viscous flows are determined by linearization of the Arrhenius equation, providing a clear explanation of the influence on hydrogen bonding. In order to confirm molecular interactions between compounds obtained by analysis of infinite dilution of solute, a FT-IR spectroscopy study was performed at T = 298.15 K. Interactional and structural effects were investigated through calculations of excess Gibbs free energy of activation of viscous flow. PB - Amer Chemical Soc, Washington T2 - Journal of Chemical and Engineering Data T1 - Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K EP - 1829 IS - 6 SP - 1817 VL - 59 DO - 10.1021/je401036f ER -
@article{ author = "Spasojević, Vuk D. and Đorđević, Bojan D. and Šerbanović, Slobodan P. and Radović, Ivona and Kijevčanin, Mirjana", year = "2014", abstract = "Densities, refractive indices, and viscosities of 1-amino-2-propanol (monoisopropanolamine (MIPA)) + 1-butanol and 1-amino-2-propanol + 2-butanol solutions are reported over the entire range of mole fractions and the temperature range from (288.15 to 333.15) K. The Redlich-Kister relation was used for correlation of measured results of excess molar volumes, viscosities, and refractive indices as a function of temperature and composition. Partial molar volumes at infinite dilution were determined from apparent molar volumes. Negative values for excess molar volumes, refractive indices, and viscosity deviations are observed over the entire composition range. The viscosities of 1-amino-2-propanol with 1-butanol and 1-amino-2-propanol with 2-butanol are well represented by an Arrhenius equation. Activation energies for viscous flows are determined by linearization of the Arrhenius equation, providing a clear explanation of the influence on hydrogen bonding. In order to confirm molecular interactions between compounds obtained by analysis of infinite dilution of solute, a FT-IR spectroscopy study was performed at T = 298.15 K. Interactional and structural effects were investigated through calculations of excess Gibbs free energy of activation of viscous flow.", publisher = "Amer Chemical Soc, Washington", journal = "Journal of Chemical and Engineering Data", title = "Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K", pages = "1829-1817", number = "6", volume = "59", doi = "10.1021/je401036f" }
Spasojević, V. D., Đorđević, B. D., Šerbanović, S. P., Radović, I.,& Kijevčanin, M.. (2014). Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K. in Journal of Chemical and Engineering Data Amer Chemical Soc, Washington., 59(6), 1817-1829. https://doi.org/10.1021/je401036f
Spasojević VD, Đorđević BD, Šerbanović SP, Radović I, Kijevčanin M. Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K. in Journal of Chemical and Engineering Data. 2014;59(6):1817-1829. doi:10.1021/je401036f .
Spasojević, Vuk D., Đorđević, Bojan D., Šerbanović, Slobodan P., Radović, Ivona, Kijevčanin, Mirjana, "Densities, Refractive Indices, Viscosities, and Spectroscopic Study of 1-Amino-2-propanol+1-Butanol and+2-Butanol Solutions at (288.15 to 333.15) K" in Journal of Chemical and Engineering Data, 59, no. 6 (2014):1817-1829, https://doi.org/10.1021/je401036f . .