The kinetics of the electrochemical degradation of methomyl has been study by the means of electrochemical techniques, UV-vis spectrophotometry, HPLC, and HPLC-ESI-MS in the sodium chloride containing solution. Degradation kinetics has been investigated on the DSA Ti/RuO2 electrode in mainly 2 g dm(-3) sodium chloride solution, applying the currents in the range of 10-90 mA and methomyl concentration from 0.05 to 0.5 mM. It has been suggested that methomyl degradation initially follows the pseudo zero-order Langmuir-Hinshelwood reaction kinetics, and mixed homogeneous and heterogeneous pseudo first-order reaction during prolonged electrolysis.
TY - JOUR
AU - Grgur, Branimir
AU - Mijin, Dušan
PY - 2014
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2798
AB - The kinetics of the electrochemical degradation of methomyl has been study by the means of electrochemical techniques, UV-vis spectrophotometry, HPLC, and HPLC-ESI-MS in the sodium chloride containing solution. Degradation kinetics has been investigated on the DSA Ti/RuO2 electrode in mainly 2 g dm(-3) sodium chloride solution, applying the currents in the range of 10-90 mA and methomyl concentration from 0.05 to 0.5 mM. It has been suggested that methomyl degradation initially follows the pseudo zero-order Langmuir-Hinshelwood reaction kinetics, and mixed homogeneous and heterogeneous pseudo first-order reaction during prolonged electrolysis.
PB - Elsevier, Amsterdam
T2 - Applied Catalysis B-Environmental
T1 - A kinetics study of the methomyl electrochemical degradation in the chloride containing solutions
EP - 438
SP - 429
VL - 147
DO - 10.1016/j.apcatb.2013.09.028
ER -
@article{
author = "Grgur, Branimir and Mijin, Dušan",
year = "2014",
abstract = "The kinetics of the electrochemical degradation of methomyl has been study by the means of electrochemical techniques, UV-vis spectrophotometry, HPLC, and HPLC-ESI-MS in the sodium chloride containing solution. Degradation kinetics has been investigated on the DSA Ti/RuO2 electrode in mainly 2 g dm(-3) sodium chloride solution, applying the currents in the range of 10-90 mA and methomyl concentration from 0.05 to 0.5 mM. It has been suggested that methomyl degradation initially follows the pseudo zero-order Langmuir-Hinshelwood reaction kinetics, and mixed homogeneous and heterogeneous pseudo first-order reaction during prolonged electrolysis.",
publisher = "Elsevier, Amsterdam",
journal = "Applied Catalysis B-Environmental",
title = "A kinetics study of the methomyl electrochemical degradation in the chloride containing solutions",
pages = "438-429",
volume = "147",
doi = "10.1016/j.apcatb.2013.09.028"
}
Grgur, B.,& Mijin, D.. (2014). A kinetics study of the methomyl electrochemical degradation in the chloride containing solutions. in Applied Catalysis B-Environmental
Elsevier, Amsterdam., 147, 429-438.
https://doi.org/10.1016/j.apcatb.2013.09.028
Grgur B, Mijin D. A kinetics study of the methomyl electrochemical degradation in the chloride containing solutions. in Applied Catalysis B-Environmental. 2014;147:429-438.
doi:10.1016/j.apcatb.2013.09.028 .
Grgur, Branimir, Mijin, Dušan, "A kinetics study of the methomyl electrochemical degradation in the chloride containing solutions" in Applied Catalysis B-Environmental, 147 (2014):429-438,
https://doi.org/10.1016/j.apcatb.2013.09.028 . .
