dc.creator | Grgur, Branimir | |
dc.creator | Mijin, Dušan | |
dc.date.accessioned | 2021-03-10T12:32:47Z | |
dc.date.available | 2021-03-10T12:32:47Z | |
dc.date.issued | 2014 | |
dc.identifier.issn | 0926-3373 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2798 | |
dc.description.abstract | The kinetics of the electrochemical degradation of methomyl has been study by the means of electrochemical techniques, UV-vis spectrophotometry, HPLC, and HPLC-ESI-MS in the sodium chloride containing solution. Degradation kinetics has been investigated on the DSA Ti/RuO2 electrode in mainly 2 g dm(-3) sodium chloride solution, applying the currents in the range of 10-90 mA and methomyl concentration from 0.05 to 0.5 mM. It has been suggested that methomyl degradation initially follows the pseudo zero-order Langmuir-Hinshelwood reaction kinetics, and mixed homogeneous and heterogeneous pseudo first-order reaction during prolonged electrolysis. | en |
dc.publisher | Elsevier, Amsterdam | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172013/RS// | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172046/RS// | |
dc.rights | restrictedAccess | |
dc.source | Applied Catalysis B-Environmental | |
dc.subject | Degradation | en |
dc.subject | Electrochemical | en |
dc.subject | Langmuir-Hinshelwood mechanism | en |
dc.subject | UV-vis | en |
dc.subject | LC-MS | en |
dc.title | A kinetics study of the methomyl electrochemical degradation in the chloride containing solutions | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 438 | |
dc.citation.other | 147: 429-438 | |
dc.citation.rank | aM21 | |
dc.citation.spage | 429 | |
dc.citation.volume | 147 | |
dc.identifier.doi | 10.1016/j.apcatb.2013.09.028 | |
dc.identifier.scopus | 2-s2.0-84885395580 | |
dc.identifier.wos | 000330489400048 | |
dc.type.version | publishedVersion | |