Приказ основних података о документу

dc.creatorStojaković, D.R.
dc.creatorRajić, Nevenka
dc.date.accessioned2021-03-10T09:34:12Z
dc.date.available2021-03-10T09:34:12Z
dc.date.issued1990
dc.identifier.issn0020-1693
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/27
dc.description.abstractIn solutions of phthalocyanine, H2Pc, (c = 1-3 × 10-5 mol dm-3) and copper(II) chloride (c ≈ 10-3 mol dm-3) in sulfuric acid (c = 16-18 mol dm-3), two pseudo first-order reactions take place: (1) decomposition of H2Pc; (2) conversion of H2Pc into copper(II) phthalocyanine, CuPc. Reaction (1) is H2O concentration dependent and its rate constant increases from 0.088 to 1.88 h-1 as the H2SO4 concentration changes from 18 to 16 mol dm-3. The rate constant of (2) does not vary significantly with H2SO4 concentration and lies around the 0.05 h-1 mark. The CuPc formed in reaction (2) does not decompose under the above conditions.en
dc.publisherElsevier Science Sa, Lausanne
dc.relationThis work was supported Serbia, Belgrade, Yugoslavia.
dc.rightsrestrictedAccess
dc.sourceInorganica Chimica Acta
dc.titleA kinetic study of the system phthalocyanine-copper(II) chloride-sulfuric aciden
dc.typearticle
dc.rights.licenseARR
dc.citation.epage20
dc.citation.issue1
dc.citation.other171(1): 17-20
dc.citation.spage17
dc.citation.volume171
dc.identifier.doi10.1016/S0020-1693(00)84656-3
dc.identifier.pmid
dc.identifier.scopus2-s2.0-33744483543
dc.type.versionpublishedVersion


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Приказ основних података о документу