Adsorption properties of two laboratory synthesized macroporous copolymers based on methyl and glycidyl methacrylate were investigated by inverse gas chromatography. Retentions of 12 organic compounds were measured in the temperature range from 65 to 80 degrees C. The gas/solid partition coefficients and the related thermodynamic function of adsorption at zero surface coverage were determined. The dispersive component of free surface energy of both copolymers, at investigated temperatures, was also calculated. The obtained experimental data were used to explain the polymer-adsorbate interaction.
Keywords:
inverse gas chromatography / macroporous copolymers of methyl and glycidyl methacrylate / surface properties / adsorption properties
TY - JOUR
AU - Onjia, Antonije
AU - Milonjić, Slobodan K.
AU - Jovanović, NN
AU - Jovanović, SM
PY - 2000
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/282
AB - Adsorption properties of two laboratory synthesized macroporous copolymers based on methyl and glycidyl methacrylate were investigated by inverse gas chromatography. Retentions of 12 organic compounds were measured in the temperature range from 65 to 80 degrees C. The gas/solid partition coefficients and the related thermodynamic function of adsorption at zero surface coverage were determined. The dispersive component of free surface energy of both copolymers, at investigated temperatures, was also calculated. The obtained experimental data were used to explain the polymer-adsorbate interaction.
PB - Elsevier, Amsterdam
T2 - Reactive & Functional Polymers
T1 - An inverse gas chromatography study of macroporous copolymers based on methyl and glycidyl methacrylate
EP - 277
IS - 3
SP - 269
VL - 43
DO - 10.1016/S1381-5148(99)00053-X
ER -
@article{
author = "Onjia, Antonije and Milonjić, Slobodan K. and Jovanović, NN and Jovanović, SM",
year = "2000",
abstract = "Adsorption properties of two laboratory synthesized macroporous copolymers based on methyl and glycidyl methacrylate were investigated by inverse gas chromatography. Retentions of 12 organic compounds were measured in the temperature range from 65 to 80 degrees C. The gas/solid partition coefficients and the related thermodynamic function of adsorption at zero surface coverage were determined. The dispersive component of free surface energy of both copolymers, at investigated temperatures, was also calculated. The obtained experimental data were used to explain the polymer-adsorbate interaction.",
publisher = "Elsevier, Amsterdam",
journal = "Reactive & Functional Polymers",
title = "An inverse gas chromatography study of macroporous copolymers based on methyl and glycidyl methacrylate",
pages = "277-269",
number = "3",
volume = "43",
doi = "10.1016/S1381-5148(99)00053-X"
}
Onjia, A., Milonjić, S. K., Jovanović, N.,& Jovanović, S.. (2000). An inverse gas chromatography study of macroporous copolymers based on methyl and glycidyl methacrylate. in Reactive & Functional Polymers
Elsevier, Amsterdam., 43(3), 269-277.
https://doi.org/10.1016/S1381-5148(99)00053-X
Onjia A, Milonjić SK, Jovanović N, Jovanović S. An inverse gas chromatography study of macroporous copolymers based on methyl and glycidyl methacrylate. in Reactive & Functional Polymers. 2000;43(3):269-277.
doi:10.1016/S1381-5148(99)00053-X .
Onjia, Antonije, Milonjić, Slobodan K., Jovanović, NN, Jovanović, SM, "An inverse gas chromatography study of macroporous copolymers based on methyl and glycidyl methacrylate" in Reactive & Functional Polymers, 43, no. 3 (2000):269-277,
https://doi.org/10.1016/S1381-5148(99)00053-X . .
