Pb(II) removal from aqueous solution by Myriophyllum spicatum and its compost: equilibrium, kinetic and thermodynamic study
Samo za registrovane korisnike
2014
Autori
Milojković, Jelena V.Mihajlović, Marija L.
Stojanović, Mirjana D.
Lopičić, Zorica
Petrović, Marija S.
Šoštarić, Tatjana
Ristić, Mirjana
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
BACKGROUND Lead is one of the frequent contaminants of industrial wastewater. Since it has been shown that aquatic plants can be used for the removal of heavy metals, herein Pb(II) biosorption by Myriophyllum spicatum and its compost were investigated. Effects of pH, ionic strength and contact time were analyzed using a batch experiment. Biomasses were characterized chemically and by Fourier transform infrared spectroscopy, scanning electron microscopy and X-ray diffraction techniques. RESULTS The adsorption process of both biosorbents followed a pseudo-second-order kinetic model. Compost exhibits better Pb(II) removal from solution (71%) compared with the plant (61%). Lead binding capacities for M. spicatum and its compost were 0.234 mmol g(-1) and 0.287 mmol g(-1) at pH 5.0, respectively. Lead binding takes place mainly through an ion exchange mechanism, but chemisorption via identified functional groups cannot be neglected. The Langmuir, Freundlich and Sips adsorption models for com...post were applied. The Sips isotherm model gave the best fit with the equilibrium experimental data. The sorption process by compost was endothermic and spontaneous. CONCLUSION Aquatic weed compost as a low cost biosorbent with high biosorption capacity can potentially be used for the removal of lead from wastewaters.
Ključne reči:
isotherm / Pb(II) ions / aquatic weed / compost / thermodynamic / biosorptionIzvor:
Journal of Chemical Technology and Biotechnology, 2014, 89, 5, 662-670Izdavač:
- Wiley, Hoboken
Finansiranje / projekti:
- Razvoj tehnologija i proizvoda na bazi mineralnih sirovina i otpadne biomase u cilju zaštite resursa za proizvodnju bezbedne hrane (RS-MESTD-Technological Development (TD or TR)-31003)
DOI: 10.1002/jctb.4184
ISSN: 0268-2575
WoS: 000333932700005
Scopus: 2-s2.0-84897576650
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Milojković, Jelena V. AU - Mihajlović, Marija L. AU - Stojanović, Mirjana D. AU - Lopičić, Zorica AU - Petrović, Marija S. AU - Šoštarić, Tatjana AU - Ristić, Mirjana PY - 2014 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2847 AB - BACKGROUND Lead is one of the frequent contaminants of industrial wastewater. Since it has been shown that aquatic plants can be used for the removal of heavy metals, herein Pb(II) biosorption by Myriophyllum spicatum and its compost were investigated. Effects of pH, ionic strength and contact time were analyzed using a batch experiment. Biomasses were characterized chemically and by Fourier transform infrared spectroscopy, scanning electron microscopy and X-ray diffraction techniques. RESULTS The adsorption process of both biosorbents followed a pseudo-second-order kinetic model. Compost exhibits better Pb(II) removal from solution (71%) compared with the plant (61%). Lead binding capacities for M. spicatum and its compost were 0.234 mmol g(-1) and 0.287 mmol g(-1) at pH 5.0, respectively. Lead binding takes place mainly through an ion exchange mechanism, but chemisorption via identified functional groups cannot be neglected. The Langmuir, Freundlich and Sips adsorption models for compost were applied. The Sips isotherm model gave the best fit with the equilibrium experimental data. The sorption process by compost was endothermic and spontaneous. CONCLUSION Aquatic weed compost as a low cost biosorbent with high biosorption capacity can potentially be used for the removal of lead from wastewaters. PB - Wiley, Hoboken T2 - Journal of Chemical Technology and Biotechnology T1 - Pb(II) removal from aqueous solution by Myriophyllum spicatum and its compost: equilibrium, kinetic and thermodynamic study EP - 670 IS - 5 SP - 662 VL - 89 DO - 10.1002/jctb.4184 ER -
@article{ author = "Milojković, Jelena V. and Mihajlović, Marija L. and Stojanović, Mirjana D. and Lopičić, Zorica and Petrović, Marija S. and Šoštarić, Tatjana and Ristić, Mirjana", year = "2014", abstract = "BACKGROUND Lead is one of the frequent contaminants of industrial wastewater. Since it has been shown that aquatic plants can be used for the removal of heavy metals, herein Pb(II) biosorption by Myriophyllum spicatum and its compost were investigated. Effects of pH, ionic strength and contact time were analyzed using a batch experiment. Biomasses were characterized chemically and by Fourier transform infrared spectroscopy, scanning electron microscopy and X-ray diffraction techniques. RESULTS The adsorption process of both biosorbents followed a pseudo-second-order kinetic model. Compost exhibits better Pb(II) removal from solution (71%) compared with the plant (61%). Lead binding capacities for M. spicatum and its compost were 0.234 mmol g(-1) and 0.287 mmol g(-1) at pH 5.0, respectively. Lead binding takes place mainly through an ion exchange mechanism, but chemisorption via identified functional groups cannot be neglected. The Langmuir, Freundlich and Sips adsorption models for compost were applied. The Sips isotherm model gave the best fit with the equilibrium experimental data. The sorption process by compost was endothermic and spontaneous. CONCLUSION Aquatic weed compost as a low cost biosorbent with high biosorption capacity can potentially be used for the removal of lead from wastewaters.", publisher = "Wiley, Hoboken", journal = "Journal of Chemical Technology and Biotechnology", title = "Pb(II) removal from aqueous solution by Myriophyllum spicatum and its compost: equilibrium, kinetic and thermodynamic study", pages = "670-662", number = "5", volume = "89", doi = "10.1002/jctb.4184" }
Milojković, J. V., Mihajlović, M. L., Stojanović, M. D., Lopičić, Z., Petrović, M. S., Šoštarić, T.,& Ristić, M.. (2014). Pb(II) removal from aqueous solution by Myriophyllum spicatum and its compost: equilibrium, kinetic and thermodynamic study. in Journal of Chemical Technology and Biotechnology Wiley, Hoboken., 89(5), 662-670. https://doi.org/10.1002/jctb.4184
Milojković JV, Mihajlović ML, Stojanović MD, Lopičić Z, Petrović MS, Šoštarić T, Ristić M. Pb(II) removal from aqueous solution by Myriophyllum spicatum and its compost: equilibrium, kinetic and thermodynamic study. in Journal of Chemical Technology and Biotechnology. 2014;89(5):662-670. doi:10.1002/jctb.4184 .
Milojković, Jelena V., Mihajlović, Marija L., Stojanović, Mirjana D., Lopičić, Zorica, Petrović, Marija S., Šoštarić, Tatjana, Ristić, Mirjana, "Pb(II) removal from aqueous solution by Myriophyllum spicatum and its compost: equilibrium, kinetic and thermodynamic study" in Journal of Chemical Technology and Biotechnology, 89, no. 5 (2014):662-670, https://doi.org/10.1002/jctb.4184 . .