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The influence of fly ash characteristics and reaction conditions on strength and structure of geopolymers

Authorized Users Only
2015
Authors
Nikolić, Violeta
Komljenović, Miroslav
Baščarević, Zvezdana
Marjanović, Nataša
Miladinović, Zoran P.
Petrović, Rada
Article (Published version)
Metadata
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Abstract
Reactivity of Class F fly ash (FA), development of strength, and structure of FA-based geopolymers, depending on the reaction conditions, were examined in this paper. The results of SEM/EDS and NMR analyses revealed that the composition of aluminosilicate gel changed during reaction, i.e. Si/Al atomic ratio decreased with the reaction time. Higher strength of geopolymers was associated with a higher fraction of aluminum rich structural units, higher crosslinking, and more compact structure. A rapid test for the assessment of FA reactivity and thus the applicability of FA for geopolymer synthesis was proposed.
Keywords:
Fly ash / Reactivity / Geopolymer / Compressive strength
Source:
Construction and Building Materials, 2015, 94, 361-370
Publisher:
  • Elsevier Sci Ltd, Oxford
Funding / projects:
  • Geopolymers - technology for converting the industrial waste into functional materials (RS-34026)
  • COST ActionEuropean Cooperation in Science and Technology (COST) [TU 1301]

DOI: 10.1016/j.conbuildmat.2015.07.014

ISSN: 0950-0618

WoS: 000359875200037

Scopus: 2-s2.0-84937552084
[ Google Scholar ]
68
54
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2963
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Nikolić, Violeta
AU  - Komljenović, Miroslav
AU  - Baščarević, Zvezdana
AU  - Marjanović, Nataša
AU  - Miladinović, Zoran P.
AU  - Petrović, Rada
PY  - 2015
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/2963
AB  - Reactivity of Class F fly ash (FA), development of strength, and structure of FA-based geopolymers, depending on the reaction conditions, were examined in this paper. The results of SEM/EDS and NMR analyses revealed that the composition of aluminosilicate gel changed during reaction, i.e. Si/Al atomic ratio decreased with the reaction time. Higher strength of geopolymers was associated with a higher fraction of aluminum rich structural units, higher crosslinking, and more compact structure. A rapid test for the assessment of FA reactivity and thus the applicability of FA for geopolymer synthesis was proposed.
PB  - Elsevier Sci Ltd, Oxford
T2  - Construction and Building Materials
T1  - The influence of fly ash characteristics and reaction conditions on strength and structure of geopolymers
EP  - 370
SP  - 361
VL  - 94
DO  - 10.1016/j.conbuildmat.2015.07.014
ER  - 
@article{
author = "Nikolić, Violeta and Komljenović, Miroslav and Baščarević, Zvezdana and Marjanović, Nataša and Miladinović, Zoran P. and Petrović, Rada",
year = "2015",
abstract = "Reactivity of Class F fly ash (FA), development of strength, and structure of FA-based geopolymers, depending on the reaction conditions, were examined in this paper. The results of SEM/EDS and NMR analyses revealed that the composition of aluminosilicate gel changed during reaction, i.e. Si/Al atomic ratio decreased with the reaction time. Higher strength of geopolymers was associated with a higher fraction of aluminum rich structural units, higher crosslinking, and more compact structure. A rapid test for the assessment of FA reactivity and thus the applicability of FA for geopolymer synthesis was proposed.",
publisher = "Elsevier Sci Ltd, Oxford",
journal = "Construction and Building Materials",
title = "The influence of fly ash characteristics and reaction conditions on strength and structure of geopolymers",
pages = "370-361",
volume = "94",
doi = "10.1016/j.conbuildmat.2015.07.014"
}
Nikolić, V., Komljenović, M., Baščarević, Z., Marjanović, N., Miladinović, Z. P.,& Petrović, R.. (2015). The influence of fly ash characteristics and reaction conditions on strength and structure of geopolymers. in Construction and Building Materials
Elsevier Sci Ltd, Oxford., 94, 361-370.
https://doi.org/10.1016/j.conbuildmat.2015.07.014
Nikolić V, Komljenović M, Baščarević Z, Marjanović N, Miladinović ZP, Petrović R. The influence of fly ash characteristics and reaction conditions on strength and structure of geopolymers. in Construction and Building Materials. 2015;94:361-370.
doi:10.1016/j.conbuildmat.2015.07.014 .
Nikolić, Violeta, Komljenović, Miroslav, Baščarević, Zvezdana, Marjanović, Nataša, Miladinović, Zoran P., Petrović, Rada, "The influence of fly ash characteristics and reaction conditions on strength and structure of geopolymers" in Construction and Building Materials, 94 (2015):361-370,
https://doi.org/10.1016/j.conbuildmat.2015.07.014 . .

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