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The protective properties of epoxy coating electrodeposited on Zn-Mn alloy substrate
dc.creator | Bucko, M. | |
dc.creator | Mišković-Stanković, Vesna | |
dc.creator | Rogan, Jelena | |
dc.creator | Bajat, Jelena | |
dc.date.accessioned | 2021-03-10T12:48:53Z | |
dc.date.available | 2021-03-10T12:48:53Z | |
dc.date.issued | 2015 | |
dc.identifier.issn | 0300-9440 | |
dc.identifier.uri | http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3047 | |
dc.description.abstract | The epoxy coating was cataphoretically deposited on steel and steel modified by electroplated Zn-Mn alloy of different chemical contents. The samples were immersed in 0.5 mol dm(-3) NaCl solution for 60 days. The electrochemical impedance spectroscopy (EIS) analysis showed that the values of pore resistance for epoxy coating on steel and Zn-Mn alloy with 16 at.% Mn were two orders of magnitude higher, while the capacitance values were two orders of magnitude lower than those for the epoxy coating on Zn-Mn alloy substrates with 5 and 8 at.% Mn. It was assumed that the main reason for such a difference was metallic substrate dissolution during cataphoretic deposition, due to high pH (12.9). This assumption was supported by energy dispersive X-ray spectrometry (EDS) measurements showing that the amount of released Zn in epoxy coatings decreased as Mn percent in the Zn-Mn alloys increased. In addition, Zn-Mn alloy coatings on steel, as well as bare steel, were immersed in 0.1 mol dm(-3) NaOH solution, pH 12.9, simulating conditions during cataphoretic deposition, and polarization resistance measurement in this solution indicated that Mn inclusions in Zn-Mn alloy substrate prevent Zn dissolution in alkaline medium. | en |
dc.publisher | Elsevier Science Sa, Lausanne | |
dc.relation | info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45019/RS// | |
dc.rights | restrictedAccess | |
dc.source | Progress in Organic Coatings | |
dc.subject | Zn-Mn alloy | en |
dc.subject | Epoxy coating | en |
dc.subject | Impedance spectroscopy | en |
dc.subject | Cataphoretic deposition | en |
dc.title | The protective properties of epoxy coating electrodeposited on Zn-Mn alloy substrate | en |
dc.type | article | |
dc.rights.license | ARR | |
dc.citation.epage | 16 | |
dc.citation.other | 79: 8-16 | |
dc.citation.rank | M21 | |
dc.citation.spage | 8 | |
dc.citation.volume | 79 | |
dc.identifier.doi | 10.1016/j.porgcoat.2014.10.010 | |
dc.identifier.scopus | 2-s2.0-84926292260 | |
dc.identifier.wos | 000348880500002 | |
dc.type.version | publishedVersion |