The possibility of application of zeolyte powders for the construction of membranes for carbon dioxide separation

2015
Authors
Nedeljković, Dragutin
Stevanović, Marija P.
Stijepović, Mirko

Stajčić, Aleksandar

Grujić, Aleksandar

Stajić-Trošić, Jasna
Stevanović, Jasmina

Article (Published version)
Metadata
Show full item recordAbstract
The aim of this study was to construct a polymer-based mixed matrix membrane that could be used for waste gases treatment. Therefore, high permeability for the carbon dioxide and low permeability for other gases commonly present in the industrial combustion waste gases (nitrogen, oxygen, hydrogen and methane) are essential. These membranes belong to the group of dense composite membranes, whose separation is based on the solutiondiffusion mechanism. In this paper, feasibility of the application of poly(ethylene oxide)-copoly(phtalamide) was tested. In order to enhance the permeability of carbon dioxide, three different zeolites with two-dimensional pores (IHW, NS/ and TER) were incorporated, and in order to improve compatibility between the inorganic particles and polymer chains, n-tetradecyldimethylamonium bromide (NTAB) was added. The best results in carbon dioxide/hydrogen selectivity were obtained with the membrane constructed with PEBAX 1657 and surface treated zeolites, while bet...ter results concerning selectivity were gained with membranes based on Polyactive.
Keywords:
mixed matrix membrane / zeolite / carbon dioxide separation / polymer matrix / membrane selectivitySource:
Chemical Industry & Chemical Engineering Quarterly, 2015, 21, 2, 277-284Publisher:
- Savez hemijskih inženjera, Beograd
Funding / projects:
- Predefined functional properties polymer composite materials processes and equipment development (RS-34011)
- Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-45019)
DOI: 10.2298/CICEQ130924025N
ISSN: 1451-9372
WoS: 000364475500006
Scopus: 2-s2.0-84931070172
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Nedeljković, Dragutin AU - Stevanović, Marija P. AU - Stijepović, Mirko AU - Stajčić, Aleksandar AU - Grujić, Aleksandar AU - Stajić-Trošić, Jasna AU - Stevanović, Jasmina PY - 2015 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3063 AB - The aim of this study was to construct a polymer-based mixed matrix membrane that could be used for waste gases treatment. Therefore, high permeability for the carbon dioxide and low permeability for other gases commonly present in the industrial combustion waste gases (nitrogen, oxygen, hydrogen and methane) are essential. These membranes belong to the group of dense composite membranes, whose separation is based on the solutiondiffusion mechanism. In this paper, feasibility of the application of poly(ethylene oxide)-copoly(phtalamide) was tested. In order to enhance the permeability of carbon dioxide, three different zeolites with two-dimensional pores (IHW, NS/ and TER) were incorporated, and in order to improve compatibility between the inorganic particles and polymer chains, n-tetradecyldimethylamonium bromide (NTAB) was added. The best results in carbon dioxide/hydrogen selectivity were obtained with the membrane constructed with PEBAX 1657 and surface treated zeolites, while better results concerning selectivity were gained with membranes based on Polyactive. PB - Savez hemijskih inženjera, Beograd T2 - Chemical Industry & Chemical Engineering Quarterly T1 - The possibility of application of zeolyte powders for the construction of membranes for carbon dioxide separation EP - 284 IS - 2 SP - 277 VL - 21 DO - 10.2298/CICEQ130924025N ER -
@article{ author = "Nedeljković, Dragutin and Stevanović, Marija P. and Stijepović, Mirko and Stajčić, Aleksandar and Grujić, Aleksandar and Stajić-Trošić, Jasna and Stevanović, Jasmina", year = "2015", abstract = "The aim of this study was to construct a polymer-based mixed matrix membrane that could be used for waste gases treatment. Therefore, high permeability for the carbon dioxide and low permeability for other gases commonly present in the industrial combustion waste gases (nitrogen, oxygen, hydrogen and methane) are essential. These membranes belong to the group of dense composite membranes, whose separation is based on the solutiondiffusion mechanism. In this paper, feasibility of the application of poly(ethylene oxide)-copoly(phtalamide) was tested. In order to enhance the permeability of carbon dioxide, three different zeolites with two-dimensional pores (IHW, NS/ and TER) were incorporated, and in order to improve compatibility between the inorganic particles and polymer chains, n-tetradecyldimethylamonium bromide (NTAB) was added. The best results in carbon dioxide/hydrogen selectivity were obtained with the membrane constructed with PEBAX 1657 and surface treated zeolites, while better results concerning selectivity were gained with membranes based on Polyactive.", publisher = "Savez hemijskih inženjera, Beograd", journal = "Chemical Industry & Chemical Engineering Quarterly", title = "The possibility of application of zeolyte powders for the construction of membranes for carbon dioxide separation", pages = "284-277", number = "2", volume = "21", doi = "10.2298/CICEQ130924025N" }
Nedeljković, D., Stevanović, M. P., Stijepović, M., Stajčić, A., Grujić, A., Stajić-Trošić, J.,& Stevanović, J.. (2015). The possibility of application of zeolyte powders for the construction of membranes for carbon dioxide separation. in Chemical Industry & Chemical Engineering Quarterly Savez hemijskih inženjera, Beograd., 21(2), 277-284. https://doi.org/10.2298/CICEQ130924025N
Nedeljković D, Stevanović MP, Stijepović M, Stajčić A, Grujić A, Stajić-Trošić J, Stevanović J. The possibility of application of zeolyte powders for the construction of membranes for carbon dioxide separation. in Chemical Industry & Chemical Engineering Quarterly. 2015;21(2):277-284. doi:10.2298/CICEQ130924025N .
Nedeljković, Dragutin, Stevanović, Marija P., Stijepović, Mirko, Stajčić, Aleksandar, Grujić, Aleksandar, Stajić-Trošić, Jasna, Stevanović, Jasmina, "The possibility of application of zeolyte powders for the construction of membranes for carbon dioxide separation" in Chemical Industry & Chemical Engineering Quarterly, 21, no. 2 (2015):277-284, https://doi.org/10.2298/CICEQ130924025N . .