Aim of this work was to study underpotential deposition of aluminium onto polycrystalline vanadium electrode from equimolar AlCl3+NaCl melt at 473, 523 and 573 K. It was found that aluminium was deposited and incorporated into polycrystalline vanadium electrode at potentials more positive than the Al reverse potential. Applied electrochemical techniques: linear sweep voltammetry and potentiostatic deposition/ galvanostatic striping, showed clear evidence of formation of three intermetallic compounds whose presence depends on temperature and applied deposition time. Deposits were studied via scanning electron microscopy (SEM), energy dispersive spectrometry and X-ray spectroscopy (EDS and EDX), atomic force microscopy (AFM) and X-ray diffraction (XRD).
TY - JOUR
AU - Jovicević, Niko
AU - Cvetković, Vesna S.
AU - Kamberović, Željko
AU - Barudžija, Tanja
PY - 2015
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3094
AB - Aim of this work was to study underpotential deposition of aluminium onto polycrystalline vanadium electrode from equimolar AlCl3+NaCl melt at 473, 523 and 573 K. It was found that aluminium was deposited and incorporated into polycrystalline vanadium electrode at potentials more positive than the Al reverse potential. Applied electrochemical techniques: linear sweep voltammetry and potentiostatic deposition/ galvanostatic striping, showed clear evidence of formation of three intermetallic compounds whose presence depends on temperature and applied deposition time. Deposits were studied via scanning electron microscopy (SEM), energy dispersive spectrometry and X-ray spectroscopy (EDS and EDX), atomic force microscopy (AFM) and X-ray diffraction (XRD).
PB - Electrochemical Science Group, Beograd
T2 - International Journal of Electrochemical Science
T1 - Aluminium Underpotential Deposition from AlCl3+NaCl Melts and Alloy Formation with Vanadium Substrate
EP - 8972
IS - 11
SP - 8959
VL - 10
UR - https://hdl.handle.net/21.15107/rcub_vinar_848
ER -
@article{
author = "Jovicević, Niko and Cvetković, Vesna S. and Kamberović, Željko and Barudžija, Tanja",
year = "2015",
abstract = "Aim of this work was to study underpotential deposition of aluminium onto polycrystalline vanadium electrode from equimolar AlCl3+NaCl melt at 473, 523 and 573 K. It was found that aluminium was deposited and incorporated into polycrystalline vanadium electrode at potentials more positive than the Al reverse potential. Applied electrochemical techniques: linear sweep voltammetry and potentiostatic deposition/ galvanostatic striping, showed clear evidence of formation of three intermetallic compounds whose presence depends on temperature and applied deposition time. Deposits were studied via scanning electron microscopy (SEM), energy dispersive spectrometry and X-ray spectroscopy (EDS and EDX), atomic force microscopy (AFM) and X-ray diffraction (XRD).",
publisher = "Electrochemical Science Group, Beograd",
journal = "International Journal of Electrochemical Science",
title = "Aluminium Underpotential Deposition from AlCl3+NaCl Melts and Alloy Formation with Vanadium Substrate",
pages = "8972-8959",
number = "11",
volume = "10",
url = "https://hdl.handle.net/21.15107/rcub_vinar_848"
}
Jovicević, N., Cvetković, V. S., Kamberović, Ž.,& Barudžija, T.. (2015). Aluminium Underpotential Deposition from AlCl3+NaCl Melts and Alloy Formation with Vanadium Substrate. in International Journal of Electrochemical Science
Electrochemical Science Group, Beograd., 10(11), 8959-8972.
https://hdl.handle.net/21.15107/rcub_vinar_848
Jovicević N, Cvetković VS, Kamberović Ž, Barudžija T. Aluminium Underpotential Deposition from AlCl3+NaCl Melts and Alloy Formation with Vanadium Substrate. in International Journal of Electrochemical Science. 2015;10(11):8959-8972.
https://hdl.handle.net/21.15107/rcub_vinar_848 .
Jovicević, Niko, Cvetković, Vesna S., Kamberović, Željko, Barudžija, Tanja, "Aluminium Underpotential Deposition from AlCl3+NaCl Melts and Alloy Formation with Vanadium Substrate" in International Journal of Electrochemical Science, 10, no. 11 (2015):8959-8972,
https://hdl.handle.net/21.15107/rcub_vinar_848 .
