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Electrochemical studies on LaNi4.15Co0.43Mn0.40Fe0.02 metal hydride alloy

Authorized Users Only
2000
Authors
Popović, MM
Grgur, Branimir
Vojnović, MV
Rakin, P
Krstajić, Nedeljko V.
Article (Published version)
Metadata
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Abstract
Electrochemical studies were performed on LaNi4.15Co0.43Mn0.40Fe0.02. alloy electrode. The kinetics of the electrochemical hydrogen absorption/desorption reaction was studied by DC polarization and AC impedance measurements. In a low overpotential range the reaction is charge-transfer controlled while in a high-overpotential range, the combine mechanism, charge-transfer and hydrogen diffusion in the bulk of the alloy is operative. Both exchange current, I-0, and hydrogen diffusion coefficient, D, slightly increase with hydrogen concentration in the alloy electrode.
Keywords:
hydride electrode / hydrogen absorption/desorption / hydrogen diffusion / AC impedance
Source:
Journal of Alloys and Compounds, 2000, 298, 1-2, 107-113
Publisher:
  • Elsevier Science Sa, Lausanne

DOI: 10.1016/S0925-8388(99)00605-2

ISSN: 0925-8388

WoS: 000084939600017

Scopus: 2-s2.0-0034135324
[ Google Scholar ]
16
15
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/320
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Popović, MM
AU  - Grgur, Branimir
AU  - Vojnović, MV
AU  - Rakin, P
AU  - Krstajić, Nedeljko V.
PY  - 2000
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/320
AB  - Electrochemical studies were performed on LaNi4.15Co0.43Mn0.40Fe0.02. alloy electrode. The kinetics of the electrochemical hydrogen absorption/desorption reaction was studied by DC polarization and AC impedance measurements. In a low overpotential range the reaction is charge-transfer controlled while in a high-overpotential range, the combine mechanism, charge-transfer and hydrogen diffusion in the bulk of the alloy is operative. Both exchange current, I-0, and hydrogen diffusion coefficient, D, slightly increase with hydrogen concentration in the alloy electrode.
PB  - Elsevier Science Sa, Lausanne
T2  - Journal of Alloys and Compounds
T1  - Electrochemical studies on LaNi4.15Co0.43Mn0.40Fe0.02 metal hydride alloy
EP  - 113
IS  - 1-2
SP  - 107
VL  - 298
DO  - 10.1016/S0925-8388(99)00605-2
ER  - 
@article{
author = "Popović, MM and Grgur, Branimir and Vojnović, MV and Rakin, P and Krstajić, Nedeljko V.",
year = "2000",
abstract = "Electrochemical studies were performed on LaNi4.15Co0.43Mn0.40Fe0.02. alloy electrode. The kinetics of the electrochemical hydrogen absorption/desorption reaction was studied by DC polarization and AC impedance measurements. In a low overpotential range the reaction is charge-transfer controlled while in a high-overpotential range, the combine mechanism, charge-transfer and hydrogen diffusion in the bulk of the alloy is operative. Both exchange current, I-0, and hydrogen diffusion coefficient, D, slightly increase with hydrogen concentration in the alloy electrode.",
publisher = "Elsevier Science Sa, Lausanne",
journal = "Journal of Alloys and Compounds",
title = "Electrochemical studies on LaNi4.15Co0.43Mn0.40Fe0.02 metal hydride alloy",
pages = "113-107",
number = "1-2",
volume = "298",
doi = "10.1016/S0925-8388(99)00605-2"
}
Popović, M., Grgur, B., Vojnović, M., Rakin, P.,& Krstajić, N. V.. (2000). Electrochemical studies on LaNi4.15Co0.43Mn0.40Fe0.02 metal hydride alloy. in Journal of Alloys and Compounds
Elsevier Science Sa, Lausanne., 298(1-2), 107-113.
https://doi.org/10.1016/S0925-8388(99)00605-2
Popović M, Grgur B, Vojnović M, Rakin P, Krstajić NV. Electrochemical studies on LaNi4.15Co0.43Mn0.40Fe0.02 metal hydride alloy. in Journal of Alloys and Compounds. 2000;298(1-2):107-113.
doi:10.1016/S0925-8388(99)00605-2 .
Popović, MM, Grgur, Branimir, Vojnović, MV, Rakin, P, Krstajić, Nedeljko V., "Electrochemical studies on LaNi4.15Co0.43Mn0.40Fe0.02 metal hydride alloy" in Journal of Alloys and Compounds, 298, no. 1-2 (2000):107-113,
https://doi.org/10.1016/S0925-8388(99)00605-2 . .

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