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Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode

Authorized Users Only
2016
Authors
Grgur, Branimir
Jugović, Branimir
Gvozdenović, Milica
Article (Published version)
Metadata
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Abstract
The potential characteristics of graphite felt electrodes, modified by iron oxide, for oxygen reduction are evaluated. Modification is carried out by Successive Ion Layer Adsorption and Reaction (SILAR) method, using a solution of ferric nitrate in methanol for the adsorption of ions, and a solution of sodium hypochlorite for reaction. The reaction activity of the oxygen reduction from the air, in sodium sulfate based solution varying the number of SILAR cycles, as well as the influence of pH is investigated. By comparing the activity with pure platinum, similar activity is obtained at pH = 9.2, as well as good electrode stability. Possible mechanism of the oxygen reduction on the graphite felt modified by iron oxide is discussed.
Keywords:
Fuel cells / Platinum / Mechanism / Hematite / Hypochlorite
Source:
Electrochimica Acta, 2016, 212, 254-259
Publisher:
  • Pergamon-Elsevier Science Ltd, Oxford
Funding / projects:
  • Electrochemical synthesis and characterization of nanostructured functional materials for application in new technologies (RS-172046)
  • 1612019

DOI: 10.1016/j.electacta.2016.07.029

ISSN: 0013-4686

WoS: 000382250200031

Scopus: 2-s2.0-84978288798
[ Google Scholar ]
5
3
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3237
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Grgur, Branimir
AU  - Jugović, Branimir
AU  - Gvozdenović, Milica
PY  - 2016
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3237
AB  - The potential characteristics of graphite felt electrodes, modified by iron oxide, for oxygen reduction are evaluated. Modification is carried out by Successive Ion Layer Adsorption and Reaction (SILAR) method, using a solution of ferric nitrate in methanol for the adsorption of ions, and a solution of sodium hypochlorite for reaction. The reaction activity of the oxygen reduction from the air, in sodium sulfate based solution varying the number of SILAR cycles, as well as the influence of pH is investigated. By comparing the activity with pure platinum, similar activity is obtained at pH = 9.2, as well as good electrode stability. Possible mechanism of the oxygen reduction on the graphite felt modified by iron oxide is discussed.
PB  - Pergamon-Elsevier Science Ltd, Oxford
T2  - Electrochimica Acta
T1  - Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode
EP  - 259
SP  - 254
VL  - 212
DO  - 10.1016/j.electacta.2016.07.029
ER  - 
@article{
author = "Grgur, Branimir and Jugović, Branimir and Gvozdenović, Milica",
year = "2016",
abstract = "The potential characteristics of graphite felt electrodes, modified by iron oxide, for oxygen reduction are evaluated. Modification is carried out by Successive Ion Layer Adsorption and Reaction (SILAR) method, using a solution of ferric nitrate in methanol for the adsorption of ions, and a solution of sodium hypochlorite for reaction. The reaction activity of the oxygen reduction from the air, in sodium sulfate based solution varying the number of SILAR cycles, as well as the influence of pH is investigated. By comparing the activity with pure platinum, similar activity is obtained at pH = 9.2, as well as good electrode stability. Possible mechanism of the oxygen reduction on the graphite felt modified by iron oxide is discussed.",
publisher = "Pergamon-Elsevier Science Ltd, Oxford",
journal = "Electrochimica Acta",
title = "Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode",
pages = "259-254",
volume = "212",
doi = "10.1016/j.electacta.2016.07.029"
}
Grgur, B., Jugović, B.,& Gvozdenović, M.. (2016). Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode. in Electrochimica Acta
Pergamon-Elsevier Science Ltd, Oxford., 212, 254-259.
https://doi.org/10.1016/j.electacta.2016.07.029
Grgur B, Jugović B, Gvozdenović M. Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode. in Electrochimica Acta. 2016;212:254-259.
doi:10.1016/j.electacta.2016.07.029 .
Grgur, Branimir, Jugović, Branimir, Gvozdenović, Milica, "Oxygen reduction on SILAR deposited iron oxide onto graphite felt electrode" in Electrochimica Acta, 212 (2016):254-259,
https://doi.org/10.1016/j.electacta.2016.07.029 . .

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