Thermodynamic and spectroscopic interpretation of molecular interactions of nicotine plus alcohol binary mixtures
Samo za registrovane korisnike
2016
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
Density rho, viscosity eta and refractive index n(D) have been experimentally measured for four binary mixtures nicotine + 1-butanol, nicotine + 2-butanol, nicotine + 1,2-propanediol and nicotine + 1,3-propanediol over the temperature range T = (293.15-323.15) K with temperature step 5 K and at atmospheric pressure. Excess molar volumes V-E, viscosity deviations Delta eta, deviations in refractive index Delta n(D), excess Gibbs free energy of activation of viscous flow Delta G*(E), thermal expansion coefficients a, excess thermal expansion coefficients alpha(E), partial molar volumes (V) over bar (i), excess partial molar volumes (V) over bar (E)(i) and it's values at infinite dilutions (V) over bar (E,infinity)(i) were calculated from experimental data and used to analyze non-ideal behavior of mixtures. Fourier-transform infrared analysis of binary mixtures and corresponding pure components was performed at 298.15 K in order to gain insight into the molecular structure of mixtures and... possible intermolecular interactions. Performed infra-red analysis confirms the presence of hydrogen bonding between unlike compounds, except for the system nicotine + 1-butanol. Here, the non-ideal behavior of mixtures is contributed to strong intermolecular interaction or in the case of nicotine + 1-butanol due to geometrical packing or dispersion forces of different species.
Ključne reči:
Experimental measurement of thermodynamic properties / Nicotine / Alcohol / FT-IR analysisIzvor:
Journal of Chemical Thermodynamics, 2016, 102, 105-129Izdavač:
- Academic Press Ltd- Elsevier Science Ltd, London
Finansiranje / projekti:
- Research Fund of Ministry of Education, Science and Technological Development, Serbia
- Novi industrijski i ekološki aspekti primene hemijske termodinamike na unapređenje hemijskih procesa sa višefaznim i višekomponentnim sistemima (RS-MESTD-Basic Research (BR or ON)-172063)
DOI: 10.1016/j.jct.2016.07.005
ISSN: 0021-9614
WoS: 000382266200012
Scopus: 2-s2.0-84978977032
Institucija/grupa
Tehnološko-metalurški fakultetTY - JOUR AU - Soldatović, Danijela AU - Vuksanović, Jelena AU - Radović, Ivona AU - Kijevčanin, Mirjana PY - 2016 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3366 AB - Density rho, viscosity eta and refractive index n(D) have been experimentally measured for four binary mixtures nicotine + 1-butanol, nicotine + 2-butanol, nicotine + 1,2-propanediol and nicotine + 1,3-propanediol over the temperature range T = (293.15-323.15) K with temperature step 5 K and at atmospheric pressure. Excess molar volumes V-E, viscosity deviations Delta eta, deviations in refractive index Delta n(D), excess Gibbs free energy of activation of viscous flow Delta G*(E), thermal expansion coefficients a, excess thermal expansion coefficients alpha(E), partial molar volumes (V) over bar (i), excess partial molar volumes (V) over bar (E)(i) and it's values at infinite dilutions (V) over bar (E,infinity)(i) were calculated from experimental data and used to analyze non-ideal behavior of mixtures. Fourier-transform infrared analysis of binary mixtures and corresponding pure components was performed at 298.15 K in order to gain insight into the molecular structure of mixtures and possible intermolecular interactions. Performed infra-red analysis confirms the presence of hydrogen bonding between unlike compounds, except for the system nicotine + 1-butanol. Here, the non-ideal behavior of mixtures is contributed to strong intermolecular interaction or in the case of nicotine + 1-butanol due to geometrical packing or dispersion forces of different species. PB - Academic Press Ltd- Elsevier Science Ltd, London T2 - Journal of Chemical Thermodynamics T1 - Thermodynamic and spectroscopic interpretation of molecular interactions of nicotine plus alcohol binary mixtures EP - 129 SP - 105 VL - 102 DO - 10.1016/j.jct.2016.07.005 ER -
@article{ author = "Soldatović, Danijela and Vuksanović, Jelena and Radović, Ivona and Kijevčanin, Mirjana", year = "2016", abstract = "Density rho, viscosity eta and refractive index n(D) have been experimentally measured for four binary mixtures nicotine + 1-butanol, nicotine + 2-butanol, nicotine + 1,2-propanediol and nicotine + 1,3-propanediol over the temperature range T = (293.15-323.15) K with temperature step 5 K and at atmospheric pressure. Excess molar volumes V-E, viscosity deviations Delta eta, deviations in refractive index Delta n(D), excess Gibbs free energy of activation of viscous flow Delta G*(E), thermal expansion coefficients a, excess thermal expansion coefficients alpha(E), partial molar volumes (V) over bar (i), excess partial molar volumes (V) over bar (E)(i) and it's values at infinite dilutions (V) over bar (E,infinity)(i) were calculated from experimental data and used to analyze non-ideal behavior of mixtures. Fourier-transform infrared analysis of binary mixtures and corresponding pure components was performed at 298.15 K in order to gain insight into the molecular structure of mixtures and possible intermolecular interactions. Performed infra-red analysis confirms the presence of hydrogen bonding between unlike compounds, except for the system nicotine + 1-butanol. Here, the non-ideal behavior of mixtures is contributed to strong intermolecular interaction or in the case of nicotine + 1-butanol due to geometrical packing or dispersion forces of different species.", publisher = "Academic Press Ltd- Elsevier Science Ltd, London", journal = "Journal of Chemical Thermodynamics", title = "Thermodynamic and spectroscopic interpretation of molecular interactions of nicotine plus alcohol binary mixtures", pages = "129-105", volume = "102", doi = "10.1016/j.jct.2016.07.005" }
Soldatović, D., Vuksanović, J., Radović, I.,& Kijevčanin, M.. (2016). Thermodynamic and spectroscopic interpretation of molecular interactions of nicotine plus alcohol binary mixtures. in Journal of Chemical Thermodynamics Academic Press Ltd- Elsevier Science Ltd, London., 102, 105-129. https://doi.org/10.1016/j.jct.2016.07.005
Soldatović D, Vuksanović J, Radović I, Kijevčanin M. Thermodynamic and spectroscopic interpretation of molecular interactions of nicotine plus alcohol binary mixtures. in Journal of Chemical Thermodynamics. 2016;102:105-129. doi:10.1016/j.jct.2016.07.005 .
Soldatović, Danijela, Vuksanović, Jelena, Radović, Ivona, Kijevčanin, Mirjana, "Thermodynamic and spectroscopic interpretation of molecular interactions of nicotine plus alcohol binary mixtures" in Journal of Chemical Thermodynamics, 102 (2016):105-129, https://doi.org/10.1016/j.jct.2016.07.005 . .