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The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate

Alkoholiza 1,2,2-trimetilpropil-metilfluorofosfata

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2000
0352-51390012857M.pdf (124.1Kb)
Authors
Mićević, Mlađen L.
Petrović, Slobodan
Article (Published version)
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Abstract
The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate (soman) was examined with a series of alkoxides and in corresponding alcohols: methanol, ethanol, 1-propanol, 2-propanol, 2-methoxyethanol and 2-ethoxyethanol. Soman reacts with the used alkoxides in a second order reaction, first order in each reactant. The kinetics of the reaction between 1,2,2-trimethylpropyl-methylfluorophosphonate and ethanol in the presence of diethylenetriamine was also examined. A third order reaction rate constant was calculated, first order in each reactant. The activation energy, frequency factor and activation entropy were determined on the basis of the kinetic data. .
Ispitana je alkoholiza 1,2,2-trimetilpropil-metilfluorofosfonata (soman) sa nizom alkoksida u odgovarajućim alkoholima: metanol, etanol, 1-propanol, 2-propanol, 2-metoksietanol i 2-etoksietanol. Soman reaguje sa ispitivanim alkoksidima u reakciji drugog reda, prvog reda prema svakom reaktantu. Ispitana je i kinetika reakcije između 1,2,2-trimetilpropil-metilfluorofosfonata i dietilentriamina u etanolu. Reakcija je ukupno trećeg reda, prvog prema svakom reaktantu. Za ispitivane reakcije su izračunate: energije aktivacije, faktori frekvencije i entropije aktivacije. .
Keywords:
decontamination / alcoholysis / 1,2,2-trimethylpropyl-methylfluorophosphonate / soman / alkoxides and diethylenetriamine
Source:
Journal of the Serbian Chemical Society, 2000, 65, 12, 857-866
Publisher:
  • Serbian Chemical Society, Belgrade

ISSN: 0352-5139

WoS: 000166372700003

Scopus: 2-s2.0-0034562153
[ Google Scholar ]
Handle
https://hdl.handle.net/21.15107/rcub_technorep_337
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/337
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Mićević, Mlađen L.
AU  - Petrović, Slobodan
PY  - 2000
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/337
AB  - The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate (soman) was examined with a series of alkoxides and in corresponding alcohols: methanol, ethanol, 1-propanol, 2-propanol, 2-methoxyethanol and 2-ethoxyethanol. Soman reacts with the used alkoxides in a second order reaction, first order in each reactant. The kinetics of the reaction between 1,2,2-trimethylpropyl-methylfluorophosphonate and ethanol in the presence of diethylenetriamine was also examined. A third order reaction rate constant was calculated, first order in each reactant. The activation energy, frequency factor and activation entropy were determined on the basis of the kinetic data. .
AB  - Ispitana je alkoholiza 1,2,2-trimetilpropil-metilfluorofosfonata (soman) sa nizom alkoksida u odgovarajućim alkoholima: metanol, etanol, 1-propanol, 2-propanol, 2-metoksietanol i 2-etoksietanol. Soman reaguje sa ispitivanim alkoksidima u reakciji drugog reda, prvog reda prema svakom reaktantu. Ispitana je i kinetika reakcije između 1,2,2-trimetilpropil-metilfluorofosfonata i dietilentriamina u etanolu. Reakcija je ukupno trećeg reda, prvog prema svakom reaktantu. Za ispitivane reakcije su izračunate: energije aktivacije, faktori frekvencije i entropije aktivacije. .
PB  - Serbian Chemical Society, Belgrade
T2  - Journal of the Serbian Chemical Society
T1  - The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate
T1  - Alkoholiza 1,2,2-trimetilpropil-metilfluorofosfata
EP  - 866
IS  - 12
SP  - 857
VL  - 65
UR  - https://hdl.handle.net/21.15107/rcub_technorep_337
ER  - 
@article{
author = "Mićević, Mlađen L. and Petrović, Slobodan",
year = "2000",
abstract = "The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate (soman) was examined with a series of alkoxides and in corresponding alcohols: methanol, ethanol, 1-propanol, 2-propanol, 2-methoxyethanol and 2-ethoxyethanol. Soman reacts with the used alkoxides in a second order reaction, first order in each reactant. The kinetics of the reaction between 1,2,2-trimethylpropyl-methylfluorophosphonate and ethanol in the presence of diethylenetriamine was also examined. A third order reaction rate constant was calculated, first order in each reactant. The activation energy, frequency factor and activation entropy were determined on the basis of the kinetic data. ., Ispitana je alkoholiza 1,2,2-trimetilpropil-metilfluorofosfonata (soman) sa nizom alkoksida u odgovarajućim alkoholima: metanol, etanol, 1-propanol, 2-propanol, 2-metoksietanol i 2-etoksietanol. Soman reaguje sa ispitivanim alkoksidima u reakciji drugog reda, prvog reda prema svakom reaktantu. Ispitana je i kinetika reakcije između 1,2,2-trimetilpropil-metilfluorofosfonata i dietilentriamina u etanolu. Reakcija je ukupno trećeg reda, prvog prema svakom reaktantu. Za ispitivane reakcije su izračunate: energije aktivacije, faktori frekvencije i entropije aktivacije. .",
publisher = "Serbian Chemical Society, Belgrade",
journal = "Journal of the Serbian Chemical Society",
title = "The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate, Alkoholiza 1,2,2-trimetilpropil-metilfluorofosfata",
pages = "866-857",
number = "12",
volume = "65",
url = "https://hdl.handle.net/21.15107/rcub_technorep_337"
}
Mićević, M. L.,& Petrović, S.. (2000). The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate. in Journal of the Serbian Chemical Society
Serbian Chemical Society, Belgrade., 65(12), 857-866.
https://hdl.handle.net/21.15107/rcub_technorep_337
Mićević ML, Petrović S. The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate. in Journal of the Serbian Chemical Society. 2000;65(12):857-866.
https://hdl.handle.net/21.15107/rcub_technorep_337 .
Mićević, Mlađen L., Petrović, Slobodan, "The alcoholysis of 1,2,2-trimethylpropyl-methylfluorophosphonate" in Journal of the Serbian Chemical Society, 65, no. 12 (2000):857-866,
https://hdl.handle.net/21.15107/rcub_technorep_337 .

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