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Effects of solid poly (ethylene glycols) addition to the solutions of aniline or N,N-dimethylaniline with water: Experimental measurements and modelling
In this work, the liquid-liquid and solid-liquid phase behaviour of ten aqueous pseudo-binary and three binary systems containing polyethylene glycol (PEG) 2050, polyethylene glycol 35000, aniline, N,N-dimethylaniline and water, in the temperature range 298.15-350.15 K and at ambient pressure of 0.1 MPa, was studied. The obtained temperature-composition phase diagrams showed that the only functional co-solvent was PEG2050 for aniline in water, while PEG35000 even showed a clear anti-solvent effect in the N,N-dimethylaniline aqueous system. The experimental solid-liquid equilibria (SLE) data have been correlated by the non-random two-liquid (NRTL) model, and the correlation results are in accordance with the experimental results.
TY - JOUR
AU - Soldatović, Danijela
AU - Grozdanić, Nikola
AU - Višak, Zoran P.
AU - Radović, Ivona
AU - Kijevčanin, Mirjana
PY - 2016
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3429
AB - In this work, the liquid-liquid and solid-liquid phase behaviour of ten aqueous pseudo-binary and three binary systems containing polyethylene glycol (PEG) 2050, polyethylene glycol 35000, aniline, N,N-dimethylaniline and water, in the temperature range 298.15-350.15 K and at ambient pressure of 0.1 MPa, was studied. The obtained temperature-composition phase diagrams showed that the only functional co-solvent was PEG2050 for aniline in water, while PEG35000 even showed a clear anti-solvent effect in the N,N-dimethylaniline aqueous system. The experimental solid-liquid equilibria (SLE) data have been correlated by the non-random two-liquid (NRTL) model, and the correlation results are in accordance with the experimental results.
PB - Srpsko hemijsko društvo, Beograd
T2 - Journal of the Serbian Chemical Society
T1 - Effects of solid poly (ethylene glycols) addition to the solutions of aniline or N,N-dimethylaniline with water: Experimental measurements and modelling
EP - 798
IS - 7
SP - 789
VL - 81
DO - 10.2298/JSC160317058S
ER -
@article{
author = "Soldatović, Danijela and Grozdanić, Nikola and Višak, Zoran P. and Radović, Ivona and Kijevčanin, Mirjana",
year = "2016",
abstract = "In this work, the liquid-liquid and solid-liquid phase behaviour of ten aqueous pseudo-binary and three binary systems containing polyethylene glycol (PEG) 2050, polyethylene glycol 35000, aniline, N,N-dimethylaniline and water, in the temperature range 298.15-350.15 K and at ambient pressure of 0.1 MPa, was studied. The obtained temperature-composition phase diagrams showed that the only functional co-solvent was PEG2050 for aniline in water, while PEG35000 even showed a clear anti-solvent effect in the N,N-dimethylaniline aqueous system. The experimental solid-liquid equilibria (SLE) data have been correlated by the non-random two-liquid (NRTL) model, and the correlation results are in accordance with the experimental results.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Effects of solid poly (ethylene glycols) addition to the solutions of aniline or N,N-dimethylaniline with water: Experimental measurements and modelling",
pages = "798-789",
number = "7",
volume = "81",
doi = "10.2298/JSC160317058S"
}
Soldatović, D., Grozdanić, N., Višak, Z. P., Radović, I.,& Kijevčanin, M.. (2016). Effects of solid poly (ethylene glycols) addition to the solutions of aniline or N,N-dimethylaniline with water: Experimental measurements and modelling. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 81(7), 789-798.
https://doi.org/10.2298/JSC160317058S
Soldatović D, Grozdanić N, Višak ZP, Radović I, Kijevčanin M. Effects of solid poly (ethylene glycols) addition to the solutions of aniline or N,N-dimethylaniline with water: Experimental measurements and modelling. in Journal of the Serbian Chemical Society. 2016;81(7):789-798.
doi:10.2298/JSC160317058S .
Soldatović, Danijela, Grozdanić, Nikola, Višak, Zoran P., Radović, Ivona, Kijevčanin, Mirjana, "Effects of solid poly (ethylene glycols) addition to the solutions of aniline or N,N-dimethylaniline with water: Experimental measurements and modelling" in Journal of the Serbian Chemical Society, 81, no. 7 (2016):789-798,
https://doi.org/10.2298/JSC160317058S . .
