Thermoplastic acrylic resin with self-healing properties
Само за регистроване кориснике
2016
Аутори
Yerro, OmarRadojević, Vesna
Radović, Ivana
Petrović, Miloš
Uskoković, Petar
Stojanović, Dušica
Aleksić, Radoslav
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
This article presents a novel processing method of a self-healing acrylic thermoplastic material starting from a healing agent in solution form. The self-healing system consisted of a solution of the healing agent dicyclopentadiene (DCPD) in dimethylformamide (DMF) and a solution of the catalyst bis(tricyclohexylphosphine) benzylidene ruthenium (IV) dichloride (called Grubbs' catalyst) in dichloromethane (DCM). Hollow glass tubes filled with the self-healing components were incorporated into autopolymerizing acrylic resins. The one set of tubes was filled with a solution of DCPD (containing the dye Rhodamine B as a marker) and the other set with a solution of Grubbs' catalyst in dichloromethane. FTIR and DSC analyses revealed that a poly(DCPD) film formed at the healed interface. The low energy impact tests of the samples showed a recovery of 83% after 4 days. The benefits of the Grubb's catalyst solution are twofold; besides the repair of the cracks, which is common for such a system,... the reaction could decrease the content of residual monomer in the acrylic resin, which could reduce diffusion of residual monomer out of the resins. POLYM. ENG. SCI., 56:251-257, 2016.
Извор:
Polymer Engineering and Science, 2016, 56, 3, 251-257Издавач:
- Wiley, Hoboken
Финансирање / пројекти:
- Развој опреме и процеса добијања полимерних композитних материјала са унапред дефинисаним функционалним својствима (RS-MESTD-Technological Development (TD or TR)-34011)
- Синтеза, развој технологија добијања и примена наноструктурних мултифункционалних материјала дефинисаних својстава (RS-MESTD-Integrated and Interdisciplinary Research (IIR or III)-45019)
DOI: 10.1002/pen.24244
ISSN: 0032-3888
WoS: 000371634200001
Scopus: 2-s2.0-84958864132
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Yerro, Omar AU - Radojević, Vesna AU - Radović, Ivana AU - Petrović, Miloš AU - Uskoković, Petar AU - Stojanović, Dušica AU - Aleksić, Radoslav PY - 2016 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3452 AB - This article presents a novel processing method of a self-healing acrylic thermoplastic material starting from a healing agent in solution form. The self-healing system consisted of a solution of the healing agent dicyclopentadiene (DCPD) in dimethylformamide (DMF) and a solution of the catalyst bis(tricyclohexylphosphine) benzylidene ruthenium (IV) dichloride (called Grubbs' catalyst) in dichloromethane (DCM). Hollow glass tubes filled with the self-healing components were incorporated into autopolymerizing acrylic resins. The one set of tubes was filled with a solution of DCPD (containing the dye Rhodamine B as a marker) and the other set with a solution of Grubbs' catalyst in dichloromethane. FTIR and DSC analyses revealed that a poly(DCPD) film formed at the healed interface. The low energy impact tests of the samples showed a recovery of 83% after 4 days. The benefits of the Grubb's catalyst solution are twofold; besides the repair of the cracks, which is common for such a system, the reaction could decrease the content of residual monomer in the acrylic resin, which could reduce diffusion of residual monomer out of the resins. POLYM. ENG. SCI., 56:251-257, 2016. PB - Wiley, Hoboken T2 - Polymer Engineering and Science T1 - Thermoplastic acrylic resin with self-healing properties EP - 257 IS - 3 SP - 251 VL - 56 DO - 10.1002/pen.24244 ER -
@article{ author = "Yerro, Omar and Radojević, Vesna and Radović, Ivana and Petrović, Miloš and Uskoković, Petar and Stojanović, Dušica and Aleksić, Radoslav", year = "2016", abstract = "This article presents a novel processing method of a self-healing acrylic thermoplastic material starting from a healing agent in solution form. The self-healing system consisted of a solution of the healing agent dicyclopentadiene (DCPD) in dimethylformamide (DMF) and a solution of the catalyst bis(tricyclohexylphosphine) benzylidene ruthenium (IV) dichloride (called Grubbs' catalyst) in dichloromethane (DCM). Hollow glass tubes filled with the self-healing components were incorporated into autopolymerizing acrylic resins. The one set of tubes was filled with a solution of DCPD (containing the dye Rhodamine B as a marker) and the other set with a solution of Grubbs' catalyst in dichloromethane. FTIR and DSC analyses revealed that a poly(DCPD) film formed at the healed interface. The low energy impact tests of the samples showed a recovery of 83% after 4 days. The benefits of the Grubb's catalyst solution are twofold; besides the repair of the cracks, which is common for such a system, the reaction could decrease the content of residual monomer in the acrylic resin, which could reduce diffusion of residual monomer out of the resins. POLYM. ENG. SCI., 56:251-257, 2016.", publisher = "Wiley, Hoboken", journal = "Polymer Engineering and Science", title = "Thermoplastic acrylic resin with self-healing properties", pages = "257-251", number = "3", volume = "56", doi = "10.1002/pen.24244" }
Yerro, O., Radojević, V., Radović, I., Petrović, M., Uskoković, P., Stojanović, D.,& Aleksić, R.. (2016). Thermoplastic acrylic resin with self-healing properties. in Polymer Engineering and Science Wiley, Hoboken., 56(3), 251-257. https://doi.org/10.1002/pen.24244
Yerro O, Radojević V, Radović I, Petrović M, Uskoković P, Stojanović D, Aleksić R. Thermoplastic acrylic resin with self-healing properties. in Polymer Engineering and Science. 2016;56(3):251-257. doi:10.1002/pen.24244 .
Yerro, Omar, Radojević, Vesna, Radović, Ivana, Petrović, Miloš, Uskoković, Petar, Stojanović, Dušica, Aleksić, Radoslav, "Thermoplastic acrylic resin with self-healing properties" in Polymer Engineering and Science, 56, no. 3 (2016):251-257, https://doi.org/10.1002/pen.24244 . .