The influence of m-aminobenzoic acid on electrochemical synthesis and behavior of poly(aniline-co-(m-aminobenzoic acid)
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2017
Authors
Jokić, BojanDžunuzović, Enis

Grgur, Branimir

Jugović, Branimir

Trišović, Tomislav

Stevanović, Jasmina

Gvozdenović, Milica

article (publishedVersion)

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Poly(aniline-co-(m-aminobenzoic acid)) was synthesized electrochemically at graphite electrode under galvanostatic conditions. Aqueous electrolyte for synthesis was consisted of HCl and different amount of aniline and m-aminobenzoic acid. The presence of the meta positioned carboxylic group in m-aminobenzoic acid influenced higher co-polymerization potential, different morphology and electrochemical behavior of copolymers compared to polyaniline. Electrochemical activity is achieved by proton exchange in neutral environment that can result in a faster charge/discharge process, which is in the case of PANI limited by slow anion exchange, making this material promising for consideration in super-capacitors and in biological system.
Keywords:
Electrochemical co-polymerization / Cyclic voltammetry / Poly(aniline-co-(m-aminobenzoic acid) / UV-vis spectroscopySource:
Journal of Polymer Research, 2017, 24, 9Publisher:
- Springer, Dordrecht
Funding / projects:
- info:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172046/RS// (RS-172046)
- info:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45019/RS// (RS-45019)
DOI: 10.1007/s10965-017-1313-5
ISSN: 1022-9760