Isopiestic determination of the osmotic and activity coefficients of the {yMg(NO3)(2) + (1-y)MgSO4}(aq) system at T=298.15 K
Само за регистроване кориснике
2017
Аутори
Ivanović, TijanaPopović, Daniela
Rard, Joseph A.
Grujić, Snežana
Miladinović, Zoran P.
Miladinović, Jelena
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Isopiestic (vapor pressure) measurements were made for aqueous mixtures of Mg(NO3)(2) and MgSO4 at T = (298.15 +/- 0.01) K with Mg(NO3)(2) ionic strength fractions y = (0.19691, 0.42542, 0.60113, 0.79583, and 1), along with a separate series of measurements for MgSO4(aq), y = 0, all using KCl(aq) as the reference standard. The resulting 44 molality-based osmotic coefficients for the ternary mixtures, ionic strength range I-m = (2.5924-8.4583) mol-kg(-1), were modeled with an extended form of Pitzer's ion interaction model, both with the usual Pitzer mixing terms and also with Scatchard's neutral electrolyte model mixing terms, and also with the Clegg-Pitzer-Brimblecombe model based on the mole-fraction-composition scale. The molality-based osmotic coefficients phi of these mixtures at each fixed ionic strength fraction fall in a regular order between those of the corresponding limiting binary solutions with no crossovers in this ionic strength range. Model parameters for Mg(NO3)(2)(aq)... and MgSO4(aq) at T = 298.15 K needed for these calculations were evaluated by using the present isopiestic results along with other sets of reliable osmotic coefficients gleaned from the published literature. Our osmotic coefficients for the ternary system are compared with those from a previous isopiestic study and a hygrometric study and the present results were judged to be more accurate. For this ternary system, both mixing parameters are needed for the extended Pitzer model with Pitzer mixing terms {standard uncertainty of fit u(phi)= 7.0 x 10(-3)} whereas three parameters gave a significantly better fit when the Scatchard mixing terms are used {standard uncertainty of fit u(phi) = 4.0 x 10(-3); the fits with two Scatchard mixing parameters did slightly better than the fit with both Pitzer mixing terms}, as did the Clegg-Pitzer-Brimblecombe model with three mixing parameters {standard uncertainty of fit u(phi) = 5.9 x 10(-3)}, with use of the three Scatchard mixing parameters giving the most precise representation of the experimental results. Including higher-order electrostatic mixing terms did not improve the representations but had the opposite effect.
Кључне речи:
Aqueous solutions / Isopiestic measurements / Mg(NO3)(2) / MgSO4 / Osmotic coefficients / Activity coefficientsИзвор:
Journal of Chemical Thermodynamics, 2017, 113, 91-103Издавач:
- Academic Press Ltd- Elsevier Science Ltd, London
Финансирање / пројекти:
- Нови индустријски и еколошки аспекти примене хемијске термодинамике на унапређење хемијских процеса са вишефазним и вишекомпонентним системима (RS-MESTD-Basic Research (BR or ON)-172063)
DOI: 10.1016/j.jct.2017.05.006
ISSN: 0021-9614
WoS: 000407984900011
Scopus: 2-s2.0-85020476192
Колекције
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Ivanović, Tijana AU - Popović, Daniela AU - Rard, Joseph A. AU - Grujić, Snežana AU - Miladinović, Zoran P. AU - Miladinović, Jelena PY - 2017 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3587 AB - Isopiestic (vapor pressure) measurements were made for aqueous mixtures of Mg(NO3)(2) and MgSO4 at T = (298.15 +/- 0.01) K with Mg(NO3)(2) ionic strength fractions y = (0.19691, 0.42542, 0.60113, 0.79583, and 1), along with a separate series of measurements for MgSO4(aq), y = 0, all using KCl(aq) as the reference standard. The resulting 44 molality-based osmotic coefficients for the ternary mixtures, ionic strength range I-m = (2.5924-8.4583) mol-kg(-1), were modeled with an extended form of Pitzer's ion interaction model, both with the usual Pitzer mixing terms and also with Scatchard's neutral electrolyte model mixing terms, and also with the Clegg-Pitzer-Brimblecombe model based on the mole-fraction-composition scale. The molality-based osmotic coefficients phi of these mixtures at each fixed ionic strength fraction fall in a regular order between those of the corresponding limiting binary solutions with no crossovers in this ionic strength range. Model parameters for Mg(NO3)(2)(aq) and MgSO4(aq) at T = 298.15 K needed for these calculations were evaluated by using the present isopiestic results along with other sets of reliable osmotic coefficients gleaned from the published literature. Our osmotic coefficients for the ternary system are compared with those from a previous isopiestic study and a hygrometric study and the present results were judged to be more accurate. For this ternary system, both mixing parameters are needed for the extended Pitzer model with Pitzer mixing terms {standard uncertainty of fit u(phi)= 7.0 x 10(-3)} whereas three parameters gave a significantly better fit when the Scatchard mixing terms are used {standard uncertainty of fit u(phi) = 4.0 x 10(-3); the fits with two Scatchard mixing parameters did slightly better than the fit with both Pitzer mixing terms}, as did the Clegg-Pitzer-Brimblecombe model with three mixing parameters {standard uncertainty of fit u(phi) = 5.9 x 10(-3)}, with use of the three Scatchard mixing parameters giving the most precise representation of the experimental results. Including higher-order electrostatic mixing terms did not improve the representations but had the opposite effect. PB - Academic Press Ltd- Elsevier Science Ltd, London T2 - Journal of Chemical Thermodynamics T1 - Isopiestic determination of the osmotic and activity coefficients of the {yMg(NO3)(2) + (1-y)MgSO4}(aq) system at T=298.15 K EP - 103 SP - 91 VL - 113 DO - 10.1016/j.jct.2017.05.006 ER -
@article{ author = "Ivanović, Tijana and Popović, Daniela and Rard, Joseph A. and Grujić, Snežana and Miladinović, Zoran P. and Miladinović, Jelena", year = "2017", abstract = "Isopiestic (vapor pressure) measurements were made for aqueous mixtures of Mg(NO3)(2) and MgSO4 at T = (298.15 +/- 0.01) K with Mg(NO3)(2) ionic strength fractions y = (0.19691, 0.42542, 0.60113, 0.79583, and 1), along with a separate series of measurements for MgSO4(aq), y = 0, all using KCl(aq) as the reference standard. The resulting 44 molality-based osmotic coefficients for the ternary mixtures, ionic strength range I-m = (2.5924-8.4583) mol-kg(-1), were modeled with an extended form of Pitzer's ion interaction model, both with the usual Pitzer mixing terms and also with Scatchard's neutral electrolyte model mixing terms, and also with the Clegg-Pitzer-Brimblecombe model based on the mole-fraction-composition scale. The molality-based osmotic coefficients phi of these mixtures at each fixed ionic strength fraction fall in a regular order between those of the corresponding limiting binary solutions with no crossovers in this ionic strength range. Model parameters for Mg(NO3)(2)(aq) and MgSO4(aq) at T = 298.15 K needed for these calculations were evaluated by using the present isopiestic results along with other sets of reliable osmotic coefficients gleaned from the published literature. Our osmotic coefficients for the ternary system are compared with those from a previous isopiestic study and a hygrometric study and the present results were judged to be more accurate. For this ternary system, both mixing parameters are needed for the extended Pitzer model with Pitzer mixing terms {standard uncertainty of fit u(phi)= 7.0 x 10(-3)} whereas three parameters gave a significantly better fit when the Scatchard mixing terms are used {standard uncertainty of fit u(phi) = 4.0 x 10(-3); the fits with two Scatchard mixing parameters did slightly better than the fit with both Pitzer mixing terms}, as did the Clegg-Pitzer-Brimblecombe model with three mixing parameters {standard uncertainty of fit u(phi) = 5.9 x 10(-3)}, with use of the three Scatchard mixing parameters giving the most precise representation of the experimental results. Including higher-order electrostatic mixing terms did not improve the representations but had the opposite effect.", publisher = "Academic Press Ltd- Elsevier Science Ltd, London", journal = "Journal of Chemical Thermodynamics", title = "Isopiestic determination of the osmotic and activity coefficients of the {yMg(NO3)(2) + (1-y)MgSO4}(aq) system at T=298.15 K", pages = "103-91", volume = "113", doi = "10.1016/j.jct.2017.05.006" }
Ivanović, T., Popović, D., Rard, J. A., Grujić, S., Miladinović, Z. P.,& Miladinović, J.. (2017). Isopiestic determination of the osmotic and activity coefficients of the {yMg(NO3)(2) + (1-y)MgSO4}(aq) system at T=298.15 K. in Journal of Chemical Thermodynamics Academic Press Ltd- Elsevier Science Ltd, London., 113, 91-103. https://doi.org/10.1016/j.jct.2017.05.006
Ivanović T, Popović D, Rard JA, Grujić S, Miladinović ZP, Miladinović J. Isopiestic determination of the osmotic and activity coefficients of the {yMg(NO3)(2) + (1-y)MgSO4}(aq) system at T=298.15 K. in Journal of Chemical Thermodynamics. 2017;113:91-103. doi:10.1016/j.jct.2017.05.006 .
Ivanović, Tijana, Popović, Daniela, Rard, Joseph A., Grujić, Snežana, Miladinović, Zoran P., Miladinović, Jelena, "Isopiestic determination of the osmotic and activity coefficients of the {yMg(NO3)(2) + (1-y)MgSO4}(aq) system at T=298.15 K" in Journal of Chemical Thermodynamics, 113 (2017):91-103, https://doi.org/10.1016/j.jct.2017.05.006 . .