The influence of alkaline cations on the mechanism and kinetics of dehydration of polymeric phthalatocuprate(II) dihydrates
2017
Аутори
Zdravković, Jelena D.Poleti, Dejan
Rogan, Jelena
Blagojević, Vladimir A.
Mészáros, Katalin
Minić, Dragica M.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Thermal dehydration of two heterometallic complexes containing dianion of phthalic acid, pht, Na-2[Cu(pht)(2)] center dot 2H(2)O, 1, and K-2[Cu(pht)(2)] center dot 2H(2)O, 2, was investigated under non-isothermal conditions. Mechanism and kinetics of dehydration were analyzed in detail using TG/DSC/MS measurements, XRPD analysis and FT-IR spectroscopy. The reversibility of dehydration processes was identified. According to XRPD, dehydrated product of 1 maintains original structure, but dehydration of 2 undergoes structural transformation giving a dehydrated product of different crystal structure. In both cases dehydration process involves more than one elementary step, which was confirmed using isoconversional methods Deconvolution of this process using Fraiser-Suzuki function yielded two single step processes for 1 and 2. Subsequent kinetic analysis was performed using Malek algorithm, resulting in the determination of kinetic triplets (E-a, A and f(alpha)) for each individual step. I...n addition, the dehydrated complexes were investigated as possible candidates for H-2 adsorption, using molecular simulations.
Кључне речи:
Heterometallic complexes / Mechanism and kinetics of dehydration / Deconvolution / Phthalate ionИзвор:
Journal of Analytical and Applied Pyrolysis, 2017, 126, 323-331Издавач:
- Elsevier Science Bv, Amsterdam
Финансирање / пројекти:
- 0-3D наноструктуре за примену у електроници и обновљивим изворима енергије: синтеза, карактеризација и процесирање (RS-45007)
- Неинвазивна И инвазивна детекција ендотелне дисфункције И коронарног вазоспазма код болесника са синдромом бола у грудима (RS-175020)
DOI: 10.1016/j.jaap.2017.05.014
ISSN: 0165-2370
WoS: 000407984300035
Scopus: 2-s2.0-85020429725
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Zdravković, Jelena D. AU - Poleti, Dejan AU - Rogan, Jelena AU - Blagojević, Vladimir A. AU - Mészáros, Katalin AU - Minić, Dragica M. PY - 2017 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3588 AB - Thermal dehydration of two heterometallic complexes containing dianion of phthalic acid, pht, Na-2[Cu(pht)(2)] center dot 2H(2)O, 1, and K-2[Cu(pht)(2)] center dot 2H(2)O, 2, was investigated under non-isothermal conditions. Mechanism and kinetics of dehydration were analyzed in detail using TG/DSC/MS measurements, XRPD analysis and FT-IR spectroscopy. The reversibility of dehydration processes was identified. According to XRPD, dehydrated product of 1 maintains original structure, but dehydration of 2 undergoes structural transformation giving a dehydrated product of different crystal structure. In both cases dehydration process involves more than one elementary step, which was confirmed using isoconversional methods Deconvolution of this process using Fraiser-Suzuki function yielded two single step processes for 1 and 2. Subsequent kinetic analysis was performed using Malek algorithm, resulting in the determination of kinetic triplets (E-a, A and f(alpha)) for each individual step. In addition, the dehydrated complexes were investigated as possible candidates for H-2 adsorption, using molecular simulations. PB - Elsevier Science Bv, Amsterdam T2 - Journal of Analytical and Applied Pyrolysis T1 - The influence of alkaline cations on the mechanism and kinetics of dehydration of polymeric phthalatocuprate(II) dihydrates EP - 331 SP - 323 VL - 126 DO - 10.1016/j.jaap.2017.05.014 ER -
@article{ author = "Zdravković, Jelena D. and Poleti, Dejan and Rogan, Jelena and Blagojević, Vladimir A. and Mészáros, Katalin and Minić, Dragica M.", year = "2017", abstract = "Thermal dehydration of two heterometallic complexes containing dianion of phthalic acid, pht, Na-2[Cu(pht)(2)] center dot 2H(2)O, 1, and K-2[Cu(pht)(2)] center dot 2H(2)O, 2, was investigated under non-isothermal conditions. Mechanism and kinetics of dehydration were analyzed in detail using TG/DSC/MS measurements, XRPD analysis and FT-IR spectroscopy. The reversibility of dehydration processes was identified. According to XRPD, dehydrated product of 1 maintains original structure, but dehydration of 2 undergoes structural transformation giving a dehydrated product of different crystal structure. In both cases dehydration process involves more than one elementary step, which was confirmed using isoconversional methods Deconvolution of this process using Fraiser-Suzuki function yielded two single step processes for 1 and 2. Subsequent kinetic analysis was performed using Malek algorithm, resulting in the determination of kinetic triplets (E-a, A and f(alpha)) for each individual step. In addition, the dehydrated complexes were investigated as possible candidates for H-2 adsorption, using molecular simulations.", publisher = "Elsevier Science Bv, Amsterdam", journal = "Journal of Analytical and Applied Pyrolysis", title = "The influence of alkaline cations on the mechanism and kinetics of dehydration of polymeric phthalatocuprate(II) dihydrates", pages = "331-323", volume = "126", doi = "10.1016/j.jaap.2017.05.014" }
Zdravković, J. D., Poleti, D., Rogan, J., Blagojević, V. A., Mészáros, K.,& Minić, D. M.. (2017). The influence of alkaline cations on the mechanism and kinetics of dehydration of polymeric phthalatocuprate(II) dihydrates. in Journal of Analytical and Applied Pyrolysis Elsevier Science Bv, Amsterdam., 126, 323-331. https://doi.org/10.1016/j.jaap.2017.05.014
Zdravković JD, Poleti D, Rogan J, Blagojević VA, Mészáros K, Minić DM. The influence of alkaline cations on the mechanism and kinetics of dehydration of polymeric phthalatocuprate(II) dihydrates. in Journal of Analytical and Applied Pyrolysis. 2017;126:323-331. doi:10.1016/j.jaap.2017.05.014 .
Zdravković, Jelena D., Poleti, Dejan, Rogan, Jelena, Blagojević, Vladimir A., Mészáros, Katalin, Minić, Dragica M., "The influence of alkaline cations on the mechanism and kinetics of dehydration of polymeric phthalatocuprate(II) dihydrates" in Journal of Analytical and Applied Pyrolysis, 126 (2017):323-331, https://doi.org/10.1016/j.jaap.2017.05.014 . .