A terephthalate-bridged heteronuclear Cu(II)-Mn(II) complex [Cu2Mn(dipya)(2)(tpht)(3)](n), I, where dipya is 2,2'-dipyridylamine and tpht is the anion of 1,4-benzenedicarboxylic (terephthalic, H(2)tpht) acid was synthesized under hydrothermal conditions. The obtained complex I was characterized by a single-crystal X-ray diffraction, FTIR spectroscopy, TG/DSC analysis and magnetic measurements. The Cu(II) and Mn(II) metal centers adopt distorted octahedral geometry and they are linked by bridging tpht ligands. Two crystallographically different tpht anions are coordinated as tridentate and hexadentate ligands forming two-dimensional layers. The layers are interconnected by hydrogen bonds and additionally stabilized by non-covalent C-H center dot center dot center dot pi p interactions. The measurements of magnetic susceptibility proved that I is an almost perfect paramagnet.
TY - JOUR
AU - Radovanović, Lidija
AU - Rogan, Jelena
AU - Poleti, Dejan
AU - Rodić, Marko
AU - Jaglicić, Zvonko
PY - 2017
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3602
AB - A terephthalate-bridged heteronuclear Cu(II)-Mn(II) complex [Cu2Mn(dipya)(2)(tpht)(3)](n), I, where dipya is 2,2'-dipyridylamine and tpht is the anion of 1,4-benzenedicarboxylic (terephthalic, H(2)tpht) acid was synthesized under hydrothermal conditions. The obtained complex I was characterized by a single-crystal X-ray diffraction, FTIR spectroscopy, TG/DSC analysis and magnetic measurements. The Cu(II) and Mn(II) metal centers adopt distorted octahedral geometry and they are linked by bridging tpht ligands. Two crystallographically different tpht anions are coordinated as tridentate and hexadentate ligands forming two-dimensional layers. The layers are interconnected by hydrogen bonds and additionally stabilized by non-covalent C-H center dot center dot center dot pi p interactions. The measurements of magnetic susceptibility proved that I is an almost perfect paramagnet.
PB - Srpsko hemijsko društvo, Beograd
T2 - Journal of the Serbian Chemical Society
T1 - A terephthalate-bridged two-dimensional heteronuclear Cu(II)-Mn(II) complex with a terminal 2,2 '-dipyridylamine ligand
EP - 1258
IS - 11
SP - 1247
VL - 82
DO - 10.2298/JSC170425086R
ER -
@article{
author = "Radovanović, Lidija and Rogan, Jelena and Poleti, Dejan and Rodić, Marko and Jaglicić, Zvonko",
year = "2017",
abstract = "A terephthalate-bridged heteronuclear Cu(II)-Mn(II) complex [Cu2Mn(dipya)(2)(tpht)(3)](n), I, where dipya is 2,2'-dipyridylamine and tpht is the anion of 1,4-benzenedicarboxylic (terephthalic, H(2)tpht) acid was synthesized under hydrothermal conditions. The obtained complex I was characterized by a single-crystal X-ray diffraction, FTIR spectroscopy, TG/DSC analysis and magnetic measurements. The Cu(II) and Mn(II) metal centers adopt distorted octahedral geometry and they are linked by bridging tpht ligands. Two crystallographically different tpht anions are coordinated as tridentate and hexadentate ligands forming two-dimensional layers. The layers are interconnected by hydrogen bonds and additionally stabilized by non-covalent C-H center dot center dot center dot pi p interactions. The measurements of magnetic susceptibility proved that I is an almost perfect paramagnet.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "A terephthalate-bridged two-dimensional heteronuclear Cu(II)-Mn(II) complex with a terminal 2,2 '-dipyridylamine ligand",
pages = "1258-1247",
number = "11",
volume = "82",
doi = "10.2298/JSC170425086R"
}
Radovanović, L., Rogan, J., Poleti, D., Rodić, M.,& Jaglicić, Z.. (2017). A terephthalate-bridged two-dimensional heteronuclear Cu(II)-Mn(II) complex with a terminal 2,2 '-dipyridylamine ligand. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 82(11), 1247-1258.
https://doi.org/10.2298/JSC170425086R
Radovanović L, Rogan J, Poleti D, Rodić M, Jaglicić Z. A terephthalate-bridged two-dimensional heteronuclear Cu(II)-Mn(II) complex with a terminal 2,2 '-dipyridylamine ligand. in Journal of the Serbian Chemical Society. 2017;82(11):1247-1258.
doi:10.2298/JSC170425086R .
Radovanović, Lidija, Rogan, Jelena, Poleti, Dejan, Rodić, Marko, Jaglicić, Zvonko, "A terephthalate-bridged two-dimensional heteronuclear Cu(II)-Mn(II) complex with a terminal 2,2 '-dipyridylamine ligand" in Journal of the Serbian Chemical Society, 82, no. 11 (2017):1247-1258,
https://doi.org/10.2298/JSC170425086R . .
