The thermal degradation of poly(ditetrahydrofurfuryl itaconate)
Само за регистроване кориснике
2001
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
The goal of this investigation was to study the thermal degradation of poly(ditetrahydro-furfuryl itaconate) (PDTHFI) by thermogravimetry (TG). The monomer was polymerized in bulk at 40 degreesC using AIBN as initiator. Non-oxidative degradation was studied under nitrogen, while oxidative degradation was studied under air, applying four heating rates (2.5, 10, 20 and 40 K/min), up to 600 degreesC. The apparent activation energy of thermal degradation, E-a, was calculated using the Flynn-Wall method. The obtained non-oxidative TG curves of PDTHFI are parallel and no heating rate effect was observed. A carbonaceous residue remained at 600 degreesC, regardless of the heating rate applied. The E-a of PDTHFI is constant in the whole mass loss range and its mean value is 124 kJ/mol. The non-oxidative differential TG (DTG) curves of PDTHFI consist of two peaks, the second being dominant. If it is assumed that depolymerization is the main degradation mechanism, analogous to other polyitaconate...s, these two peaks could be ascribed to two depolymerization initiation modes: end-chain beta -scission and random main chain scission. The oxidative TG curves are more complex than the non-oxidative ones and show a heating rate effect. The E-a steadily increases in the mass loss range of 5-50% from 120 to 200 kJ/mol. The oxidative DTG curves consist of a major peak with two shoulders and a second minor peak.
Кључне речи:
thermal degradation / poly(ditetrahydrofurfuryl itaconate) / heterocyclic polyitaconates / thermogravimetry / differential thermogravimetryИзвор:
Journal of Analytical and Applied Pyrolysis, 2001, 58, 205-211Издавач:
- Elsevier, Amsterdam
DOI: 10.1016/S0165-2370(00)00178-9
ISSN: 0165-2370
WoS: 000167485500015
Scopus: 2-s2.0-18544397501
Институција/група
Tehnološko-metalurški fakultetTY - JOUR AU - Veličković, Sava AU - Katsikas, Lynne AU - Popović, Ivanka PY - 2001 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/360 AB - The goal of this investigation was to study the thermal degradation of poly(ditetrahydro-furfuryl itaconate) (PDTHFI) by thermogravimetry (TG). The monomer was polymerized in bulk at 40 degreesC using AIBN as initiator. Non-oxidative degradation was studied under nitrogen, while oxidative degradation was studied under air, applying four heating rates (2.5, 10, 20 and 40 K/min), up to 600 degreesC. The apparent activation energy of thermal degradation, E-a, was calculated using the Flynn-Wall method. The obtained non-oxidative TG curves of PDTHFI are parallel and no heating rate effect was observed. A carbonaceous residue remained at 600 degreesC, regardless of the heating rate applied. The E-a of PDTHFI is constant in the whole mass loss range and its mean value is 124 kJ/mol. The non-oxidative differential TG (DTG) curves of PDTHFI consist of two peaks, the second being dominant. If it is assumed that depolymerization is the main degradation mechanism, analogous to other polyitaconates, these two peaks could be ascribed to two depolymerization initiation modes: end-chain beta -scission and random main chain scission. The oxidative TG curves are more complex than the non-oxidative ones and show a heating rate effect. The E-a steadily increases in the mass loss range of 5-50% from 120 to 200 kJ/mol. The oxidative DTG curves consist of a major peak with two shoulders and a second minor peak. PB - Elsevier, Amsterdam T2 - Journal of Analytical and Applied Pyrolysis T1 - The thermal degradation of poly(ditetrahydrofurfuryl itaconate) EP - 211 SP - 205 VL - 58 DO - 10.1016/S0165-2370(00)00178-9 ER -
@article{ author = "Veličković, Sava and Katsikas, Lynne and Popović, Ivanka", year = "2001", abstract = "The goal of this investigation was to study the thermal degradation of poly(ditetrahydro-furfuryl itaconate) (PDTHFI) by thermogravimetry (TG). The monomer was polymerized in bulk at 40 degreesC using AIBN as initiator. Non-oxidative degradation was studied under nitrogen, while oxidative degradation was studied under air, applying four heating rates (2.5, 10, 20 and 40 K/min), up to 600 degreesC. The apparent activation energy of thermal degradation, E-a, was calculated using the Flynn-Wall method. The obtained non-oxidative TG curves of PDTHFI are parallel and no heating rate effect was observed. A carbonaceous residue remained at 600 degreesC, regardless of the heating rate applied. The E-a of PDTHFI is constant in the whole mass loss range and its mean value is 124 kJ/mol. The non-oxidative differential TG (DTG) curves of PDTHFI consist of two peaks, the second being dominant. If it is assumed that depolymerization is the main degradation mechanism, analogous to other polyitaconates, these two peaks could be ascribed to two depolymerization initiation modes: end-chain beta -scission and random main chain scission. The oxidative TG curves are more complex than the non-oxidative ones and show a heating rate effect. The E-a steadily increases in the mass loss range of 5-50% from 120 to 200 kJ/mol. The oxidative DTG curves consist of a major peak with two shoulders and a second minor peak.", publisher = "Elsevier, Amsterdam", journal = "Journal of Analytical and Applied Pyrolysis", title = "The thermal degradation of poly(ditetrahydrofurfuryl itaconate)", pages = "211-205", volume = "58", doi = "10.1016/S0165-2370(00)00178-9" }
Veličković, S., Katsikas, L.,& Popović, I.. (2001). The thermal degradation of poly(ditetrahydrofurfuryl itaconate). in Journal of Analytical and Applied Pyrolysis Elsevier, Amsterdam., 58, 205-211. https://doi.org/10.1016/S0165-2370(00)00178-9
Veličković S, Katsikas L, Popović I. The thermal degradation of poly(ditetrahydrofurfuryl itaconate). in Journal of Analytical and Applied Pyrolysis. 2001;58:205-211. doi:10.1016/S0165-2370(00)00178-9 .
Veličković, Sava, Katsikas, Lynne, Popović, Ivanka, "The thermal degradation of poly(ditetrahydrofurfuryl itaconate)" in Journal of Analytical and Applied Pyrolysis, 58 (2001):205-211, https://doi.org/10.1016/S0165-2370(00)00178-9 . .