The electrocatalytic degradation of C.I. Acid Orange 3 from simulated wastewater by indirect electrochemical oxidation using an IrOx electrode was investigated. The effects of different operating parameters on the rate of dye decolorization were studied. The influences of mixing, electrolyte concentration, applied current, and initial dye concentration were examined. The change in dye concentration was followed by ultraviolet-visible spectroscopy, while the formation of reaction intermediates was established using high-performance liquid chromatography-mass spectrometry analysis. Ultraviolet-visible spectroscopy showed a decrease of the absorption peak at 374 nm during the electrolysis and the appearance of a new absorption maximum at 460 nm. The decolorization reaction can be followed only at 460 nm. Four intermediate products (two mono- and two dichlorinated) were detected. At the end of the study, a phytotoxicity assay was performed to determine the effectiveness of the applied meth...od. The results showed that the applied electrochemical treatment of C.I. Acid Orange 3 leads to a decrease in phytotoxicity from 53 to 28%.
TY - JOUR
AU - Mijin, Dušan
AU - Radišić, Marina
AU - Šekuljica, Nataša
AU - Grgur, Branimir
PY - 2017
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3612
AB - The electrocatalytic degradation of C.I. Acid Orange 3 from simulated wastewater by indirect electrochemical oxidation using an IrOx electrode was investigated. The effects of different operating parameters on the rate of dye decolorization were studied. The influences of mixing, electrolyte concentration, applied current, and initial dye concentration were examined. The change in dye concentration was followed by ultraviolet-visible spectroscopy, while the formation of reaction intermediates was established using high-performance liquid chromatography-mass spectrometry analysis. Ultraviolet-visible spectroscopy showed a decrease of the absorption peak at 374 nm during the electrolysis and the appearance of a new absorption maximum at 460 nm. The decolorization reaction can be followed only at 460 nm. Four intermediate products (two mono- and two dichlorinated) were detected. At the end of the study, a phytotoxicity assay was performed to determine the effectiveness of the applied method. The results showed that the applied electrochemical treatment of C.I. Acid Orange 3 leads to a decrease in phytotoxicity from 53 to 28%.
PB - Springer International Publishing Ag, Cham
T2 - Chemical Papers
T1 - Electrochemical decolorization of CI Acid Orange 3 in the presence of sodium chloride at iridium oxide electrode
EP - 2184
IS - 11
SP - 2173
VL - 71
DO - 10.1007/s11696-017-0211-y
ER -
@article{
author = "Mijin, Dušan and Radišić, Marina and Šekuljica, Nataša and Grgur, Branimir",
year = "2017",
abstract = "The electrocatalytic degradation of C.I. Acid Orange 3 from simulated wastewater by indirect electrochemical oxidation using an IrOx electrode was investigated. The effects of different operating parameters on the rate of dye decolorization were studied. The influences of mixing, electrolyte concentration, applied current, and initial dye concentration were examined. The change in dye concentration was followed by ultraviolet-visible spectroscopy, while the formation of reaction intermediates was established using high-performance liquid chromatography-mass spectrometry analysis. Ultraviolet-visible spectroscopy showed a decrease of the absorption peak at 374 nm during the electrolysis and the appearance of a new absorption maximum at 460 nm. The decolorization reaction can be followed only at 460 nm. Four intermediate products (two mono- and two dichlorinated) were detected. At the end of the study, a phytotoxicity assay was performed to determine the effectiveness of the applied method. The results showed that the applied electrochemical treatment of C.I. Acid Orange 3 leads to a decrease in phytotoxicity from 53 to 28%.",
publisher = "Springer International Publishing Ag, Cham",
journal = "Chemical Papers",
title = "Electrochemical decolorization of CI Acid Orange 3 in the presence of sodium chloride at iridium oxide electrode",
pages = "2184-2173",
number = "11",
volume = "71",
doi = "10.1007/s11696-017-0211-y"
}
Mijin, D., Radišić, M., Šekuljica, N.,& Grgur, B.. (2017). Electrochemical decolorization of CI Acid Orange 3 in the presence of sodium chloride at iridium oxide electrode. in Chemical Papers
Springer International Publishing Ag, Cham., 71(11), 2173-2184.
https://doi.org/10.1007/s11696-017-0211-y
Mijin D, Radišić M, Šekuljica N, Grgur B. Electrochemical decolorization of CI Acid Orange 3 in the presence of sodium chloride at iridium oxide electrode. in Chemical Papers. 2017;71(11):2173-2184.
doi:10.1007/s11696-017-0211-y .
Mijin, Dušan, Radišić, Marina, Šekuljica, Nataša, Grgur, Branimir, "Electrochemical decolorization of CI Acid Orange 3 in the presence of sodium chloride at iridium oxide electrode" in Chemical Papers, 71, no. 11 (2017):2173-2184,
https://doi.org/10.1007/s11696-017-0211-y . .
