In this paper, the Prigogine-Flory-Patterson (PFP) theoretical model and the extended real association solution (ERAS) model for the prediction of the excess molar volumes of 17 binary sets of alcohols (methanol, ethanol, propan-1-ol, butan-1-ol, butan-2-ol and pentan-1-ol) with benzene, chlorobenzene, acetonitrile, hexan-1-amine and n-heptane were tested at 298.15 K and atmospheric pressure. The binary sets contained 333 experimental data points for 11 different compounds. The ERAS model demonstrated better correlative characteristics for binary mixtures comparing to PFP model. The ERAS model is successfully applied on all binary systems except ethanol + benzene and propan- 1-ol + benzene. PFP model gave less satisfactory results for all systems except butan-1-ol + hexan-1-amine, for which obtained results were acceptable.
TY - JOUR
AU - Radović, Ivona
AU - Grozdanić, Nikola
AU - Đorđević, Bojan D.
AU - Šerbanović, Slobodan P.
AU - Kijevčanin, Mirjana
PY - 2017
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3640
AB - In this paper, the Prigogine-Flory-Patterson (PFP) theoretical model and the extended real association solution (ERAS) model for the prediction of the excess molar volumes of 17 binary sets of alcohols (methanol, ethanol, propan-1-ol, butan-1-ol, butan-2-ol and pentan-1-ol) with benzene, chlorobenzene, acetonitrile, hexan-1-amine and n-heptane were tested at 298.15 K and atmospheric pressure. The binary sets contained 333 experimental data points for 11 different compounds. The ERAS model demonstrated better correlative characteristics for binary mixtures comparing to PFP model. The ERAS model is successfully applied on all binary systems except ethanol + benzene and propan- 1-ol + benzene. PFP model gave less satisfactory results for all systems except butan-1-ol + hexan-1-amine, for which obtained results were acceptable.
PB - Srpsko hemijsko društvo, Beograd
T2 - Journal of the Serbian Chemical Society
T1 - Prediction of excess molar volumes of binary mixtures by Prigogine-Flory-Patterson (PFP) and extended real association solution (ERAS) models
EP - 1390
IS - 12
SP - 1379
VL - 82
DO - 10.2298/JSC170817103R
ER -
@article{
author = "Radović, Ivona and Grozdanić, Nikola and Đorđević, Bojan D. and Šerbanović, Slobodan P. and Kijevčanin, Mirjana",
year = "2017",
abstract = "In this paper, the Prigogine-Flory-Patterson (PFP) theoretical model and the extended real association solution (ERAS) model for the prediction of the excess molar volumes of 17 binary sets of alcohols (methanol, ethanol, propan-1-ol, butan-1-ol, butan-2-ol and pentan-1-ol) with benzene, chlorobenzene, acetonitrile, hexan-1-amine and n-heptane were tested at 298.15 K and atmospheric pressure. The binary sets contained 333 experimental data points for 11 different compounds. The ERAS model demonstrated better correlative characteristics for binary mixtures comparing to PFP model. The ERAS model is successfully applied on all binary systems except ethanol + benzene and propan- 1-ol + benzene. PFP model gave less satisfactory results for all systems except butan-1-ol + hexan-1-amine, for which obtained results were acceptable.",
publisher = "Srpsko hemijsko društvo, Beograd",
journal = "Journal of the Serbian Chemical Society",
title = "Prediction of excess molar volumes of binary mixtures by Prigogine-Flory-Patterson (PFP) and extended real association solution (ERAS) models",
pages = "1390-1379",
number = "12",
volume = "82",
doi = "10.2298/JSC170817103R"
}
Radović, I., Grozdanić, N., Đorđević, B. D., Šerbanović, S. P.,& Kijevčanin, M.. (2017). Prediction of excess molar volumes of binary mixtures by Prigogine-Flory-Patterson (PFP) and extended real association solution (ERAS) models. in Journal of the Serbian Chemical Society
Srpsko hemijsko društvo, Beograd., 82(12), 1379-1390.
https://doi.org/10.2298/JSC170817103R
Radović I, Grozdanić N, Đorđević BD, Šerbanović SP, Kijevčanin M. Prediction of excess molar volumes of binary mixtures by Prigogine-Flory-Patterson (PFP) and extended real association solution (ERAS) models. in Journal of the Serbian Chemical Society. 2017;82(12):1379-1390.
doi:10.2298/JSC170817103R .
Radović, Ivona, Grozdanić, Nikola, Đorđević, Bojan D., Šerbanović, Slobodan P., Kijevčanin, Mirjana, "Prediction of excess molar volumes of binary mixtures by Prigogine-Flory-Patterson (PFP) and extended real association solution (ERAS) models" in Journal of the Serbian Chemical Society, 82, no. 12 (2017):1379-1390,
https://doi.org/10.2298/JSC170817103R . .
