Electrochemical and microscopic techniques were used for the characterisation of Zn-Mn coatings electrodeposited from choline chloride-urea deep eutectic solvent. Cyclic voltammograms show that there was no discernible Mn reduction peak when only Mn2+ was present in DES solution. The distinct Mn peak developed only upon addition of Zn2+ to the solution, probably due to previous Zn nucleation on the steel substrate. It was found that 22-27 wt-% Mn deposited at current densities of 3-8 mA cm(-2), amounts significantly higher than those obtained from aqueous electrolytes. Since higher deposition current densities resulted in the formation of a porous surface consisting of clusters of nodular crystallites, the optimal deposition c.d was determined to be 3 mA cm(-2).
TY - JOUR
AU - Bucko, M.
AU - Culliton, D.
AU - Betts, A. J.
AU - Bajat, Jelena
PY - 2017
UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3700
AB - Electrochemical and microscopic techniques were used for the characterisation of Zn-Mn coatings electrodeposited from choline chloride-urea deep eutectic solvent. Cyclic voltammograms show that there was no discernible Mn reduction peak when only Mn2+ was present in DES solution. The distinct Mn peak developed only upon addition of Zn2+ to the solution, probably due to previous Zn nucleation on the steel substrate. It was found that 22-27 wt-% Mn deposited at current densities of 3-8 mA cm(-2), amounts significantly higher than those obtained from aqueous electrolytes. Since higher deposition current densities resulted in the formation of a porous surface consisting of clusters of nodular crystallites, the optimal deposition c.d was determined to be 3 mA cm(-2).
PB - Taylor & Francis Ltd, Abingdon
T2 - Transactions of the Institute of Metal Finishing
T1 - The electrochemical deposition of Zn-Mn coating from choline chloride-urea deep eutectic solvent
EP - 64
IS - 1
SP - 60
VL - 95
DO - 10.1080/00202967.2017.1255412
ER -
@article{
author = "Bucko, M. and Culliton, D. and Betts, A. J. and Bajat, Jelena",
year = "2017",
abstract = "Electrochemical and microscopic techniques were used for the characterisation of Zn-Mn coatings electrodeposited from choline chloride-urea deep eutectic solvent. Cyclic voltammograms show that there was no discernible Mn reduction peak when only Mn2+ was present in DES solution. The distinct Mn peak developed only upon addition of Zn2+ to the solution, probably due to previous Zn nucleation on the steel substrate. It was found that 22-27 wt-% Mn deposited at current densities of 3-8 mA cm(-2), amounts significantly higher than those obtained from aqueous electrolytes. Since higher deposition current densities resulted in the formation of a porous surface consisting of clusters of nodular crystallites, the optimal deposition c.d was determined to be 3 mA cm(-2).",
publisher = "Taylor & Francis Ltd, Abingdon",
journal = "Transactions of the Institute of Metal Finishing",
title = "The electrochemical deposition of Zn-Mn coating from choline chloride-urea deep eutectic solvent",
pages = "64-60",
number = "1",
volume = "95",
doi = "10.1080/00202967.2017.1255412"
}
Bucko, M., Culliton, D., Betts, A. J.,& Bajat, J.. (2017). The electrochemical deposition of Zn-Mn coating from choline chloride-urea deep eutectic solvent. in Transactions of the Institute of Metal Finishing
Taylor & Francis Ltd, Abingdon., 95(1), 60-64.
https://doi.org/10.1080/00202967.2017.1255412
Bucko M, Culliton D, Betts AJ, Bajat J. The electrochemical deposition of Zn-Mn coating from choline chloride-urea deep eutectic solvent. in Transactions of the Institute of Metal Finishing. 2017;95(1):60-64.
doi:10.1080/00202967.2017.1255412 .
Bucko, M., Culliton, D., Betts, A. J., Bajat, Jelena, "The electrochemical deposition of Zn-Mn coating from choline chloride-urea deep eutectic solvent" in Transactions of the Institute of Metal Finishing, 95, no. 1 (2017):60-64,
https://doi.org/10.1080/00202967.2017.1255412 . .
