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dc.creatorTomašević, Anđelka
dc.creatorMijin, Dušan
dc.creatorMarinković, Aleksandar
dc.creatorRadišić, Marina
dc.creatorPrlainović, Nevena
dc.creatorĐurović-Pejčev, Rada
dc.creatorGašić, Slavica
dc.date.accessioned2021-03-10T13:32:08Z
dc.date.available2021-03-10T13:32:08Z
dc.date.issued2017
dc.identifier.issn0944-1344
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/3711
dc.description.abstractA comparative study on photocatalytic degradation of the pesticide carbofuran and its commercial product Furadan 35-ST in an aqueous suspension of ZnO, irradiated by long-wave light (315-400 nm), is presented in this study. In order to assess the effects of inert ingredients present in the commercial product Furadan 35-ST, non-competitive and competitive adsorption and kinetic studies of carbofuran degradation processes were conducted. A higher photochemical degradation rate was found for pure carbofuran in comparison to a two-component system, carbofuran and single addition of ingredients at appropriate concentrations, and the commercial product Furadan 35-ST. The overall effect of inert ingredients was evaluated from a competitive study using the model system of Furadan 35-ST. The results of a mineralization study, obtained by ion chromatography (IC) and total organic carbon (TOC) analyses, revealed the formation of acetate, oxalate, and formate ions. Photodegradation products of carbofuran, three of them detected for the first time, were identified based on high-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) and gas chromatography-mass spectrometry (GC-MS) results, and their photodegradation pathways were proposed.en
dc.publisherSpringer Heidelberg, Heidelberg
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/46008/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172013/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172007/RS//
dc.relationinfo:eu-repo/grantAgreement/MESTD/Technological Development (TD or TR)/31043/RS//
dc.rightsrestrictedAccess
dc.sourceEnvironmental Science and Pollution Research
dc.subjectHeterogeneous photocatalysisen
dc.subjectCarbofuranen
dc.subjectFuradan 35-STen
dc.subjectInert ingredientsen
dc.subjectTransformation productsen
dc.titleThe photocatalytic degradation of carbofuran and Furadan 35-ST: the influence of inert ingredientsen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage13822
dc.citation.issue15
dc.citation.other24(15): 13808-13822
dc.citation.rankM22
dc.citation.spage13808
dc.citation.volume24
dc.identifier.doi10.1007/s11356-017-8949-x
dc.identifier.pmid28405924
dc.identifier.rcubconv_5310
dc.identifier.scopus2-s2.0-85017479467
dc.identifier.wos000401566600057
dc.type.versionpublishedVersion


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