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dc.creatorSoldatović, Danijela
dc.creatorVuksanović, Jelena
dc.creatorRadović, Ivona
dc.creatorVišak, Zoran P.
dc.creatorKijevčanin, Mirjana
dc.date.accessioned2021-03-10T13:33:44Z
dc.date.available2021-03-10T13:33:44Z
dc.date.issued2017
dc.identifier.issn0021-9614
dc.identifier.urihttp://TechnoRep.tmf.bg.ac.rs/handle/123456789/3736
dc.description.abstractIn this study, densities and viscosities of four binary systems {aniline/N,N-dimethylaniline + 1-butyl-3-methylimidazolium triflate ([bmim][OTf])} and {aniline/N,N-dimethylaniline + 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([bmim][NTf2])} were measured at atmospheric pressure and within the temperature range T = (288.15 to 333.15) K. Excess molar volumes V-E, viscosity deviations Delta eta and excess molar Gibbs energies of activation of viscous flow Delta G*(E) were calculated and the results were fitted to a Redlich-Kister polynomial equation. Also, enthalpic and entropic parts of the Delta G*(E) function were determined, at the same composition, for three studied systems that exhibit complete miscibility, since {aniline + [bmim][OTf]} is a partially miscible system. Considering the calculated thermodynamic properties, molecular interactions in the investigated binary systems were analysed and are discussed.en
dc.publisherAcademic Press Ltd- Elsevier Science Ltd, London
dc.relationMinistry of Education, Science and Technological Development, Serbia
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172063/RS//
dc.rightsopenAccess
dc.sourceJournal of Chemical Thermodynamics
dc.subjectDensityen
dc.subjectViscosityen
dc.subjectExcess molar Gibbs free energyen
dc.subjectAnilineen
dc.subjectN,N-dimethylanilineen
dc.subjectIonic liquidsen
dc.titleExcess molar volumes and viscosity behaviour of binary mixtures of aniline/or N,N-dimethylaniline with imidazolium ionic liquids having triflate or bistriflamide anionen
dc.typearticle
dc.rights.licenseARR
dc.citation.epage154
dc.citation.other109: 137-154
dc.citation.rankM21
dc.citation.spage137
dc.citation.volume109
dc.identifier.doi10.1016/j.jct.2017.02.007
dc.identifier.fulltexthttp://TechnoRep.tmf.bg.ac.rs/bitstream/id/1562/3733.pdf
dc.identifier.scopus2-s2.0-85013754743
dc.identifier.wos000399854400015
dc.type.versionpublishedVersion


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Приказ основних података о документу