Voltammetric and Quantum Investigation of Selected Succinimides

2018
Authors
Božić, Bojan
Lović, Jelena

Banjac, Nebojša

Vitnik, Željko

Vitnik, Vesna

Mijin, Dušan

Ušćumlić, Gordana

Avramov-Ivić, Milka

Article (Published version)

Metadata
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A series of succinimide derivatives were studied using the cyclic and square wave voltammetry. Density function theory was used in order to determinate which of the structural parameters influence the electrochemical activity. The quantum chemical calculations of the investigated succinimides were linked with the experimental electrochemical data and used to propose the oxidation mechanism. The most active among studied succinimides is 1,3-diphenylsuccinimide. The results obtained from the cyclic and square wave voltammetry and quantum chemical calculations indicate that the investigated compounds undergo oxidation by irreversible, diffusion controlled process including transfer of 1e(-) and 1 proton. The voltammetric and DFT results signify that the mechanism of electrochemical oxidation of all compounds involve the conversion of carbonyl-methyne-phenyl segment or methylene group in free radical. This conversion proceeds by the loss of one proton one electron process.
Keywords:
Diphenylsuccinimide / Threephenylsuccinimide / Voltammetry / Quantum chemical calculations / Reaction mechanismsSource:
International Journal of Electrochemical Science, 2018, 13, 5, 4285-4297Publisher:
- Electrochemical Science Group, Beograd
Funding / projects:
- Study of the Synthesis, Structure and Activity of Natural and Synthetic Organic Compounds (RS-172013)
- Rational design and synthesis of biologically active and coordination compounds and functional materials, relevant for (bio)nanotechnology (RS-172035)
- New approach in designing materials for energy conversion and energy storage systems (RS-172060)
DOI: 10.20964/2018.05.54
ISSN: 1452-3981
WoS: 000436257800020
Scopus: 2-s2.0-85046802281
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Božić, Bojan AU - Lović, Jelena AU - Banjac, Nebojša AU - Vitnik, Željko AU - Vitnik, Vesna AU - Mijin, Dušan AU - Ušćumlić, Gordana AU - Avramov-Ivić, Milka PY - 2018 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3871 AB - A series of succinimide derivatives were studied using the cyclic and square wave voltammetry. Density function theory was used in order to determinate which of the structural parameters influence the electrochemical activity. The quantum chemical calculations of the investigated succinimides were linked with the experimental electrochemical data and used to propose the oxidation mechanism. The most active among studied succinimides is 1,3-diphenylsuccinimide. The results obtained from the cyclic and square wave voltammetry and quantum chemical calculations indicate that the investigated compounds undergo oxidation by irreversible, diffusion controlled process including transfer of 1e(-) and 1 proton. The voltammetric and DFT results signify that the mechanism of electrochemical oxidation of all compounds involve the conversion of carbonyl-methyne-phenyl segment or methylene group in free radical. This conversion proceeds by the loss of one proton one electron process. PB - Electrochemical Science Group, Beograd T2 - International Journal of Electrochemical Science T1 - Voltammetric and Quantum Investigation of Selected Succinimides EP - 4297 IS - 5 SP - 4285 VL - 13 DO - 10.20964/2018.05.54 ER -
@article{ author = "Božić, Bojan and Lović, Jelena and Banjac, Nebojša and Vitnik, Željko and Vitnik, Vesna and Mijin, Dušan and Ušćumlić, Gordana and Avramov-Ivić, Milka", year = "2018", abstract = "A series of succinimide derivatives were studied using the cyclic and square wave voltammetry. Density function theory was used in order to determinate which of the structural parameters influence the electrochemical activity. The quantum chemical calculations of the investigated succinimides were linked with the experimental electrochemical data and used to propose the oxidation mechanism. The most active among studied succinimides is 1,3-diphenylsuccinimide. The results obtained from the cyclic and square wave voltammetry and quantum chemical calculations indicate that the investigated compounds undergo oxidation by irreversible, diffusion controlled process including transfer of 1e(-) and 1 proton. The voltammetric and DFT results signify that the mechanism of electrochemical oxidation of all compounds involve the conversion of carbonyl-methyne-phenyl segment or methylene group in free radical. This conversion proceeds by the loss of one proton one electron process.", publisher = "Electrochemical Science Group, Beograd", journal = "International Journal of Electrochemical Science", title = "Voltammetric and Quantum Investigation of Selected Succinimides", pages = "4297-4285", number = "5", volume = "13", doi = "10.20964/2018.05.54" }
Božić, B., Lović, J., Banjac, N., Vitnik, Ž., Vitnik, V., Mijin, D., Ušćumlić, G.,& Avramov-Ivić, M.. (2018). Voltammetric and Quantum Investigation of Selected Succinimides. in International Journal of Electrochemical Science Electrochemical Science Group, Beograd., 13(5), 4285-4297. https://doi.org/10.20964/2018.05.54
Božić B, Lović J, Banjac N, Vitnik Ž, Vitnik V, Mijin D, Ušćumlić G, Avramov-Ivić M. Voltammetric and Quantum Investigation of Selected Succinimides. in International Journal of Electrochemical Science. 2018;13(5):4285-4297. doi:10.20964/2018.05.54 .
Božić, Bojan, Lović, Jelena, Banjac, Nebojša, Vitnik, Željko, Vitnik, Vesna, Mijin, Dušan, Ušćumlić, Gordana, Avramov-Ivić, Milka, "Voltammetric and Quantum Investigation of Selected Succinimides" in International Journal of Electrochemical Science, 13, no. 5 (2018):4285-4297, https://doi.org/10.20964/2018.05.54 . .