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Image analysis as a useful tool for fast detection of dimensional and structural changes of poly(ethylene terephthalate) containers

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2018
3899.pdf (1.474Mb)
Authors
Jevremović, Nenad
Veličković, Sava
Kalagasidis Krušić, Melina
Panić, Vesna
Volkov-Husović, Tatjana
Jančić-Heinemann, Radmila
Popović, Ivanka
Article (Published version)
Metadata
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Abstract
The aim of this paper is to present image analysis as a useful technique for fast, reliable and non-destructive detection of dimensional and structural changes in polymers. The possibility of applying image analysis was demonstrated in the case of solvent-induced crystallization of poly(ethylene terephthalate) (PET) containers filled with commonly used organic solvents: chlorobenzene, isophorone, xylene, Espesol, Shellsol A 100, Solvesso 150, propylene glycol, glycerin and water and subjected to the storage stability test at 54 degrees C for 14 days (CIPAC 1-MT 46.1.3). In addition, the obtained results were analyzed using one-step analysis of variance (ANOVA) combined with the Duncan's statistical test (p lt 0.05). According to the achieved results, three main impacts of the presented paper could be distinguished: 1) dimensional and transparency changes could be precisely followed by image analysis in both following cases: for small changes in water, as well as for significant ones in... chlorobenzene; 2) a correlation between the changes in the degree of crystallinity and transparency could be obtained without the continuous material testing by DSC; 3) image analysis is potentially applicable for assessment of other crystalline polymers.

Keywords:
image analysis / fast detection / ageing / solvent diffusion / poly(ethylene terephthalate)
Source:
Hemijska industrija, 2018, 72, 6, 351-361
Publisher:
  • Savez hemijskih inženjera, Beograd
Funding / projects:
  • Synthesis and characterization of novel functional polymers and polymeric nanocomposites (RS-172062)
  • Size-, shape- and structure- dependent properties of nanoparticles and nanocomposites (RS-172056)
  • Predefined functional properties polymer composite materials processes and equipment development (RS-34011)
  • Synthesis, processing and characterization of nanostructured materials for application in the field of energy, mechanical engineering, environmental protection and biomedicine (RS-45012)

DOI: 10.2298/HEMIND180516027J

ISSN: 0367-598X

WoS: 000454433300004

Scopus: 2-s2.0-85063003847
[ Google Scholar ]
URI
http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3902
Collections
  • Radovi istraživača / Researchers’ publications (TMF)
  • Radovi istraživača (Inovacioni centar) / Researchers’ publications (Innovation Centre)
Institution/Community
Tehnološko-metalurški fakultet
TY  - JOUR
AU  - Jevremović, Nenad
AU  - Veličković, Sava
AU  - Kalagasidis Krušić, Melina
AU  - Panić, Vesna
AU  - Volkov-Husović, Tatjana
AU  - Jančić-Heinemann, Radmila
AU  - Popović, Ivanka
PY  - 2018
UR  - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3902
AB  - The aim of this paper is to present image analysis as a useful technique for fast, reliable and non-destructive detection of dimensional and structural changes in polymers. The possibility of applying image analysis was demonstrated in the case of solvent-induced crystallization of poly(ethylene terephthalate) (PET) containers filled with commonly used organic solvents: chlorobenzene, isophorone, xylene, Espesol, Shellsol A 100, Solvesso 150, propylene glycol, glycerin and water and subjected to the storage stability test at 54 degrees C for 14 days (CIPAC 1-MT 46.1.3). In addition, the obtained results were analyzed using one-step analysis of variance (ANOVA) combined with the Duncan's statistical test (p lt 0.05). According to the achieved results, three main impacts of the presented paper could be distinguished: 1) dimensional and transparency changes could be precisely followed by image analysis in both following cases: for small changes in water, as well as for significant ones in chlorobenzene; 2) a correlation between the changes in the degree of crystallinity and transparency could be obtained without the continuous material testing by DSC; 3) image analysis is potentially applicable for assessment of other crystalline polymers.
PB  - Savez hemijskih inženjera, Beograd
T2  - Hemijska industrija
T1  - Image analysis as a useful tool for fast detection of dimensional and structural changes of poly(ethylene terephthalate) containers
EP  - 361
IS  - 6
SP  - 351
VL  - 72
DO  - 10.2298/HEMIND180516027J
ER  - 
@article{
author = "Jevremović, Nenad and Veličković, Sava and Kalagasidis Krušić, Melina and Panić, Vesna and Volkov-Husović, Tatjana and Jančić-Heinemann, Radmila and Popović, Ivanka",
year = "2018",
abstract = "The aim of this paper is to present image analysis as a useful technique for fast, reliable and non-destructive detection of dimensional and structural changes in polymers. The possibility of applying image analysis was demonstrated in the case of solvent-induced crystallization of poly(ethylene terephthalate) (PET) containers filled with commonly used organic solvents: chlorobenzene, isophorone, xylene, Espesol, Shellsol A 100, Solvesso 150, propylene glycol, glycerin and water and subjected to the storage stability test at 54 degrees C for 14 days (CIPAC 1-MT 46.1.3). In addition, the obtained results were analyzed using one-step analysis of variance (ANOVA) combined with the Duncan's statistical test (p lt 0.05). According to the achieved results, three main impacts of the presented paper could be distinguished: 1) dimensional and transparency changes could be precisely followed by image analysis in both following cases: for small changes in water, as well as for significant ones in chlorobenzene; 2) a correlation between the changes in the degree of crystallinity and transparency could be obtained without the continuous material testing by DSC; 3) image analysis is potentially applicable for assessment of other crystalline polymers.",
publisher = "Savez hemijskih inženjera, Beograd",
journal = "Hemijska industrija",
title = "Image analysis as a useful tool for fast detection of dimensional and structural changes of poly(ethylene terephthalate) containers",
pages = "361-351",
number = "6",
volume = "72",
doi = "10.2298/HEMIND180516027J"
}
Jevremović, N., Veličković, S., Kalagasidis Krušić, M., Panić, V., Volkov-Husović, T., Jančić-Heinemann, R.,& Popović, I.. (2018). Image analysis as a useful tool for fast detection of dimensional and structural changes of poly(ethylene terephthalate) containers. in Hemijska industrija
Savez hemijskih inženjera, Beograd., 72(6), 351-361.
https://doi.org/10.2298/HEMIND180516027J
Jevremović N, Veličković S, Kalagasidis Krušić M, Panić V, Volkov-Husović T, Jančić-Heinemann R, Popović I. Image analysis as a useful tool for fast detection of dimensional and structural changes of poly(ethylene terephthalate) containers. in Hemijska industrija. 2018;72(6):351-361.
doi:10.2298/HEMIND180516027J .
Jevremović, Nenad, Veličković, Sava, Kalagasidis Krušić, Melina, Panić, Vesna, Volkov-Husović, Tatjana, Jančić-Heinemann, Radmila, Popović, Ivanka, "Image analysis as a useful tool for fast detection of dimensional and structural changes of poly(ethylene terephthalate) containers" in Hemijska industrija, 72, no. 6 (2018):351-361,
https://doi.org/10.2298/HEMIND180516027J . .

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