Synthesis of nife2o4 nanofibers by joint sol-gel and electrospinning technique

2018
Authors
Grujić, Aleksandar
Ćosović, Vladan
Stajić-Trošić, Jasna
Ćosović, Aleksandar
Stijepović, Mirko

Putić, Lana S.
Žák, Tomáš
Article (Published version)
Metadata
Show full item recordAbstract
In this study, electrospinning combined with sol-gel technique is applied in order to produce magnetic nickel ferrite (Ni-ferrite) nanofibers. The prepared Ni-ferrite gel was mixed with poly(vinylpyrrolidone) (PVP) solution which was used as a spinning aid to enable spinnability of the mixture. Structural and morphological characteristics of the asspun ferrite gel/PVP composite web structure and calcinated Ni-ferrite nanofibers were analyzed using scanning electron microscopy (SEM). Phase composition analysis was carried out by Fourier-transform infrared (FT-IR) spectroscopy, X-Ray diffraction analysis (XRD) and Fe-57 Mossbauer spectroscopy (MS). The obtained results suggest that the pure nanocrystalline NiFe2O4 dense mat to the almost coral-like structure of fibers with diameters ranging from hundreds of nanometers to few micrometers was obtained. The results of MS analysis revealed the existence of a crystallite size distribution within the material as well as the existence of a supe...rparamagnetic fraction with very small crystallite sizes ( lt 13nm). Magnetic behavior of the obtained material at elevated temperatures was also scrutinized using thermomagnetic measurements (TM) up to 800 degrees C.
Keywords:
Ni-ferrite / sol-gel / electrospinning, nanofibers / thermomagnetic behaviorSource:
Metallurgical & Materials Engineering, 2018, 24, 3, 173-180Publisher:
- Savez inženjera metalurgije Srbije, Beograd
Funding / projects:
- Predefined functional properties polymer composite materials processes and equipment development (RS-34011)
- Synthesis, processing and applications of nanostructured multifunctional materials with defined properties (RS-45019)
- Advanced multicomponent metal systems and nanostructured materials with diverse functional properties (RS-172037)
Institution/Community
Tehnološko-metalurški fakultetTY - JOUR AU - Grujić, Aleksandar AU - Ćosović, Vladan AU - Stajić-Trošić, Jasna AU - Ćosović, Aleksandar AU - Stijepović, Mirko AU - Putić, Lana S. AU - Žák, Tomáš PY - 2018 UR - http://TechnoRep.tmf.bg.ac.rs/handle/123456789/3914 AB - In this study, electrospinning combined with sol-gel technique is applied in order to produce magnetic nickel ferrite (Ni-ferrite) nanofibers. The prepared Ni-ferrite gel was mixed with poly(vinylpyrrolidone) (PVP) solution which was used as a spinning aid to enable spinnability of the mixture. Structural and morphological characteristics of the asspun ferrite gel/PVP composite web structure and calcinated Ni-ferrite nanofibers were analyzed using scanning electron microscopy (SEM). Phase composition analysis was carried out by Fourier-transform infrared (FT-IR) spectroscopy, X-Ray diffraction analysis (XRD) and Fe-57 Mossbauer spectroscopy (MS). The obtained results suggest that the pure nanocrystalline NiFe2O4 dense mat to the almost coral-like structure of fibers with diameters ranging from hundreds of nanometers to few micrometers was obtained. The results of MS analysis revealed the existence of a crystallite size distribution within the material as well as the existence of a superparamagnetic fraction with very small crystallite sizes ( lt 13nm). Magnetic behavior of the obtained material at elevated temperatures was also scrutinized using thermomagnetic measurements (TM) up to 800 degrees C. PB - Savez inženjera metalurgije Srbije, Beograd T2 - Metallurgical & Materials Engineering T1 - Synthesis of nife2o4 nanofibers by joint sol-gel and electrospinning technique EP - 180 IS - 3 SP - 173 VL - 24 DO - 10.30544/387 ER -
@article{ author = "Grujić, Aleksandar and Ćosović, Vladan and Stajić-Trošić, Jasna and Ćosović, Aleksandar and Stijepović, Mirko and Putić, Lana S. and Žák, Tomáš", year = "2018", abstract = "In this study, electrospinning combined with sol-gel technique is applied in order to produce magnetic nickel ferrite (Ni-ferrite) nanofibers. The prepared Ni-ferrite gel was mixed with poly(vinylpyrrolidone) (PVP) solution which was used as a spinning aid to enable spinnability of the mixture. Structural and morphological characteristics of the asspun ferrite gel/PVP composite web structure and calcinated Ni-ferrite nanofibers were analyzed using scanning electron microscopy (SEM). Phase composition analysis was carried out by Fourier-transform infrared (FT-IR) spectroscopy, X-Ray diffraction analysis (XRD) and Fe-57 Mossbauer spectroscopy (MS). The obtained results suggest that the pure nanocrystalline NiFe2O4 dense mat to the almost coral-like structure of fibers with diameters ranging from hundreds of nanometers to few micrometers was obtained. The results of MS analysis revealed the existence of a crystallite size distribution within the material as well as the existence of a superparamagnetic fraction with very small crystallite sizes ( lt 13nm). Magnetic behavior of the obtained material at elevated temperatures was also scrutinized using thermomagnetic measurements (TM) up to 800 degrees C.", publisher = "Savez inženjera metalurgije Srbije, Beograd", journal = "Metallurgical & Materials Engineering", title = "Synthesis of nife2o4 nanofibers by joint sol-gel and electrospinning technique", pages = "180-173", number = "3", volume = "24", doi = "10.30544/387" }
Grujić, A., Ćosović, V., Stajić-Trošić, J., Ćosović, A., Stijepović, M., Putić, L. S.,& Žák, T.. (2018). Synthesis of nife2o4 nanofibers by joint sol-gel and electrospinning technique. in Metallurgical & Materials Engineering Savez inženjera metalurgije Srbije, Beograd., 24(3), 173-180. https://doi.org/10.30544/387
Grujić A, Ćosović V, Stajić-Trošić J, Ćosović A, Stijepović M, Putić LS, Žák T. Synthesis of nife2o4 nanofibers by joint sol-gel and electrospinning technique. in Metallurgical & Materials Engineering. 2018;24(3):173-180. doi:10.30544/387 .
Grujić, Aleksandar, Ćosović, Vladan, Stajić-Trošić, Jasna, Ćosović, Aleksandar, Stijepović, Mirko, Putić, Lana S., Žák, Tomáš, "Synthesis of nife2o4 nanofibers by joint sol-gel and electrospinning technique" in Metallurgical & Materials Engineering, 24, no. 3 (2018):173-180, https://doi.org/10.30544/387 . .